Enantioselective synthesis of allylboronates bearing a tertiary or quaternary B-substituted stereogenic carbon by NHC-Cu-catalyzed substitution reactions.
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Multifunctional organoboron compounds for scalable natural product synthesis.Axial preferences in allylations via the Zimmerman-Traxler transition state.Enantioselective 1,1-arylborylation of alkenes: merging chiral anion phase transfer with Pd catalysis.Nickel-catalyzed coupling reactions of alkyl electrophiles, including unactivated tertiary halides, to generate carbon-boron bonds.A direct approach to amines with remote stereocentres by enantioselective CuH-catalysed reductive relay hydroaminationSimple organic molecules as catalysts for enantioselective synthesis of amines and alcoholsCatalytic asymmetric synthesis of allylic alcohols and derivatives and their applications in organic synthesis.Nickel-Catalyzed Borylation of Benzylic Ammonium Salts: Stereospecific Synthesis of Enantioenriched Benzylic Boronates.A catalytic enantiotopic-group-selective Suzuki reaction for the construction of chiral organoboronates.Evolution of catalytic stereoselective olefin metathesis: from ancillary transformation to purveyor of stereochemical identity.Accessing Both Retention and Inversion Pathways in Stereospecific, Nickel-Catalyzed Miyaura Borylations of Allylic Pivalates.Quaternary carbon stereogenic centers through copper-catalyzed enantioselective allylic substitutions with readily accessible aryl- or heteroaryllithium reagents and aluminum chlorides.Mechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to α,β-Unsaturated Carbonyl Compounds.Kinetic resolution of racemic 2-substituted 1,2-dihydroquinolines via asymmetric Cu-catalyzed borylationEnantioselective synthesis of alkyne-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution reactions with (i-Bu)2(alkynyl)aluminum reagents.Nonracemic allylic boronates through enantiotopic-group-selective cross-coupling of geminal bis(boronates) and vinyl halides.Enantioselective synthesis of boron-substituted quaternary carbons by NHC-Cu-catalyzed boronate conjugate additions to unsaturated carboxylic esters, ketones, or thioesters.Synthesis of quaternary carbon stereogenic centers through enantioselective Cu-catalyzed allylic substitutions with vinylaluminum reagents.Catalytic enantioselective 1,2-diboration of 1,3-dienes: versatile reagents for stereoselective allylation.A robust, efficient, and highly enantioselective method for synthesis of homopropargyl aminesEnantioselective palladium-catalyzed diboration of 1,1-disubstituted allenes.Catalytic asymmetric synthesis of chiral allylic esters.Enantioselective synthesis of homoallylic amines through reactions of (pinacolato)allylborons with aryl-, heteroaryl-, alkyl-, or alkene-substituted aldimines catalyzed by chiral C1-symmetric NHC-Cu complexes.Enantioselective synthesis of boron-substituted quaternary carbon stereogenic centers through NHC-catalyzed conjugate additions of (pinacolato)boron units to enones.Synthesis of Chiral Tertiary Boronic Esters by Oxime-Directed Catalytic Asymmetric Hydroboration.Enantioselective carbocycle formation through intramolecular Pd-catalyzed allyl-aryl cross-coupling.Asymmetric synthesis of α-chiral allylic silanes by enantioconvergent γ-selective copper(I)-catalyzed allylic silylation.Highly stereoselective synthesis of Z-homoallylic alcohols by kinetic resolution of racemic secondary allyl boronates.Mechanism-based enhancement of scope and enantioselectivity for reactions involving a copper-substituted stereogenic carbon centre.Copper(I)-Catalyzed Enantioselective Nucleophilic Borylation of Aliphatic Ketones: Synthesis of Enantioenriched Chiral Tertiary α-Hydroxyboronates.Practical, Broadly Applicable, α-Selective, Z-Selective, Diastereoselective, and Enantioselective Addition of Allylboron Compounds to Mono-, Di-, Tri-, and Polyfluoroalkyl Ketones.Catalytic diastereo- and enantioselective additions of versatile allyl groups to N-H ketimines.Enantioselective Conjunctive Cross-Coupling of Bis(alkenyl)borates: A General Synthesis of Chiral Allylboron Reagents.One-pot three-component highly selective synthesis of homoallylboronates by using metal-free catalysis.One-pot three-component catalytic enantioselective synthesis of homoallylboronates.New catalysts with unsymmetrical N-heterocyclic carbene ligands.Iterative asymmetric allylic substitutions: syn- and anti-1,2-diols through catalyst control.Practical, efficient, and broadly applicable synthesis of readily differentiable vicinal diboronate compounds by catalytic three-component reactions.Highly Enantioselective Synthesis of Tertiary Boronic Esters and their Stereospecific Conversion to other Functional Groups and Quaternary Stereocentres
P2860
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P2860
Enantioselective synthesis of allylboronates bearing a tertiary or quaternary B-substituted stereogenic carbon by NHC-Cu-catalyzed substitution reactions.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Enantioselective synthesis of ...... alyzed substitution reactions.
@en
type
label
Enantioselective synthesis of ...... alyzed substitution reactions.
@en
prefLabel
Enantioselective synthesis of ...... alyzed substitution reactions.
@en
P2860
P356
P1476
Enantioselective synthesis of ...... alyzed substitution reactions.
@en
P2093
Aikomari Guzman-Martinez
Amir H Hoveyda
P2860
P304
10634-10637
P356
10.1021/JA104254D
P407
P577
2010-08-01T00:00:00Z