Diketiminate silicon(II) and related NHSi ligands generated in the coordination sphere of nickel(0).
about
Formation of N-heterocyclic, donor-stabilized borenium ions.New vistas in N-heterocyclic silylene (NHSi) transition-metal coordination chemistry: syntheses, structures and reactivity towards activation of small molecules.Silicon(II) coordination chemistry: N-heterocyclic carbene complexes of Si2+ and SiI+.Reaction of N-heterocyclic silylenes with thioketone: formation of silicon-sulfur three (Si-C-S)- and five (Si-C-C-C-S)-membered ring systems.Facile cyclometallation of a mesitylsilylene: synthesis and preliminary catalytic activity of iridium(iii) and iridium(v) iridasilacyclopentenes.Donor-Stabilized Silylene/Phosphine-Supported Carbon(0) Center with High Electron Density.Pushing the σ-donor strength in iridium pincer complexes: bis(silylene) and bis(germylene) ligands are stronger donors than bis(phosphorus(III)) ligands.Synthesis and unexpected coordination of a silicon(II)-based SiCSi pincerlike arene to palladium.Versatile conversion of N-heterocyclic silylene to silyl metal compounds by insertion of divalent silicon into metal-carbon and metal-hydrogen bonds.Exceptionally Strong Electron-Donating Ability of Bora-Ylide Substituent vis-à-vis Silylene and Silylium Ion.A zwitterionic hydrocarbon-soluble borenium ion based on a β-diketiminate backbone.Facile Access to Transition-Metal-Carbonyl Complexes with an Amidinate-Stabilized Chlorosilylene LigandSyntheses of Iron Carbonyl N-Heterocyclic Stannylene ComplexesFacile Synthesis of a Rare Chlorosilylene-BH3 Adduct
P2860
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P2860
Diketiminate silicon(II) and related NHSi ligands generated in the coordination sphere of nickel(0).
description
2009 nî lūn-bûn
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2009年の論文
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2009年学术文章
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2009年学术文章
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2009年学术文章
@zh-cn
2009年学术文章
@zh-hans
2009年学术文章
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2009年學術文章
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name
Diketiminate silicon
@nl
Diketiminate silicon(II) and r ...... rdination sphere of nickel(0).
@en
type
label
Diketiminate silicon
@nl
Diketiminate silicon(II) and r ...... rdination sphere of nickel(0).
@en
prefLabel
Diketiminate silicon
@nl
Diketiminate silicon(II) and r ...... rdination sphere of nickel(0).
@en
P356
P1476
Diketiminate silicon(II) and r ...... rdination sphere of nickel(0).
@en
P2093
Antje Meltzer
Carsten Präsang
P304
P356
10.1021/JA9026727
P407
P577
2009-06-01T00:00:00Z