Rhodium-catalyzed intra- and intermolecular [5 + 2] cycloaddition of 3-acyloxy-1,4-enyne and alkyne with concomitant 1,2-acyloxy migration
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Rhodium-catalyzed acyloxy migration of propargylic esters in cycloadditions, inspiration from the recent "gold rush"Catalytic Efficiency Is a Function of How Rhodium(I) (5 + 2) Catalysts Accommodate a Conserved Substrate Transition State Geometry: Induced Fit Model for Explaining Transition Metal Catalysis.Computational Prediction of One-Step Synthesis of Seven-membered Fused Rings by (5+2) Cycloaddition Utilising Cycloalkenes.Synthesis of Substituted Tropones by Sequential Rh-Catalyzed [5+2] Cycloaddition and EliminationEffect of ester on rhodium-catalyzed intermolecular [5+2] cycloaddition of 3-acyloxy-1,4-enynes and alkynes.New Approaches to the Synthesis of Metal Carbenes.3-Acyloxy-1,4-enyne: a New Five-carbon Synthon for Rhodium-Catalyzed (5+2) CycloadditionsRhodium-catalyzed chemo- and regioselective cross-dimerization of two terminal alkynes.Rhodium-Catalyzed Intermolecular [5+1] and [5+2] Cycloadditions Using 1,4-Enynes with an Electron-Donating Ester on the 3-Position.Generation of rhodium(I) carbenes from ynamides and their reactions with alkynes and alkenesRhodium-catalyzed carbonylation of cyclopropyl substituted propargyl esters: a tandem 1,3-acyloxy migration [5 + 1] cycloaddition.Rhodium(I)-Catalyzed Benzannulation of Heteroaryl Propargylic Esters: Synthesis of Indoles and Related Heterocycles.Rh-catalyzed (5+2) cycloadditions of 3-acyloxy-1,4-enynes and alkynes: computational study of mechanism, reactivity, and regioselectivity.Transfer of chirality in the rhodium-catalyzed intramolecular [5+2] cycloaddition of 3-acyloxy-1,4-enynes (ACEs) and alkynes: synthesis of enantioenriched bicyclo[5.3.0]decatrienes.Rhodium-Catalyzed Stereoselective Intramolecular [5 + 2] Cycloaddition of 3-Acyloxy 1,4-Enyne and Alkene.Rhodium-catalyzed tandem annulation and (5 + 1) cycloaddition: 3-hydroxy-1,4-enyne as the 5-carbon component.Rhodium- and platinum-catalyzed [4+3] cycloaddition with concomitant indole annulation: synthesis of cyclohepta[b]indoles.Divergent Reactivity of Rhodium(I) Carbenes Derived from Indole Annulations.Rhodium-Catalyzed Intramolecular [5+2] Cycloaddition of Inverted 3-Acyloxy-1,4-enyne and Alkyne: Experimental and Theoretical Studies.Rhodium(I)-catalyzed cycloisomerization of benzylallene-alkynes through C-H activation.Rhodium(I)-Catalyzed Bridged [5+2] Cycloaddition of cis-Allene-vinylcyclopropanes to Synthesize the Bicyclo[4.3.1]decane Skeleton.Transition metal mediated carbonylative benzannulations.Triflic Acid-Catalyzed Enynes Cyclization: A New Strategy beyond Electrophilic π-Activation.Modular Access to the Stereoisomers of Fused Bicyclic Azepines: Rhodium-Catalyzed Intramolecular Stereospecific Hetero-[5+2] Cycloaddition of Vinyl Aziridines and Alkenes.Gold-catalyzed 1,2-acyloxy migration/intramolecular [3+2] 1,3-dipolar cycloaddtion cascade reaction: an efficient strategy for syntheses of medium-sized-ring ethers and amines.Hexafluoroantimonic acid catalysis: formal [3+2+2] cycloaddition of aziridines with two alkynes.Rhodium(I)-catalyzed cyclization of allenynes with a carbonyl group through unusual insertion of a C-O bond into a rhodacycle intermediate.Synthesis of Secondary Unsaturated Lactams via an Aza-Heck Reaction.
P2860
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P2860
Rhodium-catalyzed intra- and intermolecular [5 + 2] cycloaddition of 3-acyloxy-1,4-enyne and alkyne with concomitant 1,2-acyloxy migration
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
2012年论文
@zh
2012年论文
@zh-cn
name
Rhodium-catalyzed intra- and i ...... comitant 1,2-acyloxy migration
@en
type
label
Rhodium-catalyzed intra- and i ...... comitant 1,2-acyloxy migration
@en
prefLabel
Rhodium-catalyzed intra- and i ...... comitant 1,2-acyloxy migration
@en
P2093
P2860
P356
P1476
Rhodium-catalyzed intra- and i ...... comitant 1,2-acyloxy migration
@en
P2093
Casi M Schienebeck
Dongxu Shu
Patrick J Robichaux
Suyu Huang
Weiping Tang
Xiaoxun Li
Xing-Zhong Shu
P2860
P304
P356
10.1021/JA2109097
P407
P577
2012-03-12T00:00:00Z