about
Proton-coupled electron transferThe x-ray structure of D-amino acid oxidase at very high resolution identifies the chemical mechanism of flavin-dependent substrate dehydrogenationA Radical Transfer Pathway in Spore Photoproduct LyaseAt the dawn of the 21st century: Is dynamics the missing link for understanding enzyme catalysis?Effects of the donor-acceptor distance and dynamics on hydride tunneling in the dihydrofolate reductase catalyzed reactionPerspective: Defining and quantifying the role of dynamics in enzyme catalysisA new conceptual framework for enzyme catalysisThe role of enzyme dynamics and tunnelling in catalysing hydride transfer: studies of distal mutants of dihydrofolate reductase.Effects of a distal mutation on active site chemistry.A flexible glutamine regulates the catalytic activity of toluene o-xylene monooxygenase.Hydrogen tunneling in adenosylcobalamin-dependent glutamate mutase: evidence from intrinsic kinetic isotope effects measured by intramolecular competition.Hydrogen tunneling links protein dynamics to enzyme catalysisUpdate 1 of: Tunneling and dynamics in enzymatic hydride transfer.Mechanism of the Swern oxidation: significant deviations from transition state theory.Convex Arrhenius plots and their interpretationCoordinated effects of distal mutations on environmentally coupled tunneling in dihydrofolate reductase.Isotope effects as probes for enzyme catalyzed hydrogen-transfer reactions.Small temperature dependence of the kinetic isotope effect for the hydride transfer reaction catalyzed by Escherichia coli dihydrofolate reductase.Multidimensional tunneling, recrossing, and the transmission coefficient for enzymatic reactionsRoles of multiple-proton transfer pathways and proton-coupled electron transfer in the reactivity of the bis-FeIV state of MauG.Hydrogen tunnelling in enzyme-catalysed H-transfer reactions: flavoprotein and quinoprotein systems.Relationship of femtosecond-picosecond dynamics to enzyme-catalyzed H-transfer.Concepts in bio-molecular spectroscopy: vibrational case studies on metalloenzymes.Transition state theory can be used in studies of enzyme catalysis: lessons from simulations of tunnelling and dynamical effects in lipoxygenase and other systems.Arrhenius curves of hydrogen transfers: tunnel effects, isotope effects and effects of pre-equilibria.Deuterium isotope effects in the photocycle transitions of the photoactive yellow protein.Simulating enzyme reactions: challenges and perspectives.Effects of isoleucine 135 side chain length on the cofactor donor-acceptor distance within F420H2:NADP+ oxidoreductase: A kinetic analysis.Intrinsic isotope effects on benzylic hydroxylation by the aromatic amino acid hydroxylases: evidence for hydrogen tunneling, coupled motion, and similar reactivities.Isotope effects and heavy-atom tunneling in the Roush allylboration of aldehydesThe EVB as a quantitative tool for formulating simulations and analyzing biological and chemical reactions.Comparison of enzymatic and non-enzymatic nitroethane anion formation: thermodynamics and contribution of tunneling.A critical test of the "tunneling and coupled motion" concept in enzymatic alcohol oxidation.Characterization of azido-NAD+ to assess its potential as a two-dimensional infrared probe of enzyme dynamics.Kinetic isotope effects on aromatic and benzylic hydroxylation by Chromobacterium violaceum phenylalanine hydroxylase as probes of chemical mechanism and reactivity.Coupling of protein motions and hydrogen transfer during catalysis by Escherichia coli dihydrofolate reductase.Allosteric modulation of semicarbazide-sensitive amine oxidase activities in vitro by imidazoline receptor ligands.Importance of barrier shape in enzyme-catalyzed reactions. Vibrationally assisted hydrogen tunneling in tryptophan tryptophylquinone-dependent amine dehydrogenases.Deuterium isotope effects during carbon-hydrogen bond cleavage by trimethylamine dehydrogenase. Implications for mechanism and vibrationally assisted hydrogen tunneling in wild-type and mutant enzymes.Semiclassical evaluation of kinetic isotope effects in 13-atomic system.
P2860
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P2860
description
1999 nî lūn-bûn
@nan
1999 թուականի Յուլիսին հրատարակուած գիտական յօդուած
@hyw
1999 թվականի հուլիսին հրատարակված գիտական հոդված
@hy
1999年の論文
@ja
1999年論文
@yue
1999年論文
@zh-hant
1999年論文
@zh-hk
1999年論文
@zh-mo
1999年論文
@zh-tw
1999年论文
@wuu
name
Hydrogen tunneling in biology.
@ast
Hydrogen tunneling in biology.
@en
type
label
Hydrogen tunneling in biology.
@ast
Hydrogen tunneling in biology.
@en
prefLabel
Hydrogen tunneling in biology.
@ast
Hydrogen tunneling in biology.
@en
P1476
Hydrogen tunneling in biology.
@en
P2093
P304
P356
10.1016/S1074-5521(99)80058-1
P577
1999-07-01T00:00:00Z