A stable silicon-based allene analogue with a formally sp-hybridized silicon atom.
about
New perspectives for "non-classical" molecules: heavy [1.1.1]propellanes of group 14.Bonding and structure of disilenes and related unsaturated group-14 element compounds.New bonding modes of carbon and heavier group 14 atoms Si-Pb.Reactivity in the periphery of functionalised multiple bonds of heavier group 14 elements.Advances in Phosphasilene Chemistry.Stable singlet carbenes as mimics for transition metal centers.A Brief Survey of our Contribution to Stable Carbene Chemistry.Diazabutadiene complexes of selenium as Se2+ transfer reagents.The role of 2,6-diaminopyridine ligands in the isolation of an unprecedented, low-valent tin complex.A stable singlet biradicaloid siladicarbene: (L:)2Si.A mechanistic analysis of the tetrasilyl-substituted trimetallaallenes, >E=E=E< (E = C, Si, Ge, Sn, and Pb).A coordination compound of Ge(0) stabilized by a diiminopyridine ligand.Reduction of the dihalocyclopentasilanes. A quest for a homocyclic silylene.Distinguishing carbones from allenes by complexation to AuCl.Isolation of an imino-N-heterocyclic carbene/germanium(0) adduct: a mesoionic germylene equivalent.Bonding in Heavier Group 14 Zero-Valent Complexes-A Combined Maximum Probability Domain and Valence Bond Theory Approach.Highly Bent 1,3-Digerma-2-silaallene.A Bis(silylenyl)pyridine Zero-Valent Germanium Complex and Its Remarkable Reactivity.π-Electron systems containing Si=Si double bonds.Synthesis, characterization, and electronic structures of a methyl germyliumylidene ion and germylone-group VI metal complexes.A cyclic silylone ("siladicarbene") with an electron-rich silicon(0) atom.Donor-acceptor bonding in novel low-coordinated compounds of boron and group-14 atoms C-Sn.Reactions of an Isolable Dialkylsilylene with Aroyl Chlorides. A New Route to Aroylsilanes.Borylene Complexes (BH)L2 and Nitrogen Cation Complexes (N+)L2: Isoelectronic Homologues of Carbones CL2Charge Density and Chemical BondingExperimental Charge Density Study of a SilyloneExperimentelle Elektronendichteuntersuchung eines SilylonsEin stabiles biradikaloides Singulett-Siladicarben: (L:)2Si
P2860
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P2860
A stable silicon-based allene analogue with a formally sp-hybridized silicon atom.
description
2003 nî lūn-bûn
@nan
2003年の論文
@ja
2003年学术文章
@wuu
2003年学术文章
@zh-cn
2003年学术文章
@zh-hans
2003年学术文章
@zh-my
2003年学术文章
@zh-sg
2003年學術文章
@yue
2003年學術文章
@zh
2003年學術文章
@zh-hant
name
A stable silicon-based allene analogue with a formally sp-hybridized silicon atom.
@en
A stable silicon-based allene analogue with a formally sp-hybridized silicon atom.
@nl
type
label
A stable silicon-based allene analogue with a formally sp-hybridized silicon atom.
@en
A stable silicon-based allene analogue with a formally sp-hybridized silicon atom.
@nl
prefLabel
A stable silicon-based allene analogue with a formally sp-hybridized silicon atom.
@en
A stable silicon-based allene analogue with a formally sp-hybridized silicon atom.
@nl
P356
P1433
P1476
A stable silicon-based allene analogue with a formally sp-hybridized silicon atom
@en
P2888
P304
P356
10.1038/NATURE01380
P407
P577
2003-02-01T00:00:00Z
P6179
1032368669