Dehydrogenation as a substrate-activating strategy in homogeneous transition-metal catalysis.
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Catalytic enantioselective C-H functionalization of alcohols by redox-triggered carbonyl addition: borrowing hydrogen, returning carbonPd/C-catalyzed aerobic oxidative esterification of alcohols and aldehydes: a highly efficient microwave-assisted green protocol.Ru(II) -mediated hydrogen transfer from aqueous glycerol to CO2: from waste to value-added products.From racemic alcohols to enantiopure amines: Ru-catalyzed diastereoselective aminationMolecular complexity via C-H activation: a dehydrogenative Diels-Alder reaction.Improvement of durability of an organic photocatalyst in p-xylene oxygenation by addition of a Cu(II) complex.Acceptorless dehydrogenation and dehydrogenative coupling of alcohols catalysed by protic NHC ruthenium complexes.Acceptorless dehydrogenation of small molecules through cooperative base metal catalysis.Intramolecular Hydrogen Transfer Reactions Catalyzed by Pentamethylcyclopentadienyl Rhodium and Cobalt Olefin Complexes: Mechanistic StudiesFormation of C-C bonds via ruthenium-catalyzed transfer hydrogenation().Atom-economic catalytic amide synthesis from amines and carboxylic acids activated in situ with acetylenes.Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes.Synthesis of cyclic enones via direct palladium-catalyzed aerobic dehydrogenation of ketones.Palladium-catalyzed aerobic dehydrogenation of substituted cyclohexanones to phenols.Catalytic Enantioselective Carbonyl Allylation and Propargylation via Alcohol-Mediated Hydrogen Transfer: Merging the Chemistry of Grignard and Sabatier.Advancements in the Synthesis and Applications of Cationic N-Heterocycles through Transition Metal-Catalyzed C-H Activation.Transition-metal catalyzed valorization of lignin: the key to a sustainable carbon-neutral future.Shuttle Catalysis-New Strategies in Organic Synthesis.N-Alkylation by Hydrogen Autotransfer Reactions.Catalytic enantioselective OFF ↔ ON activation processes initiated by hydrogen transfer: concepts and challenges.Synthesis of Quinolines via a Metal-Catalyzed Dehydrogenative N-Heterocyclization.C-Alkylation by Hydrogen Autotransfer Reactions.A site-holding effect of TiO2 surface hydroxyl in the photocatalytic direct synthesis of 1,1-diethoxyethane from ethanol.Alkyne-aldehyde reductive C-C coupling through ruthenium-catalyzed transfer hydrogenation: direct regio- and stereoselective carbonyl vinylation to form trisubstituted allylic alcohols in the absence of premetallated reagents.C-H functionalisation of cycloalkanes.Isomerization of Internal Alkynes to Iridium(III) Allene Complexes via C-H Bond Activation: Expanded Substrate Scope, and Progress towards a Catalytic Methodology.Allenamide hydro-hydroxyalkylation: 1,2-amino alcohols via ruthenium-catalyzed carbonyl anti-aminoallylation.Iridium Catalyzed Hydro-hydroxyalkylation of Butadiene: Carbonyl Crotylation.Ruthenium-catalyzed C-C bond cleavage in lignin model substrates.Crystal structure of the tetra-hydro-furan disolvate of a 94:6 solid solution of [N2,N6-bis-(di-tert-butyl-phosphan-yl)pyridine-2,6-di-amine]-dibromido-manganese(II) and its monophosphine oxide analogue.Ruthenium-Catalyzed Amination of Secondary Alcohols using Borrowing Hydrogen Methodology.Aerobic dehydrogenation of cyclohexanone to phenol catalyzed by Pd(TFA)2/2-dimethylaminopyridine: evidence for the role of Pd nanoparticlesTerminal olefins to linear α,β-unsaturated ketones: Pd(II)/hypervalent iodine co-catalyzed Wacker oxidation-dehydrogenation.Aerobic dehydrogenation of cyclohexanone to cyclohexenone catalyzed by Pd(DMSO)2(TFA)2: evidence for ligand-controlled chemoselectivity.Guided desaturation of unactivated aliphatics.Versatile routes for synthesis of diarylamines through acceptorless dehydrogenative aromatization catalysis over supported gold-palladium bimetallic nanoparticles.C(21)-C(40) of tetrafibricin via metal catalysis: beyond stoichiometric chiral reagents, auxiliaries, and premetalated nucleophiles.Sequential allylic C-H amination/vinylic C-H arylation: a strategy for unnatural amino acid synthesis from α-olefins.Diastereo- and enantioselective ruthenium-catalyzed hydrohydroxyalkylation of 2-silyl-butadienes: carbonyl syn-crotylation from the alcohol oxidation level.Direct generation of acyclic polypropionate stereopolyads via double diastereo- and enantioselective iridium-catalyzed crotylation of 1,3-diols: beyond stepwise carbonyl addition in polyketide construction.
P2860
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P2860
Dehydrogenation as a substrate-activating strategy in homogeneous transition-metal catalysis.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on February 2010
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
Dehydrogenation as a substrate ...... us transition-metal catalysis.
@en
Dehydrogenation as a substrate ...... us transition-metal catalysis.
@nl
type
label
Dehydrogenation as a substrate ...... us transition-metal catalysis.
@en
Dehydrogenation as a substrate ...... us transition-metal catalysis.
@nl
prefLabel
Dehydrogenation as a substrate ...... us transition-metal catalysis.
@en
Dehydrogenation as a substrate ...... us transition-metal catalysis.
@nl
P356
P1433
P1476
Dehydrogenation as a substrate ...... ous transition-metal catalysis
@en
P2093
Robert H Crabtree
P304
P356
10.1021/CR900202J
P577
2010-02-01T00:00:00Z