Group transfer reactions of d0 transition metal complexes: redox-active ligands provide a mechanism for expanded reactivity.
about
Redox non-innocence permits catalytic nitrene carbonylation by (dadi)Ti[double bond, length as m-dash]NAd (Ad = adamantyl)Dioxygen reactivity of biomimetic Fe(II) complexes with noninnocent catecholate, o-aminophenolate, and o-phenylenediamine ligands.Trianionic pincer and pincer-type metal complexes and catalysts.New avenues for ligand-mediated processes--expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands.Homoleptic nickel(II) complexes of redox-tunable pincer-type ligands.Arene C-H amination at nickel in terphenyl-diphosphine complexes with labile metal-arene interactionsControlled Interconversion of a Dinuclear Au Species Supported by a Redox-Active Bridging PNP Ligand Facilitates Ligand-to-Gold Electron Transfer.Theoretical mechanism studies on the competitive CO-induced N-N bond cleavage of N2O with N-O bond cleavage mediated by (η5-C5Me5)Mo[N((i)Pr)C(Me)N((i)Pr)](CO)2.C-H functionalization: thoroughly tuning ligands at a metal ion, a chemist can greatly enhance catalyst's activity and selectivity.Redox and anion exchange chemistry of a stibine-nickel complex: writing the L, X, Z ligand alphabet with a single element.Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine.Generation of TiII Alkyne Trimerization Catalysts in the Absence of Strong Metal Reductants.Catalytic C-H amination driven by intramolecular ligand-to-nitrene one-electron transfer through a rhodium(iii) centre.RhCl(PPh3)3-mediated C-H oxyfunctionalization of pyrrolido-functionalized bisazoaromatic pincers: a combined experimental and theoretical scrutiny of redox-active and spectroscopic properties.Catalytic formal [2+2+1] synthesis of pyrroles from alkynes and diazenes via Ti(II)/Ti(IV) redox catalysis.Harnessing redox activity for the formation of uranium tris(imido) compounds.Triggering Redox Activity in a Thiophene Compound: Radical Stabilization and Coordination Chemistry.Multi-electron redox processes at a Zr(iv) center facilitated by an appended redox-active cobalt-containing metalloligand.Interactions between the trianionic ligand-centred redox-active metalloligand [Cr(III)(perfluorocatecholato)3](3-) and guest metal ions.
P2860
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P2860
Group transfer reactions of d0 transition metal complexes: redox-active ligands provide a mechanism for expanded reactivity.
description
2013 nî lūn-bûn
@nan
2013年の論文
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2013年学术文章
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2013年学术文章
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2013年学术文章
@zh-hans
2013年学术文章
@zh-my
2013年学术文章
@zh-sg
2013年學術文章
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2013年學術文章
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2013年學術文章
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name
Group transfer reactions of d0 ...... anism for expanded reactivity.
@en
Group transfer reactions of d0 ...... anism for expanded reactivity.
@nl
type
label
Group transfer reactions of d0 ...... anism for expanded reactivity.
@en
Group transfer reactions of d0 ...... anism for expanded reactivity.
@nl
prefLabel
Group transfer reactions of d0 ...... anism for expanded reactivity.
@en
Group transfer reactions of d0 ...... anism for expanded reactivity.
@nl
P2093
P2860
P356
P1433
P1476
Group transfer reactions of d0 ...... anism for expanded reactivity.
@en
P2093
Alan F Heyduk
Rui F Munhá
Ryan A Zarkesh
P2860
P304
P356
10.1039/C2DT32063K
P407
P577
2013-01-18T00:00:00Z