Stereoselective transition metal-catalysed higher-order carbocyclisation reactions.
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Computational ligand design in enantio- and diastereoselective ynamide [5+2] cycloisomerization.Mechanism and Reactivity of Rh-Catalyzed Intermolecular [5+1] Cycloaddition of 3-Acyloxy-1,4-Enyne (ACE) and CO: A Computational Study.Gold(I)-catalyzed enantioselective cycloaddition reactions.Alkenes in [2+2+2] Cycloadditions.Mechanistic understanding of alkyne cyclotrimerization on mononuclear and dinuclear scaffolds: [4 + 2] cycloaddition of the third alkyne onto metallacyclopentadienes and dimetallacyclopentadienes.Radical cascade cyclization of 1,n-enynes and diynes for the synthesis of carbocycles and heterocycles.3-Acyloxy-1,4-enyne: a New Five-carbon Synthon for Rhodium-Catalyzed (5+2) CycloadditionsThe origin of the ligand-controlled regioselectivity in Rh-catalyzed [(2 + 2) + 2] carbocyclizations: steric vs. stereoelectronic effects.New Initiation Modes for Directed Carbonylative C-C Bond Activation: Rhodium-Catalyzed (3 + 1 + 2) Cycloadditions of Aminomethylcyclopropanes.Rhodium-Catalyzed Intermolecular [5+1] and [5+2] Cycloadditions Using 1,4-Enynes with an Electron-Donating Ester on the 3-Position.Rhodium-catalyzed carbonylation of cyclopropyl substituted propargyl esters: a tandem 1,3-acyloxy migration [5 + 1] cycloaddition.Rhodium-catalyzed intra- and intermolecular [5 + 2] cycloaddition of 3-acyloxy-1,4-enyne and alkyne with concomitant 1,2-acyloxy migrationRhodium-catalyzed 1,3-acyloxy migration and subsequent intramolecular [4+2] cycloaddition of vinylallene and unactivated alkyne.Nickel-catalyzed intramolecular [3 + 2 + 2] cycloadditions of alkylidenecyclopropanes. A straightforward entry to fused 6,7,5-tricyclic systems.Highly Regioselective Synthesis of Substituted Isoindolinones via Ruthenium-Catalyzed Alkyne Cyclotrimerizations.Intermolecular oxidative decarbonylative [2 + 2 + 2] carbocyclization of N-(2-ethynylaryl)acrylamides with tertiary and secondary alkyl aldehydes involving C(sp3)-H functionalization.Unpredictable cycloisomerization of 1,11-dien-6-ynes by a common cobalt catalyst.Rhodium-catalyzed carbonylation of 3-acyloxy-1,4-enynes for the synthesis of cyclopentenones.Rhodium-catalyzed tandem annulation and (5 + 1) cycloaddition: 3-hydroxy-1,4-enyne as the 5-carbon component.Catalytic asymmetric 1,3-dipolar cycloaddition of two different ylides: facile access to chiral 1,2,4-triazinane frameworks.Gold-catalyzed formal cycloaddition of 2-ethynylbenzyl ethers with organic oxides and α-diazoesters.Alkynes as Electrophilic or Nucleophilic Allylmetal Precursors in Transition-Metal Catalysis.Reaction of [TpRh(C2 H4 )2 ] with Dimethyl Acetylenedicarboxylate: Identification of Intermediates of the [2+2+2] Alkyne and Alkyne-Ethylene Cyclo(co)trimerizations.Diversity in Gold-Catalyzed Formal Cycloadditions of Ynamides with Azidoalkenes or 2H-Azirines: [3+2] versus [4+3] Cycloadditions.Stereoselective nickel-catalyzed [2+2+2] cycloadditions and alkenylative cyclizations of ene-allenes and alkenes.Atroposelective [2+2+2] cycloadditions catalyzed by a rhodium(I)-chiral phosphate system.Rhodium-catalyzed [(3+2)+2] carbocyclization of alkynylidenecyclopropanes with substituted allenes: stereoselective construction of tri- and tetrasubstituted exocyclic olefins.Palladium-catalyzed dearomatizative [2 + 2 + 1] carboannulation of 1,7-enynes with aryl diazonium salts and H2O: facile synthesis of spirocyclohexadienone-fused cyclopenta[c]quinolin-4(5H)-ones.Copper-promoted [2+2+2] annulation of 1,n-enynes through decomposition of azobis(alkyl nitrile)s.Intramolecular [2+2+2] cycloaddition of bis(propargylphenyl)carbodiimides: synthesis of L-shaped π-extended compounds with pyrrolo[1,2-a][1,8]naphthyridine corner units.Rh-catalysed [5 + 1] cycloaddition of allenylcyclopropanes and CO: reaction development and application to the formal synthesis of (-)-galanthamine.Copper-catalyzed oxidative [2+2+1] annulation of 1,n-enynes with α-carbonyl alkyl bromides through C-Br/C-H functionalization.Palladium(0)-catalyzed [2 + 2 + 1] cyclization of 1,6-enynes with vinyl bromides: a highly diastereoselective synthesis of tetrahydro-1H-cyclopenta[c]furans bearing two quaternary carbon centers.Rhodium(I)-catalyzed cyclization of allenynes with a carbonyl group through unusual insertion of a C-O bond into a rhodacycle intermediate.Gold-catalyzed formal [4π + 2π]-cycloadditions of propiolate derivatives with unactivated nitriles.Highly Enantioselective Catalytic [6+3] Cycloadditions of Azomethine YlidesRadical Cascade Cyclization: Reaction of 1,6-Enynes with Aryl Radicals by Electron CatalysisMechanism and origins of selectivity in rhodium-catalyzed intermolecular [3 + 2] cycloadditions of vinylaziridines with allenesMechanism and Origins of Ligand-Controlled Selectivity of Rhodium-Catalyzed Intermolecular Cycloadditions of Vinylaziridines with Alkynes
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P2860
Stereoselective transition metal-catalysed higher-order carbocyclisation reactions.
description
article científic
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article scientifique
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articolo scientifico
@it
artigo científico
@pt
bilimsel makale
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scientific article published on 27 May 2010
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Stereoselective transition metal-catalysed higher-order carbocyclisation reactions.
@en
Stereoselective transition metal-catalysed higher-order carbocyclisation reactions.
@nl
type
label
Stereoselective transition metal-catalysed higher-order carbocyclisation reactions.
@en
Stereoselective transition metal-catalysed higher-order carbocyclisation reactions.
@nl
prefLabel
Stereoselective transition metal-catalysed higher-order carbocyclisation reactions.
@en
Stereoselective transition metal-catalysed higher-order carbocyclisation reactions.
@nl
P356
P1476
Stereoselective transition metal-catalysed higher-order carbocyclisation reactions.
@en
P2093
P Andrew Evans
Phillip A Inglesby
P304
P356
10.1039/B913110H
P577
2010-05-27T00:00:00Z