Asymmetric organocatalysis in total synthesis--a trial by fire.
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The ever-expanding role of asymmetric covalent organocatalysis in scalable, natural product synthesis.Synthesis of the tetracyclic core of Illicium sesquiterpenes using an organocatalyzed asymmetric Robinson annulation.Recent advances in enantioselective organocatalyzed anhydride desymmetrization and its application to the synthesis of valuable enantiopure compounds.Low-loading asymmetric organocatalysis.Recent advances in organocatalytic methods for the synthesis of disubstituted 2- and 3-indolinones.Applications of asymmetric organocatalysis in medicinal chemistry.Asymmetric organocatalysis mediated by α,α-L-diaryl prolinols: recent advances.Catalytic asymmetric synthesis of enantioenriched heterocycles bearing a C-CF3 stereogenic center.Asymmetric Michael Addition Organocatalyzed by α,β-Dipeptides under Solvent-Free Reaction Conditions.Dienamine and Friedel-Crafts one-pot synthesis, and antitumor evaluation of diheteroarylalkanals.Metal-Catalyzed Asymmetric Michael Addition in Natural Product Synthesis.Squaramide-Catalyzed Asymmetric Reactions.Design of Selenium-Based Chiral Chemical Probes for Simultaneous Enantio- and Chemosensing of Chiral Carboxylic Acids with Remote Stereogenic Centers by NMR Spectroscopy.Generation of Complex Azabicycles and Carbobicycles from Two Simple Compounds in a Single Operation through a Metal-Free Six-Step Domino Reaction.Gold(I)-Mediated Thiourea Organocatalyst Activation: A Synergic Effect for Asymmetric Catalysis.Towards the total synthesis of keramaphidin B.Old tricks, new dogs: organocatalytic dienamine activation of α,β-unsaturated aldehydesAn Asymmetric Organocatalytic Quadruple Domino Reaction Employing a Vinylogous Friedel-Crafts/Michael/Michael/Aldol Condensation Sequence.A theoretical and experimental study of the effects of silyl substituents in enantioselective reactions catalyzed by diphenylprolinol silyl ether.Organocatalytic 1,4-conjugate addition of ascorbic acid to α,β-unsaturated aldehydes: bio-inspired total syntheses of leucodrin, leudrin and proposed structure of dilaspirolactone.Stereoselective synthesis of N-heterocycles through amine addition to nitroalkenes.Enantioselective synthesis of Amaryllidaceae alkaloids (+)-vittatine, (+)-epi-vittatine, and (+)-buphanisine.Asymmetric Michael reactions catalyzed by a highly efficient and recyclable quaternary ammonium ionic liquid-supported organocatalyst in aqueous media.Bifunctional Tripeptide with a Phosphonic Acid as a Brønsted Acid for Michael Addition: Mechanistic Insights.Double Catalytic Kinetic Resolution (DoCKR) of Acyclic anti-1,3-Diols: The Additive Horeau Amplification.Enantioselective Brønsted Acid Catalysis as a Tool for the Synthesis of Natural Products and Pharmaceuticals.Jørgensen-Hayashi catalysts supported on poly(ethylene glycol)s as highly efficient and reusable organocatalysts for the enamine-catalyzed asymmetric Michael reaction.Hydrogen-Bonding Network Promoted [3+2] Cycloaddition: Asymmetric Catalytic Construction of Spiro-pseudoindoxyl Derivatives.(16) O/(18) O Exchange of Aldehydes and Ketones caused by H2 (18) O in the Mechanistic Investigation of Organocatalyzed Michael, Mannich, and Aldol Reactions.An unprecedented protocol for the synthesis of 3-hydroxy-3-phenacyloxindole derivatives with indolin-2-ones and α-substituted ketones.Highly efficient C-H hydroxylation of carbonyl compounds with oxygen under mild conditions.Total syntheses of mitragynine, paynantheine and speciogynine via an enantioselective thiourea-catalysed Pictet-Spengler reaction.Enantioselective syntheses of corynanthe alkaloids by chiral Brønsted acid and palladium catalysis.The Diarylprolinol Silyl Ethers: Ten Years After.Origin of the enantioselectivity in organocatalytic Michael additions of β-ketoamides to α,β-unsaturated carbonyls: a combined experimental, spectroscopic and theoretical study.Catalytic enantioselective Michael addition of α-aryl-α-isocyanoacetates to vinyl selenone: synthesis of α,α-disubstituted α-amino acids and (+)- and (-)-trigonoliimine A.N-trifluoromethylthiophthalimide: a stable electrophilic SCF3 -reagent and its application in the catalytic asymmetric trifluoromethylsulfenylation.Core-Scaffold-Inspired Asymmetric Synthesis of Polysubstituted Chiral Hexahydropyridazines that Potently Inhibit Breast Cancer Cell Proliferation by Inducing Apoptosis.Oxadendralenes in asymmetric organocatalysis for the construction of tetrahydroisochromenes.Evolution of asymmetric organocatalysis: multi- and retrocatalysis
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P2860
Asymmetric organocatalysis in total synthesis--a trial by fire.
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
@pt
bilimsel makale
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scientific article published on 06 May 2010
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Asymmetric organocatalysis in total synthesis--a trial by fire.
@en
Asymmetric organocatalysis in total synthesis--a trial by fire.
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type
label
Asymmetric organocatalysis in total synthesis--a trial by fire.
@en
Asymmetric organocatalysis in total synthesis--a trial by fire.
@nl
prefLabel
Asymmetric organocatalysis in total synthesis--a trial by fire.
@en
Asymmetric organocatalysis in total synthesis--a trial by fire.
@nl
P2093
P2860
P356
P1476
Asymmetric organocatalysis in total synthesis--a trial by fire.
@en
P2093
Eugenia Marqués-López
Mathias Christmann
Raquel P Herrera
P2860
P304
P356
10.1039/B924964H
P577
2010-05-06T00:00:00Z