Cooperative catalysis by carbenes and Lewis acids in a highly stereoselective route to gamma-lactams.
about
Organocatalytic Reactions Enabled by N-Heterocyclic CarbenesCatalytic Kinetic Resolution of a Dynamic Racemate: Highly Stereoselective β-Lactone Formation by N-Heterocyclic Carbene CatalysisSynthesis of a γ-lactam library via formal cycloaddition of imines and substituted succinic anhydrides.Synthesis of a library of "lead-like" γ-lactams by a one pot, four-component reactionAmmonia synthons for the multicomponent assembly of complex gamma-lactams.Enantioconvergent synthesis of functionalized γ-butyrolactones via (3 + 2)-annulation.N-Heterocyclic carbene-catalyzed enantioselective annulations: a dual activation strategy for a formal [4+2] addition for dihydrocoumarins.Diversity-oriented synthesis of drug-like macrocyclic scaffolds using an orthogonal organo- and metal catalysis strategy.Enantioselective β-Protonation by a Cooperative Catalysis Strategy.Cooperative Lewis acid/N-heterocyclic carbene catalysisExploiting Acyl and Enol Azolium Intermediates via NHeterocyclic Carbene Catalyzed Reactions of Alpha-Reducible Aldehydes.A dual Lewis base activation strategy for enantioselective carbene-catalyzed annulations.Employing homoenolates generated by NHC catalysis in carbon-carbon bond-forming reactions: state of the art.A continuum of progress: applications of N-hetereocyclic carbene catalysis in total synthesis.Asymmetric homoenolate additions to acyl phosphonates through rational design of a tailored N-heterocyclic carbene catalyst.Catalytic asymmetric synthesis of enantioenriched heterocycles bearing a C-CF3 stereogenic center.Enamine/Carbene Cascade Catalysis in the Diastereo- and Enantioselective Synthesis of Functionalized Cyclopentanones.Enantioselective cooperative catalysis.Diastereoselective synthesis of γ- and δ-lactams from imines and sulfone-substituted anhydrides.Enantioselective magnesium-catalyzed transformations.The effect of the N-mesityl group in NHC-catalyzed reactions.Lewis acid activated synthesis of highly substituted cyclopentanes by the N-heterocyclic carbene catalyzed addition of homoenolate equivalents to unsaturated ketoesters.Catalytic dynamic kinetic resolutions with N-heterocyclic carbenes: asymmetric synthesis of highly substituted β-lactonesFunctionalized cyclopentenes through a tandem NHC-catalyzed dynamic kinetic resolution and ambient temperature decarboxylation: mechanistic insight and synthetic applicationN-Heterocyclic Carbene Catalyzed Enantioselective Annulation of Benzothiazolyl Ethyl Acetates with 2-Bromoenals.Enantioselective annulations for dihydroquinolones by in situ generation of azolium enolatesN-heterocyclic-carbene-catalyzed synthesis of 2-aryl indoles.A tandem isomerization/prins strategy: iridium(III)/Brønsted acid cooperative catalysisEnantioselective N-heterocyclic carbene catalyzed annulation reactions with imidazolidinones.N-Heterocyclic carbene/Brønsted acid cooperative catalysis as a powerful tool in organic synthesis.Enantioselective α-vinylation of aldehydes via the synergistic combination of copper and amine catalysis.Asymmetric N-heterocyclic carbene catalyzed addition of enals to nitroalkenes: controlling stereochemistry via the homoenolate reactivity pathway to access δ-lactams.An N-heterocyclic carbene/Lewis acid strategy for the stereoselective synthesis of spirooxindole lactones.Synergistic Catalysis: A Powerful Synthetic Strategy for New Reaction Development.N-heterocyclic carbene-catalyzed rearrangements of vinyl sulfones.N-Heterocyclic Carbene-Promoted Rauhut]Currier Reactions between Vinyl Sulfones and α,β-Unsaturated Aldehydes.NHC-catalyzed/titanium(IV)-mediated highly diastereo- and enantioselective dimerization of enals.A cooperative N-heterocyclic carbene/chiral phosphate catalysis system for allenolate annulations.N-heterocyclic carbene and Brønsted acid cooperative catalysis: asymmetric synthesis of trans-γ-lactams.Enantioselective N-heterocyclic carbene-catalyzed β-hydroxylation of enals using nitroarenes: an atom transfer reaction that proceeds via single electron transfer.
P2860
Q28081119-E9D81985-BF5E-4174-B410-5CC83E6B3A3DQ33897423-B51939E9-6AF1-417E-9EEF-1994EE7ADC8EQ34120715-B2C1D92C-B017-4978-8B83-B8E6B56AD8C6Q34727154-7B2C44CF-2A9A-4733-9927-C9AF922A57A7Q34881042-1E09543E-7B21-4E60-A9BB-AAC63F027F6FQ35005987-476D587A-D754-488F-BC67-54A2402D40A0Q35090918-36E4B668-5AD3-493A-8EBC-7237BDB49CE8Q35278303-7ACF03F1-BF95-416B-B811-3D35E9CFE715Q35821491-08452FC3-011E-41CC-A654-942BBEA5CD06Q36093567-36CA9FEF-7C13-4AB0-BA19-E237B57BDF72Q36714193-369F0217-4B34-46AA-8262-1E523B084BE4Q37102966-1D67773C-1BCF-4133-A025-1B928E744841Q37903278-A196B422-A66C-4234-B64F-3C687EE66FE0Q38052878-0B87B6AE-F541-4BA7-A338-74D4DC8ED21AQ38258040-4B852244-A0FD-4407-8FF4-D9277EE84C93Q38367314-DF81C61E-0630-49E3-8197-07AD8F62FDA8Q38441333-FC76639A-5512-47C1-BAA4-F79D014205E5Q38540351-004ABEF7-0180-4276-BC63-D7B1D83F33EBQ38632743-243DDFAE-D216-4976-A43B-E8054B57635DQ39312815-08B6C803-78ED-441D-85DB-4DBB6149531DQ40760722-F984D383-93ED-47EB-BC1B-7AF253EC357BQ40959175-08345D51-DFB0-4640-B139-2F4B0FE4E398Q41470235-5B4AB7A4-4AD6-460E-9B5C-953A9C2C7920Q41807524-BB7251BB-F3BE-48A6-953E-A681AC1644B9Q41841236-08F737FF-A02D-42D5-A567-34EFA8E70903Q41846458-24B1A9C7-1941-401F-B6B7-FBD512BCC36AQ41891805-343EE208-957A-489D-8F8E-1852BB00DCF4Q41898587-DD6FBE4C-4877-49FA-9408-034B1FDA8BDFQ41898589-67E5D423-7CD3-43A3-BCAF-4CA7EE2231C7Q41960536-D45BA633-582B-4BEA-AAF2-B694301AFDF0Q42107925-163B8D84-7B62-447A-9AE9-EE2A95C6C369Q42130000-C4384664-00AB-415C-9CAE-06E3E3309302Q42151656-C5C50DB5-870E-4927-BC47-E7AE9E96BA79Q42544411-F28E5A3A-7E73-42AE-AA5C-F12F46C6F1D1Q42574353-D76C24F2-6502-4E81-AAC4-B9763E1EB518Q42607555-1DB296B4-FD43-4C26-9C43-7E3E2C560120Q42636978-7E2A91BB-EE9D-40AE-B169-050E29E18D73Q42837159-DBBCC2C0-43A0-4D7F-BC35-FBC958BD9E3DQ42866247-DA3150F2-F247-462A-8E3A-8B80D68B50C5Q42962472-7FA08CAE-3274-433B-9B9C-32FE8099BA91
P2860
Cooperative catalysis by carbenes and Lewis acids in a highly stereoselective route to gamma-lactams.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Cooperative catalysis by carbe ...... ective route to gamma-lactams.
@en
Cooperative catalysis by carbe ...... ective route to gamma-lactams.
@nl
type
label
Cooperative catalysis by carbe ...... ective route to gamma-lactams.
@en
Cooperative catalysis by carbe ...... ective route to gamma-lactams.
@nl
prefLabel
Cooperative catalysis by carbe ...... ective route to gamma-lactams.
@en
Cooperative catalysis by carbe ...... ective route to gamma-lactams.
@nl
P2093
P2860
P356
P1433
P1476
Cooperative catalysis by carbe ...... ective route to gamma-lactams.
@en
P2093
Benoit Cardinal-David
Dane Holte
Dustin E A Raup
P2860
P2888
P304
P356
10.1038/NCHEM.727
P577
2010-07-18T00:00:00Z