about
13C and (2)H kinetic isotope effects and the mechanism of Lewis acid-catalyzed ene reactions of formaldehyde.Competition between reaction and intramolecular energy redistribution in solution: observation and nature of nonstatistical dynamics in the ozonolysis of vinyl ethers.Dynamics and a unified understanding of competitive [2,3]- and [1,2]-sigmatropic rearrangements based on a study of ammonium ylides.Mechanistic Studies of Formal Thioboration Reactions of Alkynes.Isotope-induced desymmetrization can mimic isotopic perturbation of equilibria. On the symmetry of bromonium ions and hydrogen bonds.Dynamic effects on the periselectivity, rate, isotope effects, and mechanism of cycloadditions of ketenes with cyclopentadiene.Isotope effects and the mechanism of epoxidation of cyclohexenone with tert-butyl hydroperoxide.Entropic intermediates and hidden rate-limiting steps in seemingly concerted cycloadditions. Observation, prediction, and origin of an isotope effect on recrossing.Dynamics and the failure of transition state theory in alkene hydroboration.Isotope effect, mechanism, and origin of catalysis in the decarboxylation of mandelylthiamin.Concert along the Edge: Dynamics and the Nature of the Border between General and Specific Acid-Base Catalysis.Racing carbon atoms. Atomic motion reaction coordinates and structural effects on Newtonian kinetic isotope effects."Concerted" transition state, stepwise mechanism. Dynamics effects in C2-C6 enyne allene cyclizations.Outer-sphere direction in iridium C-H borylationIr-Catalyzed ortho-Borylation of Phenols Directed by Substrate-Ligand Electrostatic Interactions: A Combined Experimental/in Silico Strategy for Optimizing Weak Interactions.Control elements in dynamically determined selectivity on a bifurcating surfaceTransition-state geometry measurements from (13)c isotope effects. The experimental transition state for the epoxidation of alkenes with oxaziridines.Isotope effects and heavy-atom tunneling in the Roush allylboration of aldehydesDynamically Complex [6+4] and [4+2] Cycloadditions in the Biosynthesis of Spinosyn AElectronic effects in iridium C-H borylations: insights from unencumbered substrates and variation of boryl ligand substituents.Isotope effects, dynamic matching, and solvent dynamics in a Wittig reaction. Betaines as bypassed intermediates.Dynamic origin of the stereoselectivity of a nucleophilic substitution reaction.Experimental evidence for heavy-atom tunneling in the ring-opening of cyclopropylcarbinyl radical from intramolecular 12C/13C kinetic isotope effects.Newtonian kinetic isotope effects. Observation, prediction, and origin of heavy-atom dynamic isotope effects.Controlling Selectivity by Controlling the Path of Trajectories.Recrossing and dynamic matching effects on selectivity in a Diels-Alder reaction.Controlling Selectivity by Controlling Energy Partitioning in a Thermal Reaction in Solution.Isotope effects and the mechanism of an electron-transfer-catalyzed Diels-Alder reaction.A new form of kinetic isotope effect. Dynamic effects on isotopic selectivity and regioselectivity.Mechanism of ene reactions of singlet oxygen. A two-step no-intermediate mechanism.Exo-selective Diels-Alder reactions of vinylazepines. Origin of divergent stereoselectivity in Diels-Alder reactions of vinylazepines, vinylpiperideines, and vinylcycloalkenes.Isotope effects and the nature of selectivity in rhodium-catalyzed cyclopropanations.Isotope effects, dynamics, and the mechanism of solvolysis of aryldiazonium cations in water.Mechanism and origin of enantioselectivity in the Rh2(OAc)(DPTI)3-catalyzed cyclopropenation of alkynes.Isotope effects and the nature of enantioselectivity in the shi epoxidation. The importance of asynchronicity.Dynamics and the Regiochemistry of Nitration of Toluene.Failure and Redemption of Statistical and Nonstatistical Rate Theories in the Hydroboration of Alkenes.Labelling and determination of the energy in reactive intermediates in solution enabled by energy-dependent reaction selectivity.Minimum Energy Structure of Hydridotris(pyrazolyl)borato Iridium(V) Tetrahydride Is Not aC3vCapped OctahedronIsotope effects and the mechanism of allylic hydroxylation of alkenes with selenium dioxide
P50
Q33902089-A55538D2-20D7-43B5-8A91-F5742B468DEEQ38279838-1E4B34FB-0884-4C0D-95BF-446430893708Q38582661-50BC88A4-531E-4290-BE12-5D857DCA9045Q38696990-3CADC939-A7B1-4059-8251-FCB7018FB98FQ38840867-63A377BD-704D-4799-8AFB-33D1978CCF2AQ39942350-244320C8-01A2-4B6B-8119-AD551B444A46Q40317501-80C07460-AC28-43C1-A307-8A4EDF7F9188Q40815771-F28395C3-84D6-4831-AA28-0637E78026B5Q40879766-98938F41-44BA-4E70-9323-720F248F5978Q40888134-1CA54DA2-2F60-48E7-88FF-6CA6402587FEQ40963007-ADC02F5E-92B5-47B6-A24B-CDAAF8B1A780Q41463026-80693ACE-A9EA-462F-8BD9-2D3612A963D7Q41467143-AE779D8B-B850-47AF-BB42-4174A0A2B7B2Q41633762-AF7C3B0D-C011-48C7-B819-B7E3675E88A1Q41706445-A3AC9FC0-46C1-41E6-8104-681BE6B62B3FQ41817430-0AE0988C-1AD8-4EC8-8FFF-6BA9C8ACB1DEQ41831395-9A560959-A9C3-4204-81B2-BA1C60A1FB1FQ41878433-0F29D121-21DC-42F3-8601-5985C14DA56CQ42137599-C77AF7C2-BAC0-4209-9119-D53ED680E119Q42199870-30958C12-9CA2-459D-8488-2F4D590EFB59Q42218731-95B07D86-5220-4460-97ED-3B5BE80B6BC3Q42272211-AC0C1FAF-D1DF-494A-AF78-4710C37D7CD1Q42288035-CB55BF01-4D64-4581-BE7E-42506692521DQ42574871-003E1F1E-04A1-4B55-B92D-C54C596E18F2Q42644643-BDD860A6-D63E-4672-B3A9-71F1F6E522D9Q42872297-3F024DA0-936D-443C-AF46-D5BBBD11E19BQ43164248-5D270136-0075-49CA-A95C-F571C232C5A7Q44140474-B7A3AC80-D52A-4867-81A3-184B5CDBDD6EQ44294004-738F8893-3077-4471-98D2-A13B4BB99466Q44294048-595268A4-E787-4932-9B6E-38B0A999F6F7Q44646407-FC5CAF0C-6428-4E75-932D-518AF7352844Q44694945-5EDA7E1A-0900-40AF-9661-6AFB65BC4E12Q45289324-91308146-A08B-46AC-BE5C-ED133731E198Q46456705-F44626BD-4675-4EF5-BF0D-B2F4B9E7FF60Q46470313-E7F404E3-46BA-46B2-BE27-05C8D6BCA9BCQ46508010-CED8668D-1404-4D5A-AD09-60B2EB45DA2FQ47651193-9C7B7DEF-F3AF-46F6-9DFE-0E6B76246FF2Q48044353-768A118E-9B38-4C18-B479-1618F692AD12Q59909646-41099B4B-5491-4E82-B0CB-01B0E58736FAQ73185805-EB3DD18F-462C-49B2-B755-7A74F3B7628C
P50
description
hulumtues
@sq
researcher
@en
wetenschapper
@nl
հետազոտող
@hy
name
Daniel A Singleton
@ast
Daniel A Singleton
@en
Daniel A Singleton
@es
Daniel A Singleton
@nl
Daniel A Singleton
@sl
type
label
Daniel A Singleton
@ast
Daniel A Singleton
@en
Daniel A Singleton
@es
Daniel A Singleton
@nl
Daniel A Singleton
@sl
prefLabel
Daniel A Singleton
@ast
Daniel A Singleton
@en
Daniel A Singleton
@es
Daniel A Singleton
@nl
Daniel A Singleton
@sl
P1053
O-4367-2014
P106
P21
P31
P3829
P496
0000-0003-3656-1339