High-valent nonheme iron-oxo species in biomimetic oxidations.
about
Crystallographic and spectroscopic studies of peroxide-derived myoglobin compound II and occurrence of protonated FeIV Omyo-Inositol oxygenase: a radical new pathway for O(2) and C-H activation at a nonheme diiron clusterA two-state reactivity model explains unusual kinetic isotope effect patterns in C-H bond cleavage by nonheme oxoiron(IV) complexes.The fundamental role of exchange-enhanced reactivity in C-H activation by S=2 oxo iron(IV) complexesIntramolecular gas-phase reactions of synthetic nonheme oxoiron(IV) ions: proximity and spin-state reactivity rulesA Mononuclear Carboxylate-Rich Oxoiron(IV) Complex: a Structural and Functional Mimic of TauD Intermediate 'J'Iron-oxidation-state-dependent O-O bond cleavage of meta-chloroperbenzoic acid to form an iron(IV)-oxo complex.A synthetic precedent for the [FeIV2(mu-O)2] diamond core proposed for methane monooxygenase intermediate Q.Kinetic analysis of the conversion of nonheme (alkylperoxo)iron(III) species to iron(IV) complexes.Formation of a cobalt(III) imido from a cobalt(II) amido complex. Evidence for proton-coupled electron transfer.XAS characterization of a nitridoiron(IV) complex with a very short Fe-N bond.electrochemical generation of a nonheme oxoiron(IV) complex.Axial ligand effects on the geometric and electronic structures of nonheme oxoiron(IV) complexesProton- and reductant-assisted dioxygen activation by a nonheme iron(II) complex to form an oxoiron(IV) intermediateAn inverted and more oxidizing isomer of [Fe(IV)(O)(tmc)(NCCH3)]2+Copper-hydroperoxo-mediated N-debenzylation chemistry mimicking aspects of copper monooxygenases.Flavonoids biotransformation by bacterial non-heme dioxygenases, biphenyl and naphthalene dioxygenase.Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage.Oxidation of methane by an N-bridged high-valent diiron-oxo species: electronic structure implications on the reactivity.Redox potential and C-H bond cleaving properties of a nonheme Fe(IV)=O complex in aqueous solution.M≡E and M=E Complexes of Iron and Cobalt that Emphasize Three-fold Symmetry (E = O, N, NR).The Catalytic Function of Nonheme Iron (III) Complex for Hydrocarbon OxidationIron(II) complexes supported by sulfonamido tripodal ligands: endogenous versus exogenous substrate oxidation.Mössbauer and DFT study of the ferromagnetically coupled diiron(IV) precursor to a complex with an Fe(IV)(2)O(2) diamond core.A highly oxidizing and isolable oxoruthenium(V) complex [Ru(V)(N4O)(O)]2+: electronic structure, redox properties, and oxidation reactions investigated by DFT calculations.Analysis of an alternative to the H-atom abstraction mechanism in methane C-H bond activation by nonheme iron(IV)-oxo oxidants.Nonheme iron mediated oxidation of light alkanes with oxone: characterization of reactive oxoiron(IV) ligand cation radical intermediates by spectroscopic studies and DFT calculations.Insights into the P-to-Q conversion in the catalytic cycle of methane monooxygenase from a synthetic model system.Mechanistic elucidation of C-H oxidation by electron rich non-heme iron(IV)-oxo at room temperature.Charge transfer in MOH(H2O)(+) (M = Mn, Fe, Co, Ni, Cu, Zn) complexes revealed by vibrational spectroscopy of mass-selected ions.ortho-Hydroxylation of aromatic acids by a non-heme Fe(V)=O species: how important is the ligand design?Does a higher metal oxidation state necessarily imply higher reactivity toward H-atom transfer? A computational study of C-H bond oxidation by high-valent iron-oxo and -nitrido complexes.Highly efficient oxidation of alcohols catalyzed by a porphyrin-inspired manganese complex.O2 -independent demethylation of trimethylamine N-oxide by Tdm of Methylocella silvestris.The "innocent" role of Sc(3+) on a non-heme Fe catalyst in an O2 environment.An abiotic analogue of the diiron(IV)oxo "diamond core" of soluble methane monooxygenase generated by direct activation of O2 in aqueous Fe(II)/EDTA solutions: thermodynamics and electronic structure.
P2860
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P2860
High-valent nonheme iron-oxo species in biomimetic oxidations.
description
2006 nî lūn-bûn
@nan
2006年の論文
@ja
2006年学术文章
@wuu
2006年学术文章
@zh-cn
2006年学术文章
@zh-hans
2006年学术文章
@zh-my
2006年学术文章
@zh-sg
2006年學術文章
@yue
2006年學術文章
@zh
2006年學術文章
@zh-hant
name
High-valent nonheme iron-oxo species in biomimetic oxidations.
@ast
High-valent nonheme iron-oxo species in biomimetic oxidations.
@en
type
label
High-valent nonheme iron-oxo species in biomimetic oxidations.
@ast
High-valent nonheme iron-oxo species in biomimetic oxidations.
@en
prefLabel
High-valent nonheme iron-oxo species in biomimetic oxidations.
@ast
High-valent nonheme iron-oxo species in biomimetic oxidations.
@en
P1476
High-valent nonheme iron-oxo species in biomimetic oxidations.
@en
P2093
Lawrence Que
Xiaopeng Shan
P304
P356
10.1016/J.JINORGBIO.2006.01.014
P577
2006-03-13T00:00:00Z