Dynamic effects on the periselectivity, rate, isotope effects, and mechanism of cycloadditions of ketenes with cyclopentadiene.
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Diels-Alder reactions of allene with benzene and butadiene: concerted, stepwise, and ambimodal transition states.Kinetic isotope effects in asymmetric reactionsStudies on the Himbert intramolecular arene/allene Diels-Alder cycloaddition. Mechanistic studies and expansion of scope to all-carbon tethers.Bifurcations on potential energy surfaces of organic reactionsCompetition between reaction and intramolecular energy redistribution in solution: observation and nature of nonstatistical dynamics in the ozonolysis of vinyl ethers.Deeper Insight into the Diels-Alder Reaction through the Activation Strain Model.Entropic intermediates and hidden rate-limiting steps in seemingly concerted cycloadditions. Observation, prediction, and origin of an isotope effect on recrossing.Concert along the Edge: Dynamics and the Nature of the Border between General and Specific Acid-Base Catalysis.Racing carbon atoms. Atomic motion reaction coordinates and structural effects on Newtonian kinetic isotope effects.Control elements in dynamically determined selectivity on a bifurcating surfaceTransition-state geometry measurements from (13)c isotope effects. The experimental transition state for the epoxidation of alkenes with oxaziridines.Alkoxide-induced ring opening of bicyclic 2-vinylcyclobutanones: A convenient synthesis of 2-vinyl-substituted 3-cycloalkene-1-carboxylic acid esters(1RS,4SR)-3-Dichloro-methyl-ene-1,4-dimethyl-2-oxabicyclo-[2.2.2]oct-5-ene.Isotope effects, dynamic matching, and solvent dynamics in a Wittig reaction. Betaines as bypassed intermediates.Dynamic origin of the stereoselectivity of a nucleophilic substitution reaction.Experimental evidence for heavy-atom tunneling in the ring-opening of cyclopropylcarbinyl radical from intramolecular 12C/13C kinetic isotope effects.Recrossing and dynamic matching effects on selectivity in a Diels-Alder reaction.Controlling Selectivity by Controlling Energy Partitioning in a Thermal Reaction in Solution.Nonstatistical dynamics on potentials exhibiting reaction path bifurcations and valley-ridge inflection points.Dynamics and the Regiochemistry of Nitration of Toluene.Modulation of inherent dynamical tendencies of the bisabolyl cation via preorganization in epi-isozizaene synthase.Reactivity and Selectivity of Bowl-Shaped Polycyclic Aromatic Hydrocarbons: Relationship to C60.Understanding the Reactivity of Ion-Encapsulated Fullerenes.Heavy-Atom Tunneling Calculations in Thirteen Organic Reactions: Tunneling Contributions are Substantial, and Bell's Formula Closely Approximates Multidimensional Tunneling at ≥250 K.Deuterium- and Tritium-Labelled Compounds: Applications in the Life Sciences.Nonstatistical dynamics on the caldera.Stable long-time semiclassical description of zero-point energy in high-dimensional molecular systems.Approximate quantum trajectory dynamics for reactive processes in condensed phase
P2860
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P2860
Dynamic effects on the periselectivity, rate, isotope effects, and mechanism of cycloadditions of ketenes with cyclopentadiene.
description
2006 nî lūn-bûn
@nan
2006年の論文
@ja
2006年論文
@yue
2006年論文
@zh-hant
2006年論文
@zh-hk
2006年論文
@zh-mo
2006年論文
@zh-tw
2006年论文
@wuu
2006年论文
@zh
2006年论文
@zh-cn
name
Dynamic effects on the perisel ...... ketenes with cyclopentadiene.
@en
Dynamic effects on the perisel ...... ketenes with cyclopentadiene.
@nl
type
label
Dynamic effects on the perisel ...... ketenes with cyclopentadiene.
@en
Dynamic effects on the perisel ...... ketenes with cyclopentadiene.
@nl
prefLabel
Dynamic effects on the perisel ...... ketenes with cyclopentadiene.
@en
Dynamic effects on the perisel ...... ketenes with cyclopentadiene.
@nl
P2860
P356
P1476
Dynamic effects on the perisel ...... ketenes with cyclopentadiene.
@en
P2093
Bryson R Ussing
P2860
P304
P356
10.1021/JA0606024
P407
P577
2006-06-01T00:00:00Z