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Intermolecular Ritter-type C-H amination of unactivated sp3 carbons.Catalytic Enantioselective Allylic Amination of Olefins for the Synthesis of ent-Sitagliptin.Combined C-H functionalization/Cope rearrangement with vinyl ethers as a surrogate for the vinylogous Mukaiyama aldol reaction.Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds.Catalytic enantioselective allylic amination of unactivated terminal olefins via an ene reaction/[2,3]-rearrangementAn investigation of the observed, but counter-intuitive, stereoselectivity noted during chiral amine synthesis via N-chiral-ketimines.Enantioselective functionalization of allylic C-H bonds following a strategy of functionalization and diversification.Development of a Suzuki cross-coupling reaction between 2-azidoarylboronic pinacolate esters and vinyl triflates to enable the synthesis of [2,3]-fused indole heterocycles.Making expensive dirhodium(II) catalysts cheaper: Rh(II) recycling methods.sp3 C-H oxidation by remote H-radical shift with oxygen- and nitrogen-radicals: a recent update.Trends in applying C-H oxidation to the total synthesis of natural products.Copper-catalyzed oxidative carbon-heteroatom bond formation: a recent update.Tunable differentiation of tertiary C-H bonds in intramolecular transition metal-catalyzed nitrene transfer reactions.The past, present, and future of the Yang reaction.Transition-Metal-Catalyzed Electrophilic Amination: Application of O-Benzoylhydroxylamines in the Construction of the C-N Bond.Recent advances in rhodium-catalyzed asymmetric synthesis of heterocycles.Tunable, chemoselective amination via silver catalysis.Metal-Catalyzed and Metal-Free Intermolecular Amination of Light Alkanes and BenzenesAllylic amination and N-arylation-based domino reactions providing rapid three-component strategies to fused pyrroles with different substituted patterns.Intramolecular 1,5-C(sp3)-H Radical Amination via Co(II)-Based Metalloradical Catalysis for Five-Membered Cyclic Sulfamides.A unified photoredox-catalysis strategy for C(sp3)-H hydroxylation and amidation using hypervalent iodineSelective Radical Amination of Aldehydic C(sp(2))-H Bonds with Fluoroaryl Azides via Co(II)-Based Metalloradical Catalysis: Synthesis of N-Fluoroaryl Amides from Aldehydes under Neutral and Nonoxidative Conditions.Chemoselective amination of propargylic C(sp³)-H bonds by cobalt(II)-based metalloradical catalysisLigand-controlled, tunable silver-catalyzed C-H amination.Site-selective catalytic C(sp2)-H bond azidations.Metal-free, highly efficient organocatalytic amination of benzylic C-H bonds.Copper-catalyzed annulation of amidines for quinazoline synthesis.Group transfer reactions of d0 transition metal complexes: redox-active ligands provide a mechanism for expanded reactivity.Enantioselective, intermolecular benzylic C-H amination catalysed by an engineered iron-haem enzyme.Catalytic C-H amination driven by intramolecular ligand-to-nitrene one-electron transfer through a rhodium(iii) centre.Visible-light-mediated, nitrogen-centered radical amination of tertiary alkyl halides under metal-free conditions to form α-tertiary amines.Iodine-Catalyzed Decarboxylative Amidation of β,γ-Unsaturated Carboxylic Acids with Chloramine Salts Leading to Allylic Amides.First principles (DFT) characterization of Rh(I) /dppp-catalyzed C-H activation by tandem 1,2-addition/1,4-Rh shift reactions of norbornene to phenylboronic acid.Opening an Aladdin's cave: the Suzuki coupling in a room-temperature ionic liquid.Complementary Strategies for Directed C(sp3 )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer.Manganese(iii) acetate catalyzed oxidative amination of benzylic C(sp3)-H bonds with nitriles.Chemo- and Enantioselective Intramolecular Silver-Catalyzed Aziridinations.Visible-Light-Induced Direct Oxidative C-H Amidation of Heteroarenes with Sulfonamides.Radical-mediated intramolecular β-C(sp3)-H amidation of alkylimidates: facile synthesis of 1,2-amino alcohols.Formal Direct Cross-Coupling of Phenols with Amines.
P2860
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description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on 13 January 2011
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
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vědecký článek
@cs
name
Catalytic C-H amination: the stereoselectivity issue.
@en
Catalytic C-H amination: the stereoselectivity issue.
@nl
type
label
Catalytic C-H amination: the stereoselectivity issue.
@en
Catalytic C-H amination: the stereoselectivity issue.
@nl
prefLabel
Catalytic C-H amination: the stereoselectivity issue.
@en
Catalytic C-H amination: the stereoselectivity issue.
@nl
P2093
P356
P1476
Catalytic C-H amination: the stereoselectivity issue.
@en
P2093
Camille Lescot
Florence Collet
Philippe Dauban
P304
P356
10.1039/C0CS00095G
P577
2011-01-13T00:00:00Z