Arrhenius curves of hydrogen transfers: tunnel effects, isotope effects and effects of pre-equilibria.
about
Hydrogen tunneling links protein dynamics to enzyme catalysisUpdate 1 of: Tunneling and dynamics in enzymatic hydride transfer.Optical imaging of excited-state tautomerization in single molecules.Mechanism of the Swern oxidation: significant deviations from transition state theory.Picosecond-resolved fluorescence studies of substrate and cofactor-binding domain mutants in a thermophilic alcohol dehydrogenase uncover an extended network of communication.Impaired protein conformational landscapes as revealed in anomalous Arrhenius prefactorsActive site hydrophobic residues impact hydrogen tunneling differently in a thermophilic alcohol dehydrogenase at optimal versus nonoptimal temperatures.Identification of a long-range protein network that modulates active site dynamics in extremophilic alcohol dehydrogenases.Use of a metallopeptide-based mimic provides evidence for a proton-coupled electron-transfer mechanism for superoxide reduction by nickel-containing superoxide dismutase.Temperature dependence of proton permeation through a voltage-gated proton channel.Relationship of femtosecond-picosecond dynamics to enzyme-catalyzed H-transfer.Insights into the Hydrogen-Atom Transfer of the Blue Aroxyl.VTST/MT studies of the catalytic mechanism of C-H activation by transition metal complexes with [Cu2(μ-O2)], [Fe2(μ-O2)] and Fe(IV)-O cores based on DFT potential energy surfaces.Measurement of the intramolecular isotope effect on aliphatic hydroxylation by Chromobacterium violaceum phenylalanine hydroxylase.Deep proton tunneling in the electronically adiabatic and non-adiabatic limits: comparison of the quantum and classical treatment of donor-acceptor motion in a protein environment.Kinetic isotope effects on aromatic and benzylic hydroxylation by Chromobacterium violaceum phenylalanine hydroxylase as probes of chemical mechanism and reactivity.Ultrafast CO Kinetics in Heme Proteins: Adiabatic Ligand Binding and Heavy Atom Tunneling.Theoretical investigation on the water-assisted excited-state proton transfer of 7-azaindole derivatives: substituent effect.Kinetics of low-temperature transitions and a reaction rate theory from non-equilibrium distributions.Stabilization and Structure of the cis Tautomer of a Free-Base Porphyrin.Car-Parrinello simulation of an O-H stretching envelope and potential of mean force of an intramolecular hydrogen bonded system: application to a Mannich base in solid state and in vacuum.Change in heat capacity accurately predicts vibrational coupling in enzyme catalyzed reactions.The mechanism of enantioselective ketone reduction with Noyori and Noyori-Ikariya bifunctional catalysts.
P2860
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P2860
Arrhenius curves of hydrogen transfers: tunnel effects, isotope effects and effects of pre-equilibria.
description
2006 nî lūn-bûn
@nan
2006年の論文
@ja
2006年学术文章
@wuu
2006年学术文章
@zh-cn
2006年学术文章
@zh-hans
2006年学术文章
@zh-my
2006年学术文章
@zh-sg
2006年學術文章
@yue
2006年學術文章
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2006年學術文章
@zh-hant
name
Arrhenius curves of hydrogen t ...... and effects of pre-equilibria.
@en
Arrhenius curves of hydrogen t ...... and effects of pre-equilibria.
@nl
type
label
Arrhenius curves of hydrogen t ...... and effects of pre-equilibria.
@en
Arrhenius curves of hydrogen t ...... and effects of pre-equilibria.
@nl
prefLabel
Arrhenius curves of hydrogen t ...... and effects of pre-equilibria.
@en
Arrhenius curves of hydrogen t ...... and effects of pre-equilibria.
@nl
P2860
P356
P1476
Arrhenius curves of hydrogen t ...... and effects of pre-equilibria
@en
P2093
Amnon Kohen
Juan Miguel Lopez
P2860
P304
P356
10.1098/RSTB.2006.1872
P407
P577
2006-08-01T00:00:00Z