Triggering N(2) uptake via redox-induced expulsion of coordinated NH(3) and N(2) silylation at trigonal bipyramidal iron.
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Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking ChampionA Sulfide-Bridged Diiron(II) Complex with a cis-N2H4LigandNitric oxide activation by distal redox modulation in tetranuclear iron nitrosyl complexesA Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench (57)Fe Mössbauer Data, and a Hydride Resting StateHomogeneous iron complexes for the conversion of dinitrogen into ammonia and hydrazine.Insight into the Iron-Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride LigandsSynthesis of diamidopyrrolyl molybdenum complexes relevant to reduction of dinitrogen to ammonia.Terminal iron dinitrogen and iron imide complexes supported by a tris(phosphino)borane ligand.Catalytic conversion of nitrogen to ammonia by an iron model complex.Ammonia formation by a thiolate-bridged diiron amide complex as a nitrogenase mimic.N2 functionalization at iron metallaboratranes.Conversion of Fe-NH2 to Fe-N2 with release of NH3Assembly and properties of heterobimetallic Co(II/III)/Ca(II) complexes with aquo and hydroxo ligands.Alkali Metal Variation and Twisting of the FeNNFe Core in Bridging Diiron Dinitrogen Complexes.Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane.Heterobimetallic Complexes with M(III)-(μ-OH)-M(II) Cores (M(III) = Fe, Mn, Ga; M(II) = Ca, Sr, and Ba): Structural, Kinetic, and Redox PropertiesFe-N2/CO complexes that model a possible role for the interstitial C atom of FeMo-cofactor (FeMoco).Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron.Cobalt-Magnesium and Iron-Magnesium Complexes with Weakened Dinitrogen Bridges.Synthesis, structure and reactivity of Fe(II/III)-NH3 complexes bearing a tripodal sulfonamido ligand.Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen.Coordination chemistry insights into the role of alkali metal promoters in dinitrogen reduction.A nonclassical dihydrogen adduct of S = ½ Fe(I)Catalytic NH3 synthesis using N2/H2 at molecular transition metal complexes - concepts for lead structure determination using computational chemistry.Methyl Complexes of the Transition Metals.N-H Bond Dissociation Enthalpies and Facile H Atom Transfers for Early Intermediates of Fe-N2 and Fe-CN Reductions.Multidentate silyl ligands in transition metal chemistry.A Triad of Highly Reduced, Linear Iron Nitrosyl Complexes: {FeNO}(8-10).Transformation of an [Fe(η2-N2H3)]+ species to π-delocalized [Fe2(μ-N2H2)](2+/+) complexes.An Fe-N₂ Complex That Generates Hydrazine and Ammonia via Fe═NNH₂: Demonstrating a Hybrid Distal-to-Alternating Pathway for N₂ Reduction.Proton-Coupled Reduction of an Iron Cyanide Complex to Methane and Ammonia.Low-temperature N2 binding to two-coordinate L2Fe(0) enables reductive trapping of L2FeN2(-) and NH3 generation.Alkali-Controlled C-H Cleavage or N-C Bond Formation by N2-Derived Iron Nitrides and Imides.M≡E and M=E Complexes of Iron and Cobalt that Emphasize Three-fold Symmetry (E = O, N, NR).Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor.Mononuclear five- and six-coordinate iron hydrazido and hydrazine species.Evaluating molecular cobalt complexes for the conversion of N2 to NH3Exploring secondary-sphere interactions in Fe-N x H y complexes relevant to N2 fixationElectronic nature of zwitterionic alkali metal methanides, silanides and germanides - a combined experimental and computational approach.H-H and Si-H bond addition to Fe≡NNR2 intermediates derived from N2.
P2860
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P2860
Triggering N(2) uptake via redox-induced expulsion of coordinated NH(3) and N(2) silylation at trigonal bipyramidal iron.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Triggering N(2) uptake via red ...... at trigonal bipyramidal iron.
@en
type
label
Triggering N(2) uptake via red ...... at trigonal bipyramidal iron.
@en
prefLabel
Triggering N(2) uptake via red ...... at trigonal bipyramidal iron.
@en
P2860
P356
P1433
P1476
Triggering N(2) uptake via red ...... n at trigonal bipyramidal iron
@en
P2093
Jonas C Peters
Neal P Mankad
P2860
P2888
P304
P356
10.1038/NCHEM.660
P50
P577
2010-05-16T00:00:00Z