Biosynthesis via carbocations: theoretical studies on terpene formation.
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Dynamic behavior of rearranging carbocations - implications for terpene biosynthesisLeveraging structure for enzyme function prediction: methods, opportunities, and challengesDefining the Product Chemical Space of Monoterpenoid SynthasesApplication of Computational Chemical Shift Prediction Techniques to the Cereoanhydride Structure Problem-Carboxylate Complications.Traversing the fungal terpenome.Sesquiterpene synthases: passive catalysts or active players?Electrophilic and nucleophilic enzymatic cascade reactions in biosynthesis.Predicting the functions and specificity of triterpenoid synthases: a mechanism-based multi-intermediate docking approach.Syntheses and biological studies of marine terpenoids derived from inorganic cyanide.Computational-guided discovery and characterization of a sesquiterpene synthase from Streptomyces clavuligerusExperimental and theoretical studies on the Nazarov cyclization/Wagner-Meerwein rearrangement sequence.Draft genome of Omphalotus olearius provides a predictive framework for sesquiterpenoid natural product biosynthesis in BasidiomycotaStructure of the ent-Copalyl Diphosphate Synthase PtmT2 from Streptomyces platensis CB00739, a Bacterial Type II Diterpene Synthase.Effect of isotopically sensitive branching on product distribution for pentalenene synthase: support for a mechanism predicted by quantum chemistryTerpenoid synthase structures: a so far incomplete view of complex catalysis.Mechanism-Based Post-Translational Modification and Inactivation in Terpene Synthases."Cation-Stitching Cascade": exquisite control of terpene cyclization in cyclooctatin biosynthesis.Probing the mechanism of 1,4-conjugate elimination reactions catalyzed by terpene synthasesIdentification of amino acid networks governing catalysis in the closed complex of class I terpene synthases.Caryolene-forming carbocation rearrangements.A cytochrome P450 serves as an unexpected terpene cyclase during fungal meroterpenoid biosynthesis.Carbonium vs. carbenium ion-like transition state geometries for carbocation cyclization - how strain associated with bridging affects 5-exo vs. 6-endo selectivity.From Molecular Phylogenetics to Quantum Chemistry: Discovering Enzyme Design Principles through Computation.Purification and biochemical characterization of recombinant Persicaria minor β-sesquiphellandrene synthase.Isoprenoids in three-dimensional space: the stereochemistry of terpene biosynthesis.Diterpenoids of terrestrial origin.Walking in the woods with quantum chemistry--applications of quantum chemical calculations in natural products research.How cyclobutanes are assembled in nature--insights from quantum chemistry.Lessons from the synthetic chemist nature.Carbocations and the Complex Flavor and Bouquet of Wine: Mechanistic Aspects of Terpene Biosynthesis in Wine Grapes.Bacterial terpene cyclases.Blocking Deprotonation with Retention of Aromaticity in a Plant ent-Copalyl Diphosphate Synthase Leads to Product Rearrangement.The type II isopentenyl Diphosphate:Dimethylallyl diphosphate isomerase (IDI-2): A model for acid/base chemistry in flavoenzyme catalysis.Diastereoselective Pt catalyzed cycloisomerization of polyenes to polycycles.Product Rearrangement from Altering a Single Residue in the Rice syn-Copalyl Diphosphate SynthaseThe energetic viability of an unexpected skeletal rearrangement in cyclooctatin biosynthesis.Structurally diverse hamigerans from the New Zealand marine sponge Hamigera tarangaensis: NMR-directed isolation, structure elucidation and antifungal activity.Dyotropic rearrangements in natural product total synthesis and biosynthesis.Computational studies on the cyclization of squalene to the steroids and hopenes.Recent applications of the 1,2-carbon atom migration strategy in complex natural product total synthesis.
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P2860
Biosynthesis via carbocations: theoretical studies on terpene formation.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on 04 May 2011
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
Biosynthesis via carbocations: theoretical studies on terpene formation.
@en
Biosynthesis via carbocations: theoretical studies on terpene formation.
@nl
type
label
Biosynthesis via carbocations: theoretical studies on terpene formation.
@en
Biosynthesis via carbocations: theoretical studies on terpene formation.
@nl
prefLabel
Biosynthesis via carbocations: theoretical studies on terpene formation.
@en
Biosynthesis via carbocations: theoretical studies on terpene formation.
@nl
P2860
P356
P1476
Biosynthesis via carbocations: theoretical studies on terpene formation
@en
P2093
Dean J Tantillo
P2860
P304
P356
10.1039/C1NP00006C
P577
2011-05-04T00:00:00Z