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Synthetic and mechanistic studies on Pd(0)-catalyzed diamination of conjugated dienes.The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total SynthesisEvolution of the total syntheses of ustiloxin natural products and their analoguesCatalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysisPalladium-catalyzed dynamic kinetic asymmetric transformations of vinyl aziridines with nitrogen heterocycles: rapid access to biologically active pyrroles and indoles.Advances in the enantioselective synthesis of carbocyclic nucleosides.Transition metal-catalyzed decarboxylative allylation and benzylation reactionsAcetoxy Meldrum's acid: a versatile acyl anion equivalent in the Pd-catalyzed asymmetric allylic alkylationCu(I)-catalyzed diamination of conjugated dienes. Complementary regioselectivity from two distinct mechanistic pathways involving Cu(II) and Cu(III) species.Formation of C-C Bonds via Catalytic Hydrogenation and Transfer Hydrogenation: Vinylation, Allylation, and Enolate Addition of Carbonyl Compounds and IminesPalladium-catalyzed asymmetric allylic alkylation of electron-deficient pyrroles with meso electrophilesA Highly Convergent Total Synthesis of Leustroducsin BCatalytic double stereoinduction in asymmetric allylic alkylation of oxindoles.Nickel-Catalyzed Allylic Alkylation with Diarylmethane Pronucleophiles: Reaction Development and Mechanistic Insights.Palladium-catalyzed enantioselective C-3 allylation of 3-substituted-1H-indoles using trialkylboranes.Tandem Rh-catalysis: decarboxylative β-keto acid and alkyne cross-coupling.Palladium-catalyzed chemo- and enantioselective oxidation of allylic esters and carbonates.Palladium-catalyzed asymmetric allylic alkylation of meso- and dl-1,2-divinylethylene carbonateMo-catalyzed regio-, diastereo-, and enantioselective allylic alkylation of 3-aryloxindoles.Total synthesis of enantiopure (+)-gamma-lycorane using highly efficient Pd-catalyzed asymmetric allylic alkylation.Quantitative Determination of the Regioselectivity of Nucleophilic Addition to η-Propargyl Rhenium Complexes and Direct Observation of an Equilibrium Between η-Propargyl Rhenium Complexes and RhenacyclobutenesTemplate-constrained macrocyclic peptides prepared from native, unprotected precursorsPd(0)-catalyzed sequential C-N bond formation via allylic and aromatic C-H amination of α-methylstyrenes with diaziridinone.Raising the pKa limit of "soft" nucleophiles in palladium-catalyzed allylic substitutions: application of diarylmethane pronucleophiles.Formation of C-C Bonds via Iridium-Catalyzed Hydrogenation and Transfer Hydrogenation.Phosphino-carboxamides: the inconspicuous gems.Catalytic asymmetric synthesis of allylic alcohols and derivatives and their applications in organic synthesis.Chiral counteranion strategy for asymmetric oxidative C(sp³)-H/C(sp³)-H coupling: enantioselective α-allylation of aldehydes with terminal alkenes.Catalytic Asymmetric Synthesis of Butenolides and Butyrolactones.Regio- and enantioselective N-allylations of imidazole, benzimidazole, and purine heterocycles catalyzed by single-component metallacyclic iridium complexes.Palladium-catalyzed allylic substitution with (η6-arene-CH2Z)Cr(CO)(3)-based nucleophiles.Breaking Conjugation: Unusual Regioselectivity with 2-Substituted Allylic Substrates in the Tsuji-Trost Reaction.The palladium-catalyzed aerobic kinetic resolution of secondary alcohols: reaction development, scope, and applications.Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams.Additive-Free Pd-Catalyzed α-Allylation of Imine-Containing Heterocycles.Mechanistically driven development of iridium catalysts for asymmetric allylic substitution.Recent Advances in the Stereoselective Synthesis of Tetrahydrofurans.Mechanism of the cobalt oxazoline palladacycle (COP)-catalyzed asymmetric synthesis of allylic esters.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.Silyl ketene imines: highly versatile nucleophiles for catalytic, asymmetric synthesis.
P2860
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P2860
description
2004 nî lūn-bûn
@nan
2004年の論文
@ja
2004年学术文章
@wuu
2004年学术文章
@zh
2004年学术文章
@zh-cn
2004年学术文章
@zh-hans
2004年学术文章
@zh-my
2004年学术文章
@zh-sg
2004年學術文章
@yue
2004年學術文章
@zh-hant
name
Asymmetric allylic alkylation, an enabling methodology.
@en
Asymmetric allylic alkylation, an enabling methodology.
@nl
type
label
Asymmetric allylic alkylation, an enabling methodology.
@en
Asymmetric allylic alkylation, an enabling methodology.
@nl
prefLabel
Asymmetric allylic alkylation, an enabling methodology.
@en
Asymmetric allylic alkylation, an enabling methodology.
@nl
P356
P1476
Asymmetric allylic alkylation, an enabling methodology.
@en
P304
P356
10.1021/JO0491004
P407
P50
P577
2004-09-01T00:00:00Z