Revisiting the mechanism of P450 enzymes with the radical clocks norcarane and spiro[2,5]octane.
about
Radical intermediates in the catalytic oxidation of hydrocarbons by bacterial and human cytochrome P450 enzymesHydrocarbon hydroxylation by cytochrome P450 enzymesMechanistic aspects of CYP74 allene oxide synthases and related cytochrome P450 enzymesProbing 'spin-forbidden' oxygen-atom transfer: gas-phase reactions of chromium-porphyrin complexesOxidative aliphatic C-H fluorination with fluoride ion catalyzed by a manganese porphyrin.Molecular probes of the mechanism of cytochrome P450. Oxygen traps a substrate radical intermediateThe bioinorganic chemistry of iron in oxygenases and supramolecular assemblies.Differences and comparisons of the properties and reactivities of iron(III)-hydroperoxo complexes with saturated coordination sphereCytochrome P450: what have we learned and what are the future issues?Parallel and competitive pathways for substrate desaturation, hydroxylation, and radical rearrangement by the non-heme diiron hydroxylase AlkB.Selective hydroxylation of alkanes by an extracellular fungal peroxygenase.Reactivity patterns of cytochrome P450 enzymes: multifunctionality of the active species, and the two states-two oxidants conundrum.Non-Redox Assisted Oxygen-Oxygen Bond Homolysis in Titanocene Alkylperoxide Complexes: [Cp(2)Ti(eta-OOBu)L], L = Cl, OTf, Br, OEt(2), Et(3)P.Unusual cytochrome p450 enzymes and reactions.Identity and mechanisms of alkane-oxidizing metalloenzymes from deep-sea hydrothermal vents.Catalytic strategy for carbon-carbon bond scission by the cytochrome P450 OleT.Beyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C-H activation.Generation of complexity in fungal terpene biosynthesis: discovery of a multifunctional cytochrome P450 in the fumagillin pathway.Rearrangement reactions catalyzed by cytochrome P450s.The Enigmatic P450 Decarboxylase OleT Is Capable of, but Evolved To Frustrate, Oxygen Rebound Chemistry.Divergent mechanisms of iron-containing enzymes for hydrocarbon biosynthesis.Desaturase reactions complicate the use of norcarane as a mechanistic probe. Unraveling the mixture of twenty-plus products formed in enzyme-catalyzed oxidations of norcarane.How a [Co(IV) a bond and a half O](2+) fragment oxidizes water: involvement of a biradicaloid [Co(II)-(⋅O⋅)](2+) species in forming the O-O bond.The Cytochrome P450-Catalyzed Oxidative Rearrangement in the Final Step of Pentalenolactone Biosynthesis: Substrate Structure Determines MechanismRadical rebound mechanism in cytochrome P-450-catalyzed hydroxylation of the multifaceted radical clocks alpha- and beta-thujone.Cyclopropyl fatty acids implicate a radical but not a cation as an intermediate in P450BM3-catalysed hydroxylations.Structure and function of the cytochrome P450 peroxygenase enzymes.Formation and characterization of a reactive chromium(v)-oxo complex: mechanistic insight into hydrogen-atom transfer reactions.A comprehensive test set of epoxidation rate constants for iron(iv)-oxo porphyrin cation radical complexes.
P2860
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P2860
Revisiting the mechanism of P450 enzymes with the radical clocks norcarane and spiro[2,5]octane.
description
2002 nî lūn-bûn
@nan
2002年の論文
@ja
2002年学术文章
@wuu
2002年学术文章
@zh
2002年学术文章
@zh-cn
2002年学术文章
@zh-hans
2002年学术文章
@zh-my
2002年学术文章
@zh-sg
2002年學術文章
@yue
2002年學術文章
@zh-hant
name
Revisiting the mechanism of P4 ...... orcarane and spiro[2,5]octane.
@en
Revisiting the mechanism of P4 ...... orcarane and spiro[2,5]octane.
@nl
type
label
Revisiting the mechanism of P4 ...... orcarane and spiro[2,5]octane.
@en
Revisiting the mechanism of P4 ...... orcarane and spiro[2,5]octane.
@nl
prefLabel
Revisiting the mechanism of P4 ...... orcarane and spiro[2,5]octane.
@en
Revisiting the mechanism of P4 ...... orcarane and spiro[2,5]octane.
@nl
P2093
P356
P1476
Revisiting the mechanism of P4 ...... orcarane and spiro[2,5]octane.
@en
P2093
Dorothy M Little
John T Groves
Karine Auclair
Paul R Ortiz De Montellano
Zhengbo Hu
P304
P356
10.1021/JA025608H
P407
P577
2002-05-01T00:00:00Z