Cascade hydroamination/redox reaction for the synthesis of cyclic aminals catalyzed by a combined gold complex and Brønsted acid.
about
Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reactionRedox-neutral α-oxygenation of amines: reaction development and elucidation of the mechanism.Asymmetric Redox-Annulation of Cyclic Amines.C-H bond functionalization through intramolecular hydride transfer.When gold meets chiral Brønsted acid catalysts: extending the boundaries of enantioselective gold catalysis.Organo- and Organometallic-Catalytic Intramolecular [1,5]-Hydride Transfer/Cyclization Process through C(sp(3) )-H Bond Activation.Redox-Annulation of Cyclic Amines and β-Ketoaldehydes.Hydrogen-Atom Transfer Reactions.Intramolecular Redox-Mannich Reactions: Facile Access to the Tetrahydroprotoberberine Core.The redox-Mannich reaction.Redox-neutral α,β-difunctionalization of cyclic amines.Redox-neutral α-C-H bond functionalization of secondary amines with concurrent C-P bond formation/N-alkylation.A tandem isomerization/prins strategy: iridium(III)/Brønsted acid cooperative catalysisC-H functionalization of cyclic amines: redox-annulations with α,β-unsaturated carbonyl compounds.Redox-neutral α-arylation of amines.An Ugi Reaction Incorporating a Redox-Neutral Amine C-H Functionalization StepIntramolecular [3 + 2]-cycloadditions of azomethine ylides derived from secondary amines via redox-neutral C-H functionalization.Lewis acid mediated vinyl-transfer reaction of alkynes to N-alkylimines by using the N-alkyl residue as a sacrificial hydrogen donor.Redox-Neutral Aromatization of Cyclic Amines: Mechanistic Insights and Harnessing of Reactive Intermediates for Amine α- and β-C-H Functionalization.Mechanistic study of gold(I)-catalyzed hydroamination of alkynes: outer or inner sphere mechanism?Iterative direct C(sp3)-H functionalization of amines: diastereoselective divergent syntheses of α,α'-disubstituted alicyclic amines.Regio- and Diastereoselective and Enantiospecific Metal-Free C(sp(3) )-H Arylation: Facile Access to Optically Active 5-Aryl 2,5-Disubstituted Pyrrolidines.
P2860
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P2860
Cascade hydroamination/redox reaction for the synthesis of cyclic aminals catalyzed by a combined gold complex and Brønsted acid.
description
2013 nî lūn-bûn
@nan
2013年の論文
@ja
2013年学术文章
@wuu
2013年学术文章
@zh
2013年学术文章
@zh-cn
2013年学术文章
@zh-hans
2013年学术文章
@zh-my
2013年学术文章
@zh-sg
2013年學術文章
@yue
2013年學術文章
@zh-hant
name
Cascade hydroamination/redox r ...... old complex and Brønsted acid.
@en
Cascade hydroamination/redox r ...... old complex and Brønsted acid.
@nl
type
label
Cascade hydroamination/redox r ...... old complex and Brønsted acid.
@en
Cascade hydroamination/redox r ...... old complex and Brønsted acid.
@nl
prefLabel
Cascade hydroamination/redox r ...... old complex and Brønsted acid.
@en
Cascade hydroamination/redox r ...... old complex and Brønsted acid.
@nl
P2093
P2860
P356
P1476
Cascade hydroamination/redox r ...... old complex and Brønsted acid.
@en
P2093
P2860
P304
P356
10.1002/CHEM.201300052
P407
P577
2013-03-19T00:00:00Z