Silicon(II) coordination chemistry: N-heterocyclic carbene complexes of Si2+ and SiI+.
about
[2+2+1] cycloadditions of bis(dialkylamino)acetylenes with SiI2(Idip): syntheses and reactivity studies of unprecedented 2,3,4,5-tetraamino-1 H-siloles.Synthetic chemistry with nitrous oxide.Reactive p-block cations stabilized by weakly coordinating anions.Cations and dications of heavier group 14 elements in low oxidation states.A Route to Base Coordinate Silicon Difluoride and the Silicon Trifluoride Radical.NHC→SiCl4 : an ambivalent carbene-transfer reagent.Si=Si Double Bonds: Synthesis of an NHC-Stabilized Disilavinylidene.A Disilene Base Adduct with a Dative Si-Si Single Bond.Trapping a Silicon(I) Radical with Carbenes: A Cationic cAAC-Silicon(I) Radical and an NHC-Parent-Silyliumylidene Cation.From an Isolable Acyclic Phosphinosilylene Adduct to Donor-Stabilized Si=E Compounds (E=O, S, Se).An Isolable Potassium Salt of a Borasilene-Chloride Adduct.Isolation and Structure of Germylene-Germyliumylidenes Stabilized by N-Heterocyclic Imines.Insertion of Group 12-16 Hydrides into NHCs: A Theoretical Investigation.One-Electron Oxidation of a Disilicon(0) Compound: An Experimental and Theoretical Study of [Si2](+) Trapped by N-Heterocyclic Carbenes.A facile access to a novel NHC-stabilized silyliumylidene ion and C-H activation of phenylacetylene.Reactivity of an NHC-stabilized silylene towards ketones. Formation of silicon bis-enolates vs. bis-silylation of the C[double bond, length as m-dash]O bond.Silicon-oxygen double bonds: a stable silanone with a trigonal-planar coordinated silicon center.Anorganische Chemie 2013
P2860
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P2860
Silicon(II) coordination chemistry: N-heterocyclic carbene complexes of Si2+ and SiI+.
description
2013 nî lūn-bûn
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2013年の論文
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2013年学术文章
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2013年学术文章
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2013年学术文章
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2013年学术文章
@zh-hans
2013年学术文章
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2013年学术文章
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2013年學術文章
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name
Silicon(II) coordination chemistry: N-heterocyclic carbene complexes of Si2+ and SiI+.
@en
type
label
Silicon(II) coordination chemistry: N-heterocyclic carbene complexes of Si2+ and SiI+.
@en
prefLabel
Silicon(II) coordination chemistry: N-heterocyclic carbene complexes of Si2+ and SiI+.
@en
P2093
P2860
P356
P1476
Silicon(II) coordination chemistry: N-heterocyclic carbene complexes of Si2+ and SiI+.
@en
P2093
Alexander C Filippou
Gregor Schnakenburg
Martin Straßmann
Oleg Chernov
Yury N Lebedev
P2860
P304
P356
10.1002/ANIE.201301363
P407
P577
2013-05-27T00:00:00Z