about
Persistent Dialkylsilanone Generated by Dehydrobromination of Dialkylbromosilanol.A stable fused bicyclic disilene as a model for silicon surface.Transformation of azulenes to bicyclic [4]dendralene and heptafulvene derivatives via photochemical cycloaddition of dialkylsilylene.Tethered 1,2-Si-Group Migrations in Radical-Mediated Ring Enlargements of Cyclic Alkoxysilanes: An EPR Spectroscopic and Computational Investigation.Persistent four-coordinate iron-centered radical stabilized by π-donation.The first 1,3-disilabicyclo[1.1.0]butane with long-bridge silicon-silicon bond.Excited-state reactions of an isolable silylene with aromatic compounds.A stable silicon-based allene analogue with a formally sp-hybridized silicon atom.Radical anion of isolable dialkylsilylene.Ligand dependence of pi-complex character in disilene-palladium complexes.An Isolable Potassium Salt of a Borasilene-Chloride Adduct.A Potassium Diboryllithate: Synthesis, Bonding Properties, and the Deprotonation of Benzene.Pentasila-1,4-diene: Homoconjugation between Si═Si Double Bonds via a SiMe(2) Unit.Benzodisilacyclobutadienes: 8π-Electron Systems with an Antiaromatic Silicon Ring.Stable Push-Pull Disilene: Substantial Donor-Acceptor Interactions through the Si═Si Double Bond.Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene.Facile synthesis and bridgehead-functionalization of bicyclo[3.3.3]pentasiloxanes.Palladium and platinum η(2) -disilyne complexes bearing an isolable dialkyldisilyne as a ligand.Synthesis, structure, and bonding of stable dialkylsilaketenimines.New isolable dialkylsilylene and its isolable dimer that equilibrate in solution.Synthesis, properties, and reactions of a series of stable dialkyl-substituted silicon-chalcogen doubly bonded compounds.Near-IR absorbing nickel(II) porphyrinoids prepared by regioselective insertion of silylenes into antiaromatic nickel(II) norcorrole.A Pt(0) complex with cyclic (alkyl)(amino)silylene and 1,3-divinyl-1,1,3,3-tetramethyldisiloxane ligands: synthesis, molecular structure, and catalytic hydrosilylation activity.Fused Tricyclic Disilenes with Highly Strained SiSi Double Bonds: Addition of a SiSi Single Bond to a SiSi Double BondProbing the reactivity of a stable silene using muoniumThe singlet excited state of a stable dialkylsilylene is responsible for its photoreactionsThermal and photochemical cleavage of Si=Si double bond in tetrasila-1,3-dieneFourteen-electron bis(dialkylsilylene)palladium and twelve-electron bis(dialkylsilyl)palladium complexesDesign of chiral bis-phosphoric acid catalyst derived from (R)-3,3'-di(2-hydroxy-3-arylphenyl)binaphthol: catalytic enantioselective Diels-Alder reaction of α,β-unsaturated aldehydes with amidodienesPersilastaffanes: design, synthesis, structure, and conjugation between silicon cagesConcise synthesis of halogenated chrysenes ([4]phenacenes) that favor pi-stack packing in single crystalsA stable dialkylphosphinyl radicalSynthesis and structures of (dialkylsilylene)bis(phosphine)-nickel, palladium, and platinum complexes and (η(6)-arene)(dialkylsilylene)nickel complexesA two-coordinate palladium complex with two dialkylphosphinyl ligandsA heavy analogue of the smallest bridgehead alkene stabilized by a baseAnthryl-substituted 3-silylene-2-silaaziridine obtained by isomerization of disilacyclopropanimine: an exocyclic silene showing a distinct intramolecular charge transfer transitionPersistent antimony- and bismuth-centered radicals in solutionIsolable 2,3-disila-1,3-butadiene from a double sila-Peterson reactionCleavage of Two Hydrogen Molecules by BoryldisilenesHeteroaryldisilenes: heteroaryl groups serve as electron acceptors for Si[double bond, length as m-dash]Si double bonds in intramolecular charge transfer transitions
P50
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P50
description
researcher
@en
wetenschapper
@nl
հետազոտող
@hy
name
Takeaki Iwamoto
@ast
Takeaki Iwamoto
@en
Takeaki Iwamoto
@es
Takeaki Iwamoto
@nl
Takeaki Iwamoto
@sl
type
label
Takeaki Iwamoto
@ast
Takeaki Iwamoto
@en
Takeaki Iwamoto
@es
Takeaki Iwamoto
@nl
Takeaki Iwamoto
@sl
prefLabel
Takeaki Iwamoto
@ast
Takeaki Iwamoto
@en
Takeaki Iwamoto
@es
Takeaki Iwamoto
@nl
Takeaki Iwamoto
@sl
P106
P31
P496
0000-0002-8556-5785