Catalytic C-H functionalization by metalloporphyrins: recent developments and future directions.
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Porphyrins as Catalysts in Scalable Organic ReactionsEnzymatic C(sp(3))-H Amination: P450-Catalyzed Conversion of Carbonazidates into Oxazolidinones.Combined C-H functionalization/Cope rearrangement with vinyl ethers as a surrogate for the vinylogous Mukaiyama aldol reaction.The combined C-H functionalization/Cope rearrangement: discovery and applications in organic synthesis.Characterization of Porphyrin-Co(III)-'Nitrene Radical' Species Relevant in Catalytic Nitrene Transfer Reactions.Development of a Suzuki cross-coupling reaction between 2-azidoarylboronic pinacolate esters and vinyl triflates to enable the synthesis of [2,3]-fused indole heterocycles.Enantioselective intramolecular C-H amination catalyzed by engineered cytochrome P450 enzymes in vitro and in vivo.Versatile reactivity of Pd-catalysts: mechanistic features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed C-H bond functionalization.Applications of metal-organic frameworks in heterogeneous supramolecular catalysis.Transition metal-catalyzed ketone-directed or mediated C-H functionalization.The nature of chemical innovation: new enzymes by evolution.Trends in applying C-H oxidation to the total synthesis of natural products.Tunable differentiation of tertiary C-H bonds in intramolecular transition metal-catalyzed nitrene transfer reactions.The past, present, and future of the Yang reaction.Metal-Catalysed Azidation of Organic MoleculesApplications of Nonenzymatic Catalysts to the Alteration of Natural Products.Spin-Selective Generation of Triplet Nitrenes: Olefin Aziridination through Visible-Light Photosensitization of AzidoformatesCobalt-Porphyrin-Catalysed Intramolecular Ring-Closing C-H Amination of Aliphatic Azides: A Nitrene-Radical Approach to Saturated Heterocycles.Intramolecular Radical Aziridination of Allylic Sulfamoyl Azides by Cobalt(II)-Based Metalloradical Catalysis: Effective Construction of Strained Heterobicyclic Structures.Rh-catalyzed intermolecular reactions of cyclic α-diazocarbonyl compounds with selectivity over tertiary C-H bond migration.Rh(2)(S-PTTL)(3)TPA-A Mixed Ligand Dirhodium(II) Catalyst for Enantioselective Reactions of α-Alkyl-α-Diazoesters.Synthesis of chiral N-phosphoryl aziridines through enantioselective aziridination of alkenes with phosphoryl azide via Co(II)-based metalloradical catalysis.Room Temperature Activation of Aryloxysulfonyl Azides by [Co(II)(TPP)] for Selective Radical Aziridination of Alkenes via Metalloradical Catalysis.Metalloradical activation of α-formyldiazoacetates for the catalytic asymmetric radical cyclopropanation of alkenes.Effective synthesis of chiral N-fluoroaryl aziridines through enantioselective aziridination of alkenes with fluoroaryl azides.Cobalt-catalysed site-selective intra- and intermolecular dehydrogenative amination of unactivated sp(3) carbons.The influence of heme ruffling on spin densities in ferricytochromes c probed by heme core 13C NMR.Intramolecular 1,5-C(sp3)-H Radical Amination via Co(II)-Based Metalloradical Catalysis for Five-Membered Cyclic Sulfamides.Enhancing the reactivity of nickel(ii) in hydrogen evolution reactions (HERs) by β-hydrogenation of porphyrinoid ligands.Stereoselective radical amination of electron-deficient C(sp3)-H bonds by Co(II)-based metalloradical catalysis: direct synthesis of α-amino acid derivatives via α-C-H amination.Selective Radical Amination of Aldehydic C(sp(2))-H Bonds with Fluoroaryl Azides via Co(II)-Based Metalloradical Catalysis: Synthesis of N-Fluoroaryl Amides from Aldehydes under Neutral and Nonoxidative Conditions.Chemoselective amination of propargylic C(sp³)-H bonds by cobalt(II)-based metalloradical catalysisStereoselective Radical C-H Alkylation with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis.Aerobic oxidative N-dealkylation of tertiary amines in aqueous solution catalyzed by rhodium porphyrins.Ag-promoted azido-carbocyclization of activated alkenes via C-H bond cleavage.A Cost-Efficient Method for Unsymmetrical Meso-Aryl Porphyrin Synthesis Using NaY Zeolite as an Inorganic Acid Catalyst.Efficient epoxidation of olefins by H2O2 catalyzed by iron "helmet" phthalocyanines.Copper-catalyzed annulation of amidines for quinazoline synthesis.Electronic tuning of iron-oxo-mediated C-H activation: effect of electron-donating ligand on selectivity.PdCl2 and N-hydroxyphthalimide co-catalyzed C(sp2)-H hydroxylation by dioxygen activation.
P2860
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P2860
Catalytic C-H functionalization by metalloporphyrins: recent developments and future directions.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年学术文章
@wuu
2010年学术文章
@zh-cn
2010年学术文章
@zh-hans
2010年学术文章
@zh-my
2010年学术文章
@zh-sg
2010年學術文章
@yue
2010年學術文章
@zh
2010年學術文章
@zh-hant
name
Catalytic C-H functionalizatio ...... opments and future directions.
@en
Catalytic C-H functionalizatio ...... opments and future directions.
@nl
type
label
Catalytic C-H functionalizatio ...... opments and future directions.
@en
Catalytic C-H functionalizatio ...... opments and future directions.
@nl
prefLabel
Catalytic C-H functionalizatio ...... opments and future directions.
@en
Catalytic C-H functionalizatio ...... opments and future directions.
@nl
P2860
P356
P1476
Catalytic C-H functionalizatio ...... opments and future directions.
@en
P2093
Hongjian Lu
X Peter Zhang
P2860
P304
P356
10.1039/C0CS00070A
P577
2010-11-19T00:00:00Z