Ligand-dependent scope and divergent mechanistic behavior in nickel-catalyzed reductive couplings of aldehydes and alkynes.
about
Diaminocarbene- and Fischer-carbene complexes of palladium and nickel by oxidative insertion: preparation, structure, and catalytic activity.Cooperativity of regiochemistry control strategies in reductive couplings of propargyl alcohols and aldehydesOne-pot catalytic enantio- and diastereoselective syntheses of anti-, syn-cis-disubstituted, and syn-vinyl cyclopropyl alcoholsKetone hydrosilylation with sugar silanes followed by intramolecular aglycone delivery: an orthogonal glycosylation strategy.Mechanism and transition-state structures for nickel-catalyzed reductive alkyne-aldehyde coupling reactions.Origins of regioselectivity and alkene-directing effects in nickel-catalyzed reductive couplings of alkynes and aldehydesNickel-catalyzed cycloadditions of unsaturated hydrocarbons, aldehydes, and ketones.Dimer involvement and origin of crossover in nickel-catalyzed aldehyde-alkyne reductive couplingsTotal syntheses of amphidinolides T1 and T4 via catalytic, stereoselective, reductive macrocyclizationsRegiocontrol in catalytic reductive couplings through alterations of silane rate dependenceMechanism and origins of regio- and enantioselectivities in RhI-catalyzed hydrogenative couplings of 1,3-diynes and activated carbonyl partners: intervention of a cumulene intermediateMechanistic Basis for Regioselection and Regiodivergence in Nickel-Catalyzed Reductive CouplingsFormation of C-C Bonds via Catalytic Hydrogenation and Transfer Hydrogenation: Vinylation, Allylation, and Enolate Addition of Carbonyl Compounds and IminesNickel Catalysis: Synergy between Method Development and Total SynthesisFormation of C-C bonds via ruthenium-catalyzed transfer hydrogenation().The regio- and stereochemical course of reductive cross-coupling reactions between 1,3-disubstituted allenes and vinylsilanes: Synthesis of (Z)-dienes.Highly diastereoselective preparation of anti-1,2-diols by catalytic addition of alkynylsilanes to alpha-silyloxyaldehydes.Catalytic carbonyl addition through transfer hydrogenation: a departure from preformed organometallic reagents.Convergent synthesis of piperidines by the union of conjugated alkynes with imines: a unique regioselective bond construction for heterocycle synthesis.Regioselective Reductive Cross-Coupling Reactions of Unsymmetrical Alkynes.Formation of C-C Bonds via Iridium-Catalyzed Hydrogenation and Transfer Hydrogenation.Catalytic asymmetric synthesis of allylic alcohols and derivatives and their applications in organic synthesis.Direct vinylation of alcohols or aldehydes employing alkynes as vinyl donors: a ruthenium catalyzed C-C bond-forming transfer hydrogenation.A convergent route to the CDEF-tetracycle of pectenotoxin-2.Catalytic enantioselective OFF ↔ ON activation processes initiated by hydrogen transfer: concepts and challenges.Alkyne-aldehyde reductive C-C coupling through ruthenium-catalyzed transfer hydrogenation: direct regio- and stereoselective carbonyl vinylation to form trisubstituted allylic alcohols in the absence of premetallated reagents.1,1-Disubstituted olefin synthesis via Ni-catalyzed Markovnikov hydroalkylation of alkynes with alkyl halides.A general strategy for regiocontrol in nickel-catalyzed reductive couplings of aldehydes and alkynes.Diastereoselective Nickel-Catalyzed Reductive Couplings of Aminoaldehydes and Alkynylsilanes: Application to the Synthesis of D-erythro-Sphingosine.Synthetic studies and mechanistic insight in nickel-catalyzed [4+2+1] cycloadditions.Breaking Amides using Nickel Catalysis.Mechanistic study of nickel-catalyzed ynal reductive cyclizations through kinetic analysis.Hydroacylation of 2-Butyne from the Alcohol or Aldehyde Oxidation Level via Ruthenium Catalyzed C-C Bond Forming Transfer Hydrogenation.Regioselectivity and enantioselectivity in nickel-catalysed reductive coupling reactions of alkynes.New N-heterocyclic carbene ligand and its application in asymmetric nickel-catalyzed aldehyde/alkyne reductive couplings.Metallacycle-Mediated Cross-Coupling in Natural Product Synthesis.Catalytic Hydroalkylation of Allenes.Diboron as a reductant for nickel-catalyzed reductive coupling: rational design and mechanistic studies.Synthetic Applications of the Nickel-Catalyzed Cyclization of Alkynes Combined with Addition Reactions in a Domino Process
P2860
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P2860
Ligand-dependent scope and divergent mechanistic behavior in nickel-catalyzed reductive couplings of aldehydes and alkynes.
description
2004 nî lūn-bûn
@nan
2004年の論文
@ja
2004年学术文章
@wuu
2004年学术文章
@zh
2004年学术文章
@zh-cn
2004年学术文章
@zh-hans
2004年学术文章
@zh-my
2004年学术文章
@zh-sg
2004年學術文章
@yue
2004年學術文章
@zh-hant
name
Ligand-dependent scope and div ...... ings of aldehydes and alkynes.
@en
Ligand-dependent scope and div ...... ings of aldehydes and alkynes.
@nl
type
label
Ligand-dependent scope and div ...... ings of aldehydes and alkynes.
@en
Ligand-dependent scope and div ...... ings of aldehydes and alkynes.
@nl
prefLabel
Ligand-dependent scope and div ...... ings of aldehydes and alkynes.
@en
Ligand-dependent scope and div ...... ings of aldehydes and alkynes.
@nl
P356
P1476
Ligand-dependent scope and div ...... ings of aldehydes and alkynes.
@en
P2093
Gireesh M Mahandru
P304
P356
10.1021/JA049644N
P407
P577
2004-03-01T00:00:00Z