Enantioselective synthesis of homoallylic amines through reactions of (pinacolato)allylborons with aryl-, heteroaryl-, alkyl-, or alkene-substituted aldimines catalyzed by chiral C1-symmetric NHC-Cu complexes.
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Dual Catalytic Decarboxylative Allylations of α-Amino Acids and Their Divergent MechanismsSimple organic molecules as catalysts for enantioselective synthesis of amines and alcoholsCopper-Catalyzed Enantioselective Addition of Styrene-Derived Nucleophiles to Imines Enabled by Ligand-Controlled Chemoselective HydrocuprationAsymmetric synthesis of α-alkenyl homoallylic primary amines via 1,2-addition of Grignard reagent to α,β-unsaturated phosphonyl iminesAn efficient, practical, and enantioselective method for synthesis of homoallenylamides catalyzed by an aminoalcohol-derived, boron-based catalystA broadly applicable NHC-Cu-catalyzed approach for efficient, site-, and enantioselective coupling of readily accessible (pinacolato)alkenylboron compounds to allylic phosphates and applications to natural product synthesis.NHC-Cu-catalyzed addition of propargylboron reagents to phosphinoylimines. Enantioselective synthesis of trimethylsilyl-substituted homoallenylamides and application to the synthesis of S-(-)-cyclooroidin.N-Phosphonyl/phosphinyl imines and group-assisted purification (GAP) chemistry/technology.Design, synthesis, and applications of chiral N-2-phenyl-2-propyl sulfinyl imines for group-assisted purification (GAP) asymmetric synthesisSite- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution.The isomerization of allylrhodium intermediates in the rhodium-catalyzed nucleophilic allylation of cyclic imines.N-Substituted tertiary and O-substituted quaternary carbon stereogenic centers by site-, diastereo- and enantioselective vinylogous Mannich reactions.Enantioselective copper catalysed, direct functionalisation of allenes via allyl copper intermediates.Enantioselective Generation of Adjacent Stereocenters in a Copper-Catalyzed Three-Component Coupling of Imines, Allenes, and DiboranesNi- and Pd-catalyzed synthesis of substituted and functionalized allylic boronates.A robust, efficient, and highly enantioselective method for synthesis of homopropargyl aminesCatalytic Asymmetric Allylboration of Indoles and Dihydroisoquinolines with Allylboronic Acids: Stereodivergent Synthesis of up to Three Contiguous Stereocenters.Copper-Catalyzed Borylative Cross-Coupling of Allenes and Imines: Selective Three-Component Assembly of Branched Homoallyl Amines.Enantioselective carbocycle formation through intramolecular Pd-catalyzed allyl-aryl cross-coupling.Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes.Catalytic asymmetric three-component synthesis of homoallylic amines.Sequential Ruthenium Catalysis for Olefin Isomerization and Oxidation: Application to the Synthesis of Unusual Amino Acids.Exceptionally E- and β-selective NHC-Cu-catalyzed proto-silyl additions to terminal alkynes and site- and enantioselective proto-boryl additions to the resulting vinylsilanes: synthesis of enantiomerically enriched vicinal and geminal borosilanes.Cobalt-Catalyzed Asymmetric Allylation of Cyclic Ketimines.Copper-Catalyzed Borylcupration of Allenylsilanes.Highly Diastereo- and Enantioselective Cu-Catalyzed Borylative Coupling of 1,3-Dienes and Aldimines.New catalysts with unsymmetrical N-heterocyclic carbene ligands.Enantioselective synthesis of β-substituted chiral allylic amines via Rh-catalyzed asymmetric hydrogenation.Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: dual stereocontrol with nearly perfect diastereoselectivity.Synthesis of P-stereogenic diarylphosphinic amides by directed lithiation: transformation into tertiary phosphine oxides via methanolysis, aryne chemistry and complexation behaviour toward zinc(ii).
P2860
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P2860
Enantioselective synthesis of homoallylic amines through reactions of (pinacolato)allylborons with aryl-, heteroaryl-, alkyl-, or alkene-substituted aldimines catalyzed by chiral C1-symmetric NHC-Cu complexes.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
2011年论文
@zh
2011年论文
@zh-cn
name
Enantioselective synthesis of ...... C1-symmetric NHC-Cu complexes.
@en
Enantioselective synthesis of ...... C1-symmetric NHC-Cu complexes.
@nl
type
label
Enantioselective synthesis of ...... C1-symmetric NHC-Cu complexes.
@en
Enantioselective synthesis of ...... C1-symmetric NHC-Cu complexes.
@nl
prefLabel
Enantioselective synthesis of ...... C1-symmetric NHC-Cu complexes.
@en
Enantioselective synthesis of ...... C1-symmetric NHC-Cu complexes.
@nl
P2860
P356
P1476
Enantioselective synthesis of ...... C1-symmetric NHC-Cu complexes.
@en
P2093
Erika M Vieira
Marc L Snapper
P2860
P304
P356
10.1021/JA200311N
P407
P577
2011-02-22T00:00:00Z