Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage. - Wikidata - awgldk - TriplyDB

Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage.

Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage.

http://www.wikidata.org/entity/Q40185445

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Biochemistry and theory of proton-coupled electron transfer Structure and Mechanism of the Diiron Benzoyl-Coenzyme A Epoxidase BoxB Enzymatic oxidation of methane Nitric oxide activation by distal redox modulation in tetranuclear iron nitrosyl complexes Intramolecular C-H and C-F Bond Oxygenation Mediated by a Putative Terminal Oxo Species in Tetranuclear Iron Complexes Design and synthesis of a dinucleating ligand system with varying terminal donor functions that provides no bridging donor and its application to the synthesis of a series of Fe(III)-μ-O-Fe(III) complexes.Accelerated Oxygen Atom Transfer and C-H Bond Oxygenation by Remote Redox Changes in Fe3 Mn-Iodosobenzene Adducts.Mössbauer, electron paramagnetic resonance, and density functional theory studies of synthetic S = 1/2 Fe(III)-O-Fe(IV)═O complexes. Superexchange-mediated spin transition at the Fe(IV)═O site.Study of iron dimers reveals angular dependence of valence-to-core X-ray emission spectra.Understanding hydrogen atom transfer: from bond strengths to Marcus theory.Nonheme oxo-iron(IV) intermediates form an oxyl radical upon approaching the C-H bond activation transition state.Dioxygen activation in soluble methane monooxygenase Modeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand.High-Valent Nonheme Iron Oxidants in Biology: Lessons from Synthetic Fe(IV)=O Complexes.Triggering the generation of an iron(IV)-oxo compound and its reactivity toward sulfides by Ru(II) photocatalysis.A more reactive trigonal-bipyramidal high-spin oxoiron(IV) complex with a cis-labile site.Substrate-triggered activation of a synthetic [Fe2(μ-O)2] diamond core for C-H bond cleavage.Rapid C-H bond activation by a monocopper(III)-hydroxide complex.Mono- and dinuclear iron complexes of bis(1-methylimidazol-2-yl)ketone (bik): structure, magnetic properties, and catalytic oxidation studies.Structure of the key species in the enzymatic oxidation of methane to methanol Evaluating the identity and diiron core transformations of a (μ-oxo)diiron(III) complex supported by electron-rich tris(pyridyl-2-methyl)amine ligands.Toward the synthesis of more reactive S = 2 non-heme oxoiron(IV) complexes.The Q, Compound Q is Finally Deciphered Magnetic circular dichroism and computational study of mononuclear and dinuclear iron(IV) complexes.Protonation of a peroxodiiron(III) complex and conversion to a diiron(III/IV) intermediate: implications for proton-assisted O-O bond cleavage in nonheme diiron enzymes.1H-ENDOR evidence for a hydrogen-bonding interaction that modulates the reactivity of a nonheme Fe(IV)═O unit.A Mononuclear Carboxylate-Rich Oxoiron(IV) Complex: a Structural and Functional Mimic of TauD Intermediate 'J'Triptycene-based Bis(benzimidazole) Carboxylate-Bridged Biomimetic Diiron(II) Complexes.Hydrogen-bonding effects on the reactivity of [X-Fe(III)-O-Fe(IV)═O] (X = OH, F) complexes toward C-H bond cleavage.Dichotomous hydrogen atom transfer vs proton-coupled electron transfer during activation of X-H bonds (X = C, N, O) by nonheme iron-oxo complexes of variable basicity Do Spin State and Spin Density Affect Hydrogen Atom Transfer Reactivity?Enhanced electron-transfer reactivity of nonheme manganese(IV)-oxo complexes by binding scandium ions.Oxidation of water by a nonhaem diiron(IV) complex via proton-coupled electron transfer.Spectroscopic and theoretical investigation of a complex with an [O═Fe(IV)-O-Fe(IV)═O] core related to methane monooxygenase intermediate Q.Hydrogen-abstraction reactivity patterns from A to Y: the valence bond way.Ligand Field Strength Mediates Electron Delocalization in Octahedral [((H)L)2Fe6(L')m](n+) Clusters.X-ray absorption spectroscopic characterization of the diferric-peroxo intermediate of human deoxyhypusine hydroxylase in the presence of its substrate eIF5a Structure and spin state of nonheme FeIVO complexes depending on temperature: predictive insights from DFT calculations and experiments.Isolation of a 2-hydroxytetrahydrofuran complex from copper-promoted hydroxylation of THF.An oxygenase that forms and deoxygenates toxic epoxide.

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P2860

Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage.

http://www.wikidata.org/entity/Q40185445

description

2010 nî lūn-bûn

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2010年の論文

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2010年論文

@yue

2010年論文

@zh-hant

2010年論文

@zh-hk

2010年論文

@zh-mo

2010年論文

@zh-tw

2010年论文

@wuu

2010年论文

@zh

2010年论文

@zh-cn

name

Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage.

@en

type

label

Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage.

@en

prefLabel

Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage.

@en

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P1433

Nature Chemistry

P1476

Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage.

@en

P2093

Eckard Münck

http://www.w3.org/2001/XMLSchema#string

Genqiang Xue

http://www.w3.org/2001/XMLSchema#string

Lawrence Que

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Raymond De Hont

http://www.w3.org/2001/XMLSchema#string

P2860

Observed enhancement of the reactivity of a biomimetic diiron complex by the addition of water - mechanistic insights from theoretical modeling

Heme-Containing Oxygenases.

Mechanistic studies on the hydroxylation of methane by methane monooxygenase.

Understanding C-H bond oxidations: H. and H- transfer in the oxidation of toluene by permanganate.

Non-heme Fe(IV)-oxo intermediates.

Geometric and electronic structure/function correlations in non-heme iron enzymes.

Dioxygen activation at mononuclear nonheme iron active sites: enzymes, models, and intermediates.

Stalking intermediates in oxygen activation by iron enzymes: motivation and method.

High-valent nonheme iron-oxo species in biomimetic oxidations.

A synthetic precedent for the [FeIV2(mu-O)2] diamond core proposed for methane monooxygenase intermediate Q.

P2888

P304

400-405

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scholarly article

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10.1038/NCHEM.586

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5

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2

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2010-03-21T00:00:00Z

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43299774

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20414242

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2859466

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