Transition metal-catalyzed C-H functionalization of N-oxyenamine internal oxidants.
about
Palladium-catalyzed Csp(2)-H carbonylation of aromatic oximes: selective access to benzo[d][1,2]oxazin-1-ones and 3-methyleneisoindolin-1-ones.Asymmetric Redox-Annulation of Cyclic Amines.O-Acyl oximes: versatile building blocks for N-heterocycle formation in recent transition metal catalysis.Redox-Annulation of Cyclic Amines and β-Ketoaldehydes.Metal-Catalyzed Annulations through Activation and Cleavage of C-H Bonds.Advances in the development of catalytic tethering directing groups for C-H functionalization reactions.C-H Activation and Alkyne Annulation via Automatic or Intrinsic Directing Groups: Towards High Step Economy.Intramolecular Redox-Mannich Reactions: Facile Access to the Tetrahydroprotoberberine Core.Merging Visible Light Photoredox Catalysis with Metal Catalyzed C-H Activations: On the Role of Oxygen and Superoxide Ions as Oxidants.C-H functionalization of cyclic amines: redox-annulations with α,β-unsaturated carbonyl compounds.An Ugi Reaction Incorporating a Redox-Neutral Amine C-H Functionalization StepAcetic Acid Promoted Redox Annulations with Dual C-H Functionalization.Rhodium(III)-Catalyzed Annulative Carbooxygenation of 1,1-Disubstituted Alkenes Triggered by C-H Activation.Computational Investigation of the Role Played by Rhodium(V) in the Rhodium(III)-Catalyzed ortho-Bromination of Arenes.Mechanism of the rhodium(iii)-catalyzed alkenylation reaction of N-phenoxyacetamide with styrene or N-tosylhydrazone: a computational study.Redox-Neutral Aromatization of Cyclic Amines: Mechanistic Insights and Harnessing of Reactive Intermediates for Amine α- and β-C-H Functionalization.Rh(V) -Nitrenoid as a Key Intermediate in Rh(III) -Catalyzed Heterocyclization by C-H Activation: A Computational Perspective on the Cycloaddition of Benzamide and Diazo Compounds.Copper-Catalyzed C(sp3 )-H/C(sp3 )-H Cross-Dehydrogenative Coupling with Internal Oxidants: Synthesis of 2-Trifluoromethyl-Substituted Dihydropyrrol-2-ols.Generation of Stable Ruthenium(IV) Ketimido Complexes by Oxidative Addition of Oxime Esters to Ruthenium(II): Reactivity Studies Based on Electronic Properties of the Ru-N Bond.Direct transformation of 2-acetylpyridine oxime esters into α-oxygenated imines in an Ir(iii) complex.Synthesis of Highly Substituted Pyridines through Copper-Catalyzed Condensation of Oximes and α,β-Unsaturated Imines.Palladium-catalyzed synthesis of [60]fullerene-fused benzofurans via heteroannulation of phenols.Combination of Cp*RhIII -Catalyzed C-H Activation and a Wagner-Meerwein-Type Rearrangement.A direct cross-coupling reaction of electron-deficient alkenes using an oxidizing directing group.A Visible-Light-Driven Iminyl Radical-Mediated C-C Single Bond Cleavage/Radical Addition Cascade of Oxime Esters.Rhodium-catalyzed redox-neutral coupling of phenidones with alkynes.Redox-Neutral Manganese(I)-Catalyzed C-H Activation: Traceless Directing Group Enabled Regioselective Annulation.Cobalt(III)-Catalyzed Redox-Neutral Synthesis of Unprotected Indoles Featuring an N-N Bond Cleavage.C8-H bond activation vs. C2-H bond activation: from naphthyl amines to lactams.Unnatural Amino Acid Synthesis Enabled by the Regioselective Cobalt(III)-Catalyzed Intermolecular Carboamination of Alkenes.A General Cp*CoIII -Catalyzed Intramolecular C-H Activation Approach for the Efficient Total Syntheses of Aromathecin, Protoberberine, and Tylophora Alkaloids.A copper-catalyzed reaction of oximes with diisopropyl azodicarboxylate: an alternative method for the synthesis of oxime carbonates.Catalytic substitution/cyclization sequences of O-substituted Isocyanates: synthesis of 1-alkoxybenzimidazolones and 1-alkoxy-3,4-dihydroquinazolin-2(1H)-ones.Synthesis of polysubstituted pyridines from oxime acetates using NH4I as a dual-function promoter.Synthesis of 2,2'-biphenols through direct C(sp(2))-H hydroxylation of [1,1'-biphenyl]-2-ols.Rhodium(iii)-catalyzed and MeOH-involved regioselective mono-alkenylation of N-arylureas with acrylates.Synthesis of enaminones via copper-catalyzed decarboxylative coupling reaction under redox-neutral conditions.Charge influence on the first dehydrogenation of methanol by Ptnq (n = 1-3, q = 0, +1, -1): a computational study.Palladium(ii)-catalyzed C-C and C-O bond formation for the synthesis of C1-benzoyl isoquinolines from isoquinoline N-oxides and nitroalkenes.Enaminones as Synthons for a Directed C-H Functionalization: Rh(III) -Catalyzed Synthesis of Naphthalenes.
P2860
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P2860
Transition metal-catalyzed C-H functionalization of N-oxyenamine internal oxidants.
description
2015 nî lūn-bûn
@nan
2015年の論文
@ja
2015年学术文章
@wuu
2015年学术文章
@zh-cn
2015年学术文章
@zh-hans
2015年学术文章
@zh-my
2015年学术文章
@zh-sg
2015年學術文章
@yue
2015年學術文章
@zh
2015年學術文章
@zh-hant
name
Transition metal-catalyzed C-H functionalization of N-oxyenamine internal oxidants.
@en
type
label
Transition metal-catalyzed C-H functionalization of N-oxyenamine internal oxidants.
@en
prefLabel
Transition metal-catalyzed C-H functionalization of N-oxyenamine internal oxidants.
@en
P2093
P2860
P356
P1476
Transition metal-catalyzed C-H functionalization of N-oxyenamine internal oxidants.
@en
P2093
Huanfeng Jiang
Huawen Huang
Wanqing Wu
Xiaochen Ji
P2860
P304
P356
10.1039/C4CS00288A
P577
2015-03-01T00:00:00Z