Improved catalysts for the palladium-catalyzed synthesis of oxindoles by amide alpha-arylation. Rate acceleration, use of aryl chloride substrates, and a new carbene ligand for asymmetric transformations.
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Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickelSynthesis of chiral mono(N-heterocyclic carbene) palladium and gold complexes with a 1,1'-biphenyl scaffold and their applications in catalysis.Ethylene in organic synthesis: a new route to anticholenergic pyrrolidinoindolines, and other molecules with all carbon-quaternary centers via asymmetric hydrovinylation.The palladium catalyzed asymmetric addition of oxindoles and allenes: an atom-economical versatile method for the construction of chiral indole alkaloids3,3'-[1,2-Phenyl-enebis(methyl-ene)]bis-(1-propyl-benzimidazolium) dibromide hemihydrateChiral N-heterocyclic carbenes as stereodirecting ligands in asymmetric catalysis.A Palladium Catalyst System for the Efficient Cross-Coupling Reaction of Aryl Bromides and Chlorides with Phenylboronic Acid: Synthesis and Biological Activity Evaluation.Rotational isomers of N-methyl-N-arylacetamides and their derived enolates: implications for asymmetric Hartwig oxindole cyclizations.Molybdenum-catalyzed asymmetric allylic alkylation of 3-alkyloxindoles: reaction development and applicationsAcOLeDMAP and BnOLeDMAP: conformationally restricted nucleophilic catalysts for enantioselective rearrangement of indolyl acetates and carbonates.Preparation of Aryl-Susbstituted 2-Oxyindoles by Superelectrophilic Chemistry.Synthesis of Pd Complexes Bearing an Enantiomerically-Resolved Seven-Membered N-Heterocyclic Carbene Ligands and Initial Studies of their Use in Asymmetric Wacker-Type Oxidative Cyclization ReactionsAsymmetric palladium-catalyzed intramolecular alpha-arylation of aldehydesMetal-catalyzed alpha-arylation of carbonyl and related molecules: novel trends in C-C bond formation by C-H bond functionalization.A General and Practical Palladium-Catalyzed Direct α-Arylation of Amides with Aryl Halides.N-Heterocyclic carbene transition metal complexes for catalysis in aqueous media.Recent trends in Pd-catalyzed remote functionalization of carbonyl compounds.Nickel-catalyzed asymmetric α-arylation and heteroarylation of ketones with chloroarenes: effect of halide on selectivity, oxidation state, and room-temperature reactions.Enantioselective construction of all-carbon quaternary centers by branch-selective Pd-catalyzed allyl-allyl cross-coupling.Asymmetric conjugate addition of oxindoles to 2-chloroacrylonitrile: a highly effective organocatalytic strategy for simultaneous construction of 1,3-nonadjacent stereocenters leading to chiral pyrroloindolines.Asymmetric Michael addition reaction of 3-substituted-N-Boc oxindoles to activated terminal alkenes catalyzed by a bifunctional tertiary-amine thiourea catalyst.Facile creation of 3-substituted-3-hydroxy-2-oxindoles by arginine-catalyzed aldol reactions of α,β-unsaturated ketones with isatins.Arene CH-O hydrogen bonding: a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones.Synthesis of 3,3-Disubstituted Oxindoles by Palladium-Catalyzed Asymmetric Intramolecular α-Arylation of Amides: Reaction Development and Mechanistic Studies.A Lewis acid-promoted cyclization of ethenetricarboxylate derivative aromatic compounds. Novel syntheses of oxindoles and benzofuranones via Friedel-Crafts intramolecular Michael addition.Weak arene C-H···O hydrogen bonding in palladium-catalyzed arylation and vinylation of lactones.Chiral palladium(II) complexes possessing a tridentate N-heterocyclic carbene amidate alkoxide ligand: access to oxygen-bridging dimer structures.Pd-catalyzed carbonylative α-arylation of aryl bromides: scope and mechanistic studies.Pyridine-enhanced head-to-tail dimerization of terminal alkynes by a rhodium-N-heterocyclic-carbene catalyst.Synthesis of C₂-Symmetric Benzimidazolium Salts and Their Application in Palladium-Catalyzed Enantioselective Intramolecular α-Arylation of Amides.Transition-metal-free Chemoselective Oxidative C-C Coupling of the sp3 C-H Bond of Oxindoles with Arenes and Addition to Alkene: Synthesis of 3-Aryl Oxindoles, and Benzofuro- and Indoloindoles.Palladium-catalyzed C(sp(3))-H activation: a facile method for the synthesis of 3,4-dihydroquinolinone derivatives.Regioselective synthesis of 3-anthracenyloxindoles and 3-carbazolyloxindoles by indium(iii)-catalyzed direct arylation and their fluorescent chemosensor properties.Synthesis and characterization of conformationally rigid chiral pyridine-N-heterocyclic carbene-based palladacycles with an unexpected Pd-N bond cleavage.Visible light induced radical cyclization of o-iodophenylacrylamides: a concise synthesis of indolin-2-one.A planar chiral [2.2]paracyclophane derived N-heterocyclic stannyleneEnantioselective α-Arylation of Cyclic Ketones Catalyzed by a Combination of an Unmodified Cinchona Alkaloid and a Palladium ComplexSynthetic Studies towards Communesins: Diastereoselective Oxidative Rearrangement of Aurantioclavine DerivativesPalladium-Catalyzed Amidation by Chemoselective C(sp3)H Activation: Concise Route to Oxindoles Using a Carbamoyl Chloride PrecursorPalladium-Catalyzed Amidation by Chemoselective C(sp3)H Activation: Concise Route to Oxindoles Using a Carbamoyl Chloride Precursor
P2860
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P2860
Improved catalysts for the palladium-catalyzed synthesis of oxindoles by amide alpha-arylation. Rate acceleration, use of aryl chloride substrates, and a new carbene ligand for asymmetric transformations.
description
2001 nî lūn-bûn
@nan
2001年の論文
@ja
2001年学术文章
@wuu
2001年学术文章
@zh-cn
2001年学术文章
@zh-hans
2001年学术文章
@zh-my
2001年学术文章
@zh-sg
2001年學術文章
@yue
2001年學術文章
@zh
2001年學術文章
@zh-hant
name
Improved catalysts for the pal ...... or asymmetric transformations.
@en
Improved catalysts for the pal ...... or asymmetric transformations.
@nl
type
label
Improved catalysts for the pal ...... or asymmetric transformations.
@en
Improved catalysts for the pal ...... or asymmetric transformations.
@nl
prefLabel
Improved catalysts for the pal ...... or asymmetric transformations.
@en
Improved catalysts for the pal ...... or asymmetric transformations.
@nl
P356
P1476
Improved catalysts for the pal ...... or asymmetric transformations.
@en
P2093
P304
P356
10.1021/JO005761Z
P407
P577
2001-05-01T00:00:00Z