Cobalt(II)-Catalyzed Intramolecular C−H Amination with Phosphoryl Azides: Formation of 6- and 7-Membered Cyclophosphoramidates
about
Recent advances in transition metal-catalyzed N-atom transfer reactions of azidesRuthenium-catalyzed γ-carbolinium ion formation from aryl azides; synthesis of dimebolin.Rh2(II)-catalyzed intramolecular aliphatic C-H bond amination reactions using aryl azides as the N-atom sourceHomolytic N-H activation of ammonia: hydrogen transfer of parent iridium ammine, amide, imide, and nitride species.Characterization of Porphyrin-Co(III)-'Nitrene Radical' Species Relevant in Catalytic Nitrene Transfer Reactions.Iron(II) bromide-catalyzed intramolecular C-H bond amination [1,2]-shift tandem reactions of aryl azides.Catalytic C-H functionalization by metalloporphyrins: recent developments and future directions.Selective functionalisation of saturated C-H bonds with metalloporphyrin catalysts.Complexes with nitrogen-centered radical ligands: classification, spectroscopic features, reactivity, and catalytic applications.Catalytic Synthesis of N-Heterocycles via Direct C(sp3)-H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand.Intramolecular Radical Aziridination of Allylic Sulfamoyl Azides by Cobalt(II)-Based Metalloradical Catalysis: Effective Construction of Strained Heterobicyclic Structures.Metal-Catalyzed and Metal-Free Intermolecular Amination of Light Alkanes and BenzenesCobalt-Catalyzed, Aminoquinoline-Directed Functionalization of Phosphinic Amide sp2 C-H Bonds.Rhodium-catalyzed synthesis of 2,3-disubstituted indoles from β,β-disubstituted stryryl azides.Intramolecular 1,5-C(sp3)-H Radical Amination via Co(II)-Based Metalloradical Catalysis for Five-Membered Cyclic Sulfamides.Stereoselective radical amination of electron-deficient C(sp3)-H bonds by Co(II)-based metalloradical catalysis: direct synthesis of α-amino acid derivatives via α-C-H amination.Selective Radical Amination of Aldehydic C(sp(2))-H Bonds with Fluoroaryl Azides via Co(II)-Based Metalloradical Catalysis: Synthesis of N-Fluoroaryl Amides from Aldehydes under Neutral and Nonoxidative Conditions.Chemoselective amination of propargylic C(sp³)-H bonds by cobalt(II)-based metalloradical catalysisNitrene Radical Intermediates in Catalytic Synthesis.Porphyrin Cobalt(III) "Nitrene Radical" Reactivity; Hydrogen Atom Transfer from Ortho-YH Substituents to the Nitrene Moiety of Cobalt-Bound Aryl Nitrene Intermediates (Y = O, NH).Asymmetric nitrene transfer reactions: sulfimidation, aziridination and C-H amination using azide compounds as nitrene precursors.Cobalt catalyzed sp3 C-H amination utilizing aryl azides.Iron-catalyzed C-H and C-C bond cleavage: a direct approach to amides from simple hydrocarbons.The radical mechanism of cobalt(II) porphyrin-catalyzed olefin aziridination and the importance of cooperative H-bonding.Enantio- and regioselective intermolecular benzylic and allylic C-H bond amination.Palladium-catalyzed, aminoquinoline-directed arylation of phosphonamidate and phosphinic amide sp3 C-H bonds.Chemoselective intramolecular allylic C–H amination versus CC aziridination through Co(ii)-based metalloradical catalysisComparative Study of the Catalytic Amination of Benzylic C-H Bonds Promoted by Ru(TPP)(py)2and Ru(TPP)(CO)Insights into the Mechanism of the Ruthenium-Porphyrin-Catalysed Allylic Amination of Olefins by Aryl Azides[Ru(TPP)CO]-Catalysed Intramolecular Benzylic CH Bond Amination, Affording Phenanthridine and Dihydrophenanthridine DerivativesRuthenium porphyrins-catalyzed atom-efficient amination of C-H bonds by arylazides
P2860
Q34985186-7B97FD4C-52FC-4646-8491-A31D036F3573Q34989553-1A8CF5B3-F8E2-4D2B-8049-5A5406AC2B80Q36098151-DDAAA7AC-D976-461C-831A-B3547A4EA9A4Q36134408-C81D526A-0BD2-4AB3-BFA3-C6FAD0E354BDQ36570787-3C251C77-ED2C-4413-AF5A-EB54F773A383Q36754682-91A30F07-4B22-4405-89ED-B994613220D0Q37810785-76CFC379-D68D-4330-9DBF-87518F378210Q37851029-76988B23-CF61-4F7B-BB2B-34324999C3D9Q38161491-2AF0CCFE-A731-4709-B0A1-669CF9982918Q38905373-12282FE8-24F8-45AF-9012-F875B1F0DCC5Q41036037-07DF4748-E074-44B4-96F5-7E72A662A139Q41533589-3F77EBFF-3722-4018-8E71-A37E7C14E1F5Q41784519-29C0A159-B830-4622-988E-6BF6550A75FFQ42061881-2AC607A9-978C-4F27-BEBE-63A42F1BE57CQ42327546-E856048B-4E35-40B3-9405-152F8D9DA455Q42453687-646BDE08-82C9-489A-88D1-AF1D314ED833Q42749237-1CEA9E54-234B-482C-94A1-556E26CBBD8FQ42764343-0A4DEE13-5953-4DA9-8763-622AAAF44F4FQ43129522-CAE0FCB3-F80C-4D75-A301-95AD7814EB13Q46591390-5B7592E3-370B-4C34-8C48-BCB543302186Q46943397-604BD10A-28DC-4207-9840-79033108A1F9Q49466223-A69FF4D3-F3C8-40B3-BBDB-D3AF73E8A08EQ53207791-A61F4619-5E7C-4112-9F8F-3430893D4111Q53429611-5353B081-BA94-4ECD-912B-9558B8CEF5E9Q54771939-3460DD85-4D0B-4458-8029-FEDBFC33EE4BQ55076303-E0EF9E6F-24F7-49AE-A5C9-CCB7AAA19429Q57834047-AC58001F-EE51-4F44-BA9E-CC3F43C24C51Q59078951-B7D1B4DF-FFE0-4833-8806-2926304577ADQ59079305-EB5E5729-6585-4796-800C-91522D5B831AQ59079361-363D928D-E44C-4D84-8147-25D6E01C1931Q59079550-2DCECD74-2F9A-4338-A212-F90EC12F8C76
P2860
Cobalt(II)-Catalyzed Intramolecular C−H Amination with Phosphoryl Azides: Formation of 6- and 7-Membered Cyclophosphoramidates
description
im März 2010 veröffentlichter wissenschaftlicher Artikel
@de
наукова стаття, опублікована в березні 2010
@uk
name
Cobalt(II)-Catalyzed Intramole ...... Membered Cyclophosphoramidates
@en
type
label
Cobalt(II)-Catalyzed Intramole ...... Membered Cyclophosphoramidates
@en
prefLabel
Cobalt(II)-Catalyzed Intramole ...... Membered Cyclophosphoramidates
@en
P2093
P356
P1433
P1476
Cobalt(II)-Catalyzed Intramole ...... Membered Cyclophosphoramidates
@en
P2093
Hongjian Lu
Jess E. Jones
Jingran Tao
P304
P356
10.1021/OL100110Z
P407
P577
2010-03-19T00:00:00Z