A highly enantioselective intramolecular Michael reaction catalyzed by N-heterocyclic carbenes
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Catalytic Kinetic Resolution of a Dynamic Racemate: Highly Stereoselective β-Lactone Formation by N-Heterocyclic Carbene CatalysisDiscovering New Reactions with N-Heterocyclic Carbene Catalysis.Chiral N-heterocyclic carbene-catalyzed generation of ester enolate equivalents from {alpha},{beta}-unsaturated aldehydes for enantioselective Diels-Alder reactionsCarbon-carbon bond activation of cyclobutenones enabled by the addition of chiral organocatalyst to ketoneOxyanion steering and CH-π interactions as key elements in an N-heterocyclic carbene-catalyzed [4 + 2] cycloaddition.Exploiting Acyl and Enol Azolium Intermediates via NHeterocyclic Carbene Catalyzed Reactions of Alpha-Reducible Aldehydes.Chiral NHC-catalyzed oxodiene Diels-Alder reactions with alpha-chloroaldehyde bisulfite saltsEmploying homoenolates generated by NHC catalysis in carbon-carbon bond-forming reactions: state of the art.Enantioselective syntheses of indanes: from organocatalysis to C-H functionalization.N-heterocyclic carbene-catalyzed enantioselective Mannich reactions with alpha-aryloxyacetaldehydes.Cooperative N-heterocyclic carbene/Lewis acid catalysis for highly stereoselective annulation reactions with homoenolates.Lewis acid activated synthesis of highly substituted cyclopentanes by the N-heterocyclic carbene catalyzed addition of homoenolate equivalents to unsaturated ketoesters.Protonation of Homoenolate Equivalents Generated by N-Heterocyclic Carbenes.Catalytic dynamic kinetic resolutions with N-heterocyclic carbenes: asymmetric synthesis of highly substituted β-lactonesFunctionalized cyclopentenes through a tandem NHC-catalyzed dynamic kinetic resolution and ambient temperature decarboxylation: mechanistic insight and synthetic applicationN-heterocyclic carbene-catalyzed oxidation of unactivated aldehydes to esters.Highly diastereo- and enantioselective additions of homoenolates to nitrones catalyzed by N-heterocyclic carbenes.Enantioselective N-heterocyclic carbene catalyzed annulation reactions with imidazolidinones.Enantioselective synthesis of alpha,alpha-disubstituted cyclopentenes by an N-heterocyclic carbene-catalyzed desymmetrization of 1,3-diketonesFormal synthesis of salinosporamide A via NHC-catalyzed intramolecular lactonizationN-Heterocyclic Carbene-Catalyzed Oxidations.NHC-catalyzed reactions of aryloxyacetaldehydes: a domino elimination/conjugate addition/acylation process for the synthesis of substituted coumarins.Synthesis of Enantioenriched α,α-Disubstituted Cyclopentenes Catalyzed by N-Heterocyclic Carbenes.Direct amination of homoenolates catalyzed by N-heterocyclic carbenes.Cooperative catalysis by carbenes and Lewis acids in a highly stereoselective route to gamma-lactams.N-heterocyclic carbene-catalyzed rearrangements of vinyl sulfones.N-Heterocyclic Carbene-Promoted Rauhut]Currier Reactions between Vinyl Sulfones and α,β-Unsaturated Aldehydes.NHC-catalyzed/titanium(IV)-mediated highly diastereo- and enantioselective dimerization of enals.Stereodivergency of triazolium and imidazolium-derived NHCs for catalytic, enantioselective cyclopentane synthesis.Redox-switchable ring-closing metathesis: catalyst design, synthesis, and study.Controlled β-protonation and [4+2] cycloaddition of enals and chalcones via N-heterocyclic carbene/acid catalysis: toward substrate independent reaction control.N-Heterocyclic carbene-catalyzed cascade reaction of 2-aroylvinylcinnamaldehydes with 2-aroylvinylchalcones: rapid assembly of six contiguous stereogenic centers with high diastereoselectivity.Catalytic enantioselective synthesis of indanes by a cation-directed 5-endo-trig cyclization.A Carbene Catalysis Strategy for the Synthesis of Protoilludane Natural Products.Enantioselective intermolecular all-carbon [4+2] annulation via N-heterocyclic carbene organocatalysis.N-Heterocyclic carbene-catalyzed [4 + 2] cyclization of 2-bromo-2-enal with 3-alkylenyloxindoles: efficient assembly of spirocarbocyclic oxindole.Enantioselective Stetter reactions of enals and modified chalcones catalyzed by N-heterocyclic carbenes.A highly regio- and stereoselective cascade annulation of enals and benzodi(enone)s catalyzed by N-heterocyclic carbenes.An Upstream By-product from Ester Activation via NHC-Catalysis Catalyzes Downstream Sulfonyl Migration Reaction.
P2860
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P2860
A highly enantioselective intramolecular Michael reaction catalyzed by N-heterocyclic carbenes
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
2007年论文
@zh
2007年论文
@zh-cn
name
A highly enantioselective intr ...... zed by N-heterocyclic carbenes
@en
A highly enantioselective intr ...... zed by N-heterocyclic carbenes
@nl
type
label
A highly enantioselective intr ...... zed by N-heterocyclic carbenes
@en
A highly enantioselective intr ...... zed by N-heterocyclic carbenes
@nl
prefLabel
A highly enantioselective intr ...... zed by N-heterocyclic carbenes
@en
A highly enantioselective intr ...... zed by N-heterocyclic carbenes
@nl
P2093
P2860
P356
P1476
A highly enantioselective intr ...... zed by N-heterocyclic carbenes
@en
P2093
Audrey Chan
Eric M Phillips
Manabu Wadamoto
P2860
P304
P356
10.1002/ANIE.200605235
P407
P577
2007-01-01T00:00:00Z