A general strategy for the perfluoroalkylation of arenes and arylbromides by using arylboronate esters and [(phen)CuR(F)]
about
Carbon-carbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylationsTamed arene and heteroarene trifluoromethylation.Trifluoromethylation of Arylsilanes with [(phen)CuCF3 ]Recent advances in transition metal-catalyzed Csp(2)-monofluoro-, difluoro-, perfluoromethylation and trifluoromethylthiolation.Introduction of fluorine and fluorine-containing functional groups.Recent advances in trifluoromethylation of organic compounds using Umemoto's reagents.Photocatalytic fluoroalkylation reactions of organic compounds.Copper-mediated fluorination of aryl iodides.Copper-mediated radical trifluoromethylation of unsaturated potassium organotrifluoroborates.Biocatalytic trifluoromethylation of unprotected phenols.Practical method for the Cu-mediated trifluoromethylation of arylboronic acids with CF3 radicals derived from NaSO2CF3 and tert-butyl hydroperoxide (TBHP).Regio- and Stereoselective Radical Perfluoroalkyltriflation of Alkynes Using Phenyl(perfluoroalkyl)iodonium Triflates.Copper-mediated difluoromethylation of aryl and vinyl iodides.Merging visible-light photocatalysis and transition-metal catalysis in the copper-catalyzed trifluoromethylation of boronic acids with CF3I.Direct synthesis of a trifluoromethyl copper reagent from trifluoromethyl ketones: application to trifluoromethylation.Directing-group-assisted copper-catalyzed olefinic trifluoromethylation of electron-deficient alkenes.Copper-catalyzed trifluoromethylation-cyclization of enynes: highly regioselective construction of trifluoromethylated carbocycles and heterocycles.Sterically controlled alkylation of arenes through iridium-catalyzed C-H borylation.Copper-catalyzed synthesis of trifluoromethyl-substituted isoxazolines.A vitamin B12 derivative catalyzed electrochemical trifluoromethylation and perfluoroalkylation of arenes and heteroarenes in organic media.Ligand-dependent formation of ion-pair Cu(I)/Cu(III) trifluoromethyl complexes containing bisphosphines.Decarboxylative Trifluoromethylating Reagent [Cu(O2 CCF3 )(phen)] and Difluorocarbene Precursor [Cu(phen)2 ][O2 CCF2 Cl].Dialkylzinc-mediated cross-coupling reactions of perfluoroalkyl and perfluoroaryl halides with aryl halides.Transition-metal-free synthesis of β-trifluoromethylated enamines with trifluoromethanesulfinate.TMSCF3 as a Convenient Source of CF2 =CF2 for Pentafluoroethylation, (Aryloxy)tetrafluoroethylation, and Tetrafluoroethylation.C-H Insertion as a Key Step to Spiro-Oxetanes, Scaffolds for Drug Discovery.Formation of α-SF5-Enolate Enables Preparation of 3-SF5-Quinolin-2-ones, 3-SF5-Quinolines, and 3-SF5-Pyridin-2-ones: Evaluation of their Physicochemical Properties.Synthesis and Reactivity of Fluoroalkyl Copper Complexes by the Oxycupration of Tetrafluoroethylene.Synthesis of difluoromethyl thioethers from difluoromethyl trimethylsilane and organothiocyanates generated in situ.Combination of fluoroalkylation and Kornblum-DeLaMare reaction: a new strategy for the construction of (Z)-β-perfluoroalkyl enaminones.CuCl-catalyzed ortho trifluoromethylation of arenes and heteroarenes with a pivalamido directing group.One-pot preparation of trifluoromethylated homoallylic N-acylhydrazines or α-methylene-γ-lactams from acylhydrazines, trifluoroacetaldehyde methyl hemiacetal, allyl bromide and tin.A new strategy to construct a C=C-CF3 subunit via CuBr-catalyzed domino reaction of homopropargyl amines: an efficient synthesis of trifluoromethyl containing building blocks 4-trifluoromethyl-2,3-dihydro-pyrroliums.Mechanisms and applications of cyclometalated Pt(ii) complexes in photoredox catalytic trifluoromethylation.Palladium-Catalysed Synthesis of α-(Trifluoromethyl)styrenes by Means of Directed C-H Bond FunctionalizationA decade advancement of transition metal-catalyzed borylation of aryl halides and sulfonates
P2860
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P2860
A general strategy for the perfluoroalkylation of arenes and arylbromides by using arylboronate esters and [(phen)CuR(F)]
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
2011年论文
@zh
2011年论文
@zh-cn
name
A general strategy for the per ...... sing arylboronate esters and [
@nl
A general strategy for the per ...... nate esters and [(phen)CuR(F)]
@en
type
label
A general strategy for the per ...... sing arylboronate esters and [
@nl
A general strategy for the per ...... nate esters and [(phen)CuR(F)]
@en
prefLabel
A general strategy for the per ...... sing arylboronate esters and [
@nl
A general strategy for the per ...... nate esters and [(phen)CuR(F)]
@en
P2860
P356
P1476
A general strategy for the per ...... nate esters and [(phen)CuR(F)]
@en
P2093
Nichole D Litvinas
Patrick S Fier
P2860
P304
P356
10.1002/ANIE.201106668
P407
P577
2011-11-14T00:00:00Z