Lithium diisopropylamide-mediated ortholithiations: lithium chloride catalysis.
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Fibre optic ATR-IR spectroscopy at cryogenic temperatures: in-line reaction monitoring on organolithium compounds.1,4-addition of lithium diisopropylamide to unsaturated esters: role of rate-limiting deaggregation, autocatalysis, lithium chloride catalysis, and other mixed aggregation effects.Lithium diisopropylamide-mediated lithiation of 1,4-difluorobenzene under nonequilibrium conditions: role of monomer-, dimer-, and tetramer-based intermediates and lessons about rate limitation.Regioselective lithium diisopropylamide-mediated ortholithiation of 1-chloro-3-(trifluoromethyl)benzene: role of autocatalysis, lithium chloride catalysis, and reversibility.Computational studies of lithium diisopropylamide deaggregation.Mechanism of Lithium Diisopropylamide-Mediated Ortholithiation of 1,4-Bis(trifluoromethyl)benzene under Nonequilibrium Conditions: Condition-Dependent Rate Limitation and Lithium Chloride-Catalyzed Inhibition.Lithium diisopropylamide-mediated ortholithiation of 2-fluoropyridines: rates, mechanisms, and the role of autocatalysis.Mixed lithium amide-lithium halide compounds: unusual halide-deficient amido metal anionic crowns.Development of a web-based platform for studying lithiation reactions in silico.LiTMP Trans-Metal-Trapping of Fluorinated Aromatic Molecules: A Comparative Study of Aluminum and Gallium Carbanion Traps.A hetero-alkali-metal version of the utility amide LDA: lithium-potassium diisopropylamide.Synthesis of 1-substituted tetrahydroisoquinolines by lithiation and electrophilic quenching guided by in situ IR and NMR spectroscopy and application to the synthesis of salsolidine, carnegine and laudanosine.Azomethine Ylides from Nitrones: Using Catalytic nBuLi for the Totally Stereoselective Synthesis of trans-2-Alkyl-3-oxazolines.Functionalizations of Mixtures of Regioisomeric Aryllithium Compounds by Selective Trapping with Dichlorozirconocene.Enantioselective installation of adjacent tertiary benzylic stereocentres using lithiation-borylation-protodeboronation methodology. Application to the synthesis of bifluranol and fluorohexestrol.Ligand-induced reactivity of β-diketiminate magnesium complexes for regioselective functionalization of fluoroarenes via C-H or C-F bond activations.Sodium Diisopropylamide in Tetrahydrofuran: Selectivities, Rates, and Mechanisms of Arene Metalations.Lithium Diisopropylamide: Nonequilibrium Kinetics and Lessons Learned about Rate Limitation.Large-scale preparation of key building blocks for the manufacture of fully synthetic macrolide antibiotics.Molecular salt effects in the gas phase: tuning the kinetic basicity of [HCCLiCl]⁻ and [HCCMgCl₂]⁻ by LiCl and MgCl₂.Case for Lithium Tetramethylpiperidide-Mediated Ortholithiations: Reactivity and Mechanisms.Enantioselective and Diastereoselective Tsuji-Trost Allylic Alkylation of Lactones: An Experimental and Computational StudyAssessment of the LiX salt-effect in anthracenyl lithiumsLiTMP Trans-Metal-Trapping of Fluorinated Aromatic Molecules: A Comparative Study of Aluminum and Gallium Carbanion TrapsOpening the black box of mixed-metal TMP metallating reagents: direct cadmation or lithium–cadmium transmetallation?“LiZn(TMP)3”, a Zincate or a Turbo-Lithium Amide Reagent? DOSY NMR Spectroscopic EvidenceSplit Personality of Lithium Chloride: Recent Salt Effects in Organometallic RecipesStructural and reactivity insights in Mg–Zn hybrid chemistry: Zn–I exchange and Pd-catalysed cross-coupling applications of aromatic substratesExpanding Mg-Zn Hybrid Chemistry: Inorganic Salt Effects in Addition Reactions of Organozinc Reagents to Trifluoroacetophenone and the Implications for a Synergistic Lithium-Magnesium-Zinc Activation
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P2860
Lithium diisopropylamide-mediated ortholithiations: lithium chloride catalysis.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on March 2009
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
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vědecký článek
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name
Lithium diisopropylamide-mediated ortholithiations: lithium chloride catalysis.
@en
Lithium diisopropylamide-mediated ortholithiations: lithium chloride catalysis.
@nl
type
label
Lithium diisopropylamide-mediated ortholithiations: lithium chloride catalysis.
@en
Lithium diisopropylamide-mediated ortholithiations: lithium chloride catalysis.
@nl
prefLabel
Lithium diisopropylamide-mediated ortholithiations: lithium chloride catalysis.
@en
Lithium diisopropylamide-mediated ortholithiations: lithium chloride catalysis.
@nl
P2093
P2860
P356
P1476
Lithium diisopropylamide-mediated ortholithiations: lithium chloride catalysis.
@en
P2093
Alexander C Hoepker
David B Collum
Kanwal J Singh
Lekha Gupta
P2860
P304
P356
10.1021/JO802713Y
P407
P577
2009-03-01T00:00:00Z