about
Dynamic behavior of rearranging carbocations - implications for terpene biosynthesisDesign and synthesis of propeller-shaped dispiroisoxazolinopiperidinochromanones.Matching active site and substrate structures for an RNA editing reaction.Application of Computational Chemical Shift Prediction Techniques to the Cereoanhydride Structure Problem-Carboxylate Complications.Stereocontrol in a combined allylic azide rearrangement and intramolecular Schmidt reactionA Fluorescent Adenosine Analogue as a Substrate for an A-to-I RNA Editing Enzyme.Effect of isotopically sensitive branching on product distribution for pentalenene synthase: support for a mechanism predicted by quantum chemistryTotal Synthesis of the Galbulimima Alkaloids Himandravine and GB17 Using Biomimetic Diels-Alder Reactions of Double Diene PrecursorsMechanistic studies of copper(I)-catalyzed 1,3-halogen migrationMulticomponent assembly of highly substituted indoles by dual palladium-catalyzed coupling reactionsA divergent approach to the synthesis of the yohimbinoid alkaloids venenatine and alstovenine.Caryolene-forming carbocation rearrangements.A cytochrome P450 serves as an unexpected terpene cyclase during fungal meroterpenoid biosynthesis.A gold-catalysed enantioselective Cope rearrangement of achiral 1,5-dienes.Short interfering RNA guide strand modifiers from computational screening.The carbocation continuum in terpene biosynthesis--where are the secondary cations?Biosynthesis via carbocations: theoretical studies on terpene formation.How cyclobutanes are assembled in nature--insights from quantum chemistry.Mechanism of a No-Metal-Added Heterocycloisomerization of Alkynylcyclopropylhydrazones: Synthesis of Cycloheptane-Fused Aminopyrroles Facilitated by Copper Salts at Trace Loadings.Cation-Controlled Enantioselective and Diastereoselective Synthesis of Indolines: An Autoinductive Phase-Transfer Initiated 5-endo-trig Process.Blocking Deprotonation with Retention of Aromaticity in a Plant ent-Copalyl Diphosphate Synthase Leads to Product Rearrangement.Synthesis and Utility of Dihydropyridine Boronic Esters.Acylammonium salts as dienophiles in Diels-Alder/lactonization organocascades.The energetic viability of an unexpected skeletal rearrangement in cyclooctatin biosynthesis.Snakes and ladders. The sigmatropic shiftamer concept.Total synthesis of oxidized welwitindolinones and (-)-N-methylwelwitindolinone C isonitrile.Biosynthesis of lycosantalonol, a cis-prenyl derived diterpenoid.A potential energy surface bifurcation in terpene biosynthesis.Differentiating mechanistic possibilities for the thermal, intramolecular [2 + 2] cycloaddition of allene-ynes.Formation of beyerene, kaurene, trachylobane, and atiserene diterpenes by rearrangements that avoid secondary carbocations.Transition-state complexation in palladium-promoted [3,3] sigmatropic shifts.Consequences of conformational preorganization in sesquiterpene biosynthesis: theoretical studies on the formation of the bisabolene, curcumene, acoradiene, zizaene, cedrene, duprezianene, and sesquithuriferol sesquiterpenes.Theoretical and experimental analysis of the reaction mechanism of MrTPS2, a triquinane-forming sesquiterpene synthase from chamomile.Complicated goings-on in the metal-manipulated ring-opening of cyclobutene.Transition state docking: a probe for noncovalent catalysis in biological systems. Application to antibody-catalyzed ester hydrolysis.The Importance of Methyl Positioning and Tautomeric Equilibria for Imidazole Nucleophilicity.Catalysis on the coastline: theozyme, molecular dynamics, and free energy perturbation analysis of antibody 21D8 catalysis of the decarboxylation of 5-nitro-3-carboxybenzisoxazole.Prospecting for a 5-center 4-electron (C- - -H- - -C- - -H- - -C)+ bonding array.Mechanism of Rh2(II)-Catalyzed Indole Formation: The Catalyst Does Not Control Product Selectivity.Correction: The energetic viability of an unexpected skeletal rearrangement in cyclooctatin biosynthesis.
P50
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P50
description
hulumtues
@sq
researcher
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ricercatore
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wetenschapper
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հետազոտող
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name
Dean J Tantillo
@en
Dean J Tantillo
@es
Dean J Tantillo
@nl
Dean J Tantillo
@sl
Dean J. Tantillo
@de
type
label
Dean J Tantillo
@en
Dean J Tantillo
@es
Dean J Tantillo
@nl
Dean J Tantillo
@sl
Dean J. Tantillo
@de
prefLabel
Dean J Tantillo
@en
Dean J Tantillo
@es
Dean J Tantillo
@nl
Dean J Tantillo
@sl
Dean J. Tantillo
@de
P227
P1960
ZPdDLjQAAAAJ
P21
P214
114149617065203751315
P227
1160630941
P31
P496
0000-0002-2992-8844
P569
2000-01-01T00:00:00Z
P734
P735
P7859
lccn-n2017029257