Aryl-CF(3) bond-forming reductive elimination from palladium(IV)
about
Catalysis for fluorination and trifluoromethylationA hybrid ring-opening metathesis polymerization catalyst based on an engineered variant of the β-barrel protein FhuA.Room temperature aryl trifluoromethylation via copper-mediated oxidative cross-coupling.Copper-catalyzed trifluoromethylation of aryl iodides with potassium (trifluoromethyl)trimethoxyborate.Copper-catalyzed trifluoromethylation of unactivated olefinsTaming of fluoroform: direct nucleophilic trifluoromethylation of Si, B, S, and C centers.Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation.Copper-catalyzed arylation of 1H-perfluoroalkanesPalladium-catalyzed intramolecular C-H difluoroalkylation: synthesis of substituted 3,3-difluoro-2-oxindoles.C-H bond activation at palladium(IV) centers.The palladium-catalyzed trifluoromethylation of vinyl sulfonates.Copper-Catalyzed Aerobic C-H Trifluoromethylation of Phenanthrolines.Bystanding F+ oxidants enable selective reductive elimination from high-valent metal centers in catalysis.Recent developments on the trifluoromethylation of (hetero)arenes.Introduction of fluorine and fluorine-containing functional groups.Recent advances in trifluoromethylation of organic compounds using Umemoto's reagents.Carbon-Hydrogen (C-H) Bond Activation at Pd(IV): A Frontier in C-H Functionalization Catalysis.Photocatalytic fluoroalkylation reactions of organic compounds.Silver-mediated trifluoromethoxylation of aryl stannanes and arylboronic acids.(4-Fluoro-phen-yl-κC)(N,N,N',N'-tetra-methyl-ethylenedi-amine-κ(2) N,N')(tri-fluoro-meth-yl-κC)palladium(II).Hypervalent Iodine Reagents in High Valent Transition Metal Chemistry.Silver-mediated trifluoromethylation of arenes using TMSCF3.Crystal structure of (4-fluoro-phenyl-κC (1))iodido-(N,N,N',N'-tetra-methyl-ethylenedi-amine-κ(2) N,N')palladium(II).Photoinitiated oxidative addition of CF3I to gold(I) and facile aryl-CF3 reductive eliminationThe palladium-catalyzed trifluoromethylation of aryl chlorides.A broadly applicable copper reagent for trifluoromethylations and perfluoroalkylations of aryl iodides and bromidesOxidation of a cyclometalated Pd(II) dimer with "CF3+": formation and reactivity of a catalytically competent monomeric Pd(IV) aquo complex.Pd-catalyzed α-arylation of trimethylsilyl enolates of α,α-difluoroacetamides.Identification of monodentate oxazoline as a ligand for copper-promoted ortho-C-H hydroxylation and aminationPd-catalyzed C-H fluorination with nucleophilic fluoride.Merging visible-light photocatalysis and transition-metal catalysis in the copper-catalyzed trifluoromethylation of boronic acids with CF3I.Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid.Investigations into Transition Metal Catalyzed Arene Trifluoromethylation ReactionsCopper(II)-catalyzed trifluoromethylation of N-aryl imines.Direct synthesis of a trifluoromethyl copper reagent from trifluoromethyl ketones: application to trifluoromethylation.Directing-group-assisted copper-catalyzed olefinic trifluoromethylation of electron-deficient alkenes.Copper-catalyzed trifluoromethylation-cyclization of enynes: highly regioselective construction of trifluoromethylated carbocycles and heterocycles.Sandmeyer trifluoromethylation of arenediazonium tetrafluoroborates.Copper-catalyzed synthesis of trifluoromethyl-substituted isoxazolines.C-H Bond Trifluoromethylation of Arenes Enabled by a Robust, High-Valent Nickel(IV) Complex.
P2860
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P2860
Aryl-CF(3) bond-forming reductive elimination from palladium(IV)
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Aryl-CF
@nl
Aryl-CF(3) bond-forming reductive elimination from palladium(IV)
@en
type
label
Aryl-CF
@nl
Aryl-CF(3) bond-forming reductive elimination from palladium(IV)
@en
prefLabel
Aryl-CF
@nl
Aryl-CF(3) bond-forming reductive elimination from palladium(IV)
@en
P2860
P356
P1476
Aryl-CF(3) bond-forming reductive elimination from palladium(IV)
@en
P2093
Jeff W Kampf
P2860
P304
P356
10.1021/JA100955X
P407
P577
2010-03-01T00:00:00Z