Dynamics and the failure of transition state theory in alkene hydroboration.
about
Quantum-mechanical study of 10-R-9-borabicyclo[3.3.2]decane alkene hydroboration.Kinetic isotope effects in asymmetric reactionsDimer involvement and origin of crossover in nickel-catalyzed aldehyde-alkyne reductive couplingsQuantum mechanical investigations of organocatalysis: mechanisms, reactivities, and selectivities.Theoretical and computational studies of non-equilibrium and non-statistical dynamics in the gas phase, in the condensed phase and at interfaces.Specificity in transition state binding: the Pauling model revisited.Competition between reaction and intramolecular energy redistribution in solution: observation and nature of nonstatistical dynamics in the ozonolysis of vinyl ethers.Taking the plunge: chemical reaction dynamics in liquids.A case study of the mechanism of alcohol-mediated Morita Baylis-Hillman reactions. The importance of experimental observationsRecrossing and dynamic matching effects on selectivity in a Diels-Alder reaction.Controlling Selectivity by Controlling Energy Partitioning in a Thermal Reaction in Solution.Competition between concerted and stepwise dynamics in the triplet di-π-methane rearrangement.Synthesis of cyclic amine boranes through triazole-gold(I)-catalyzed alkyne hydroboration.Nonstatistical dynamics on potentials exhibiting reaction path bifurcations and valley-ridge inflection points.Dynamics and the Regiochemistry of Nitration of Toluene.How frustrated Lewis acid/base systems pass through transition-state regions: H2 cleavage by [tBu3P/B(C6F5)3].Modulation of inherent dynamical tendencies of the bisabolyl cation via preorganization in epi-isozizaene synthase.Deuterium- and Tritium-Labelled Compounds: Applications in the Life Sciences.Non-equilibrium reaction and relaxation dynamics in a strongly interacting explicit solvent: F + CD3CN treated with a parallel multi-state EVB model.Product energy deposition of CN + alkane H abstraction reactions in gas and solution phases.Origins of observed reactivity and specificity in the addition of B2Cl4 and analogues to unsaturated compounds.A non-dissociative open-flask hydroboration with ammonia borane: ready synthesis of ammonia-trialkylboranes and aminodialkylboranes.Two-coordinate group 14 element(ii) hydrides as reagents for the facile, and sometimes reversible, hydrogermylation/hydrostannylation of unactivated alkenes and alkynes.Computational organic chemistryDeviation from the anti-Markovnikov rule: a computational study of the regio- and stereoselectivity of diene hydroboration reactionsDivergence from the classical hydroboration reactivity; boron containing materials through a hydroboration cascade of small cyclic dienes
P2860
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P2860
Dynamics and the failure of transition state theory in alkene hydroboration.
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年学术文章
@wuu
2009年学术文章
@zh-cn
2009年学术文章
@zh-hans
2009年学术文章
@zh-my
2009年学术文章
@zh-sg
2009年學術文章
@yue
2009年學術文章
@zh
2009年學術文章
@zh-hant
name
Dynamics and the failure of transition state theory in alkene hydroboration.
@en
type
label
Dynamics and the failure of transition state theory in alkene hydroboration.
@en
prefLabel
Dynamics and the failure of transition state theory in alkene hydroboration.
@en
P356
P1476
Dynamics and the failure of transition state theory in alkene hydroboration.
@en
P2093
Yatsandra Oyola
P304
P356
10.1021/JA807666D
P407
P577
2009-03-01T00:00:00Z