The organometallic fluorine chemistry of palladium and rhodium: studies toward aromatic fluorination.
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Catalysis for fluorination and trifluoromethylationLate-Stage Fluorination: From Fundamentals to ApplicationCopper-catalyzed trifluoromethylation of aryl iodides with potassium (trifluoromethyl)trimethoxyborate.Tamed arene and heteroarene trifluoromethylation.Fe(III)/NaBH4-mediated free radical hydrofluorination of unactivated alkenesStudying regioisomer formation in the Pd-catalyzed fluorination of aryl triflates by deuterium labeling.Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation.An improved palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides.Accelerating palladium-catalyzed C-F bond formation: use of a microflow packed-bed reactorDosage delivery of sensitive reagents enables glove-box-free synthesis.Evidence for in situ catalyst modification during the Pd-catalyzed conversion of aryl triflates to aryl fluorides.A Fluorinated Ligand Enables Room-Temperature and Regioselective Pd-Catalyzed Fluorination of Aryl Triflates and Bromides.Catalytic enantioselective cyclization and C3-fluorination of polyenes.In-Depth Assessment of the Palladium-Catalyzed Fluorination of Five-Membered Heteroaryl Bromides.Copper-catalyzed, directing group-assisted fluorination of arene and heteroarene C-H bonds.An improved catalyst system for the Pd-catalyzed fluorination of (hetero)aryl triflates.Silver-catalyzed vinylogous fluorination of vinyl diazoacetatesPd-catalyzed nucleophilic fluorination of aryl bromidesBystanding F+ oxidants enable selective reductive elimination from high-valent metal centers in catalysis.Transition metal catalysis and nucleophilic fluorination.High-valent organometallic copper and palladium in catalysis.Transition metal-catalyzed fluorination of multi carbon-carbon bonds: new strategies for fluorinated heterocycles.Introduction of fluorine and fluorine-containing functional groups.Stereoselectively fluorinated N-heterocycles: a brief survey.Late-stage formation of carbon-fluorine bonds.Recent advances in trifluoromethylation of organic compounds using Umemoto's reagents.Recent progress in direct introduction of fluorinated groups on alkenes and alkynes by means of C-H bond functionalization.Recent developments in the trifluoromethylation of alkynes.Photocatalytic fluoroalkylation reactions of organic compounds.Facile Access to Fluoroaromatic Molecules by Transition-Metal-Free C-F Bond Cleavage of Polyfluoroarenes: An Efficient, Green, and Sustainable Protocol.Aryl-CF(3) bond-forming reductive elimination from palladium(IV)Computational study of the hydrodefluorination of fluoroarenes at [Ru(NHC)(PR3)2(CO)(H)2]: predicted scope and regioselectivities.Silver-mediated trifluoromethylation of arenes using TMSCF3.Mechanism of C-F reductive elimination from palladium(IV) fluorides.The Evolution of Pd0/PdII-Catalyzed Aromatic Fluorination.Copper-mediated fluorination of aryl iodides.Metal-free trifluoromethylation of aromatic and heteroaromatic aldehydes and ketones.Electrophilic fluorination of cationic Pt-aryl complexesOxidation of a cyclometalated Pd(II) dimer with "CF3+": formation and reactivity of a catalytically competent monomeric Pd(IV) aquo complex.Ligand-Enabled Stereoselective β-C(sp(3))-H Fluorination: Synthesis of Unnatural Enantiopure anti-β-Fluoro-α-amino Acids.
P2860
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P2860
The organometallic fluorine chemistry of palladium and rhodium: studies toward aromatic fluorination.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on January 2010
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
The organometallic fluorine ch ...... toward aromatic fluorination.
@en
The organometallic fluorine ch ...... toward aromatic fluorination.
@nl
type
label
The organometallic fluorine ch ...... toward aromatic fluorination.
@en
The organometallic fluorine ch ...... toward aromatic fluorination.
@nl
prefLabel
The organometallic fluorine ch ...... toward aromatic fluorination.
@en
The organometallic fluorine ch ...... toward aromatic fluorination.
@nl
P356
P1476
The organometallic fluorine ch ...... toward aromatic fluorination.
@en
P2093
Vladimir V Grushin
P304
P356
10.1021/AR9001763
P577
2010-01-01T00:00:00Z