Palladium-catalyzed enantioselective diboration of prochiral allenes.
about
Catalytic enantioselective 1,6-conjugate additions of propargyl and allyl groupsHighly (E)-selective BF(3).Et(2)O-promoted allylboration of chiral nonracemic alpha-substituted allylboronates and analysis of the origin of stereocontrolEnantio- and diastereoselective synthesis of (E)-1,5-syn-diols: application to the synthesis of the C(23)-C(40) fragment of tetrafibricinDevelopment of a Double Allylboration Reagent Targeting 1,5-syn-(E)-Diols: Application to the Synthesis of the C(23)-C(40) Fragment of Tetrafibricin.TADDOL-based phosphorus(III)-ligands in enantioselective Pd(0)-catalysed C-H functionalisations.Enantioselective synthesis of (Z)- and (E)-2-methyl-1,5-anti-pentenediols via an allene hydroboration-double-allylboration reaction sequence.Enantiodivergent Hydroboration Reactions of a Racemic Allenylsilane with Diisopinocampheylborane and Curtin-Hammett Controlled Double Asymmetric Crotylboration Reactions of (S)-E-α-phenyldimethylsilyl( (d) diisopinocampheyl)-crotylborane.Enantiodivergent hydroboration reactions of a racemic allenylsilane with diisopinocampheylborane and Curtin-Hammett controlled double asymmetric crotylboration reactions of (S)-E-αphenyldimethylsilyl( (d) diisopinocampheyl)-crotylborane.Polyborylated reagents for modern organic synthesisRegioselective allene hydrosilylation catalyzed by N-heterocyclic carbene complexes of nickel and palladium.Allenes and computational chemistry: from bonding situations to reaction mechanisms.Pinene-derived iminodiacetic acid (PIDA): a powerful ligand for stereoselective synthesis and iterative cross-coupling of C(sp3) boronate building blocks.Transition-metal-free B-B and B-interelement reactions with organic molecules.A catalytic enantiotopic-group-selective Suzuki reaction for the construction of chiral organoboronates.A catalytic enantioselective tandem allylation strategy for rapid terpene construction: application to the synthesis of pumilaside aglyconCatalytic enantioselective allyl-allyl cross-coupling with a borylated allylboronate.Accessing Both Retention and Inversion Pathways in Stereospecific, Nickel-Catalyzed Miyaura Borylations of Allylic Pivalates.Mechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to α,β-Unsaturated Carbonyl Compounds.Catalytic Borylative Opening of Propargyl Cyclopropane, Epoxide, Aziridine, and Oxetane Substrates: Ligand Controlled Synthesis of Allenyl Boronates and Alkenyl Diboronates.Ni-catalyzed borylative diene-aldehyde coupling: the remarkable effect of P(SiMe3)3.Enantioselective synthesis of allylboronates bearing a tertiary or quaternary B-substituted stereogenic carbon by NHC-Cu-catalyzed substitution reactions.Diastereoselective construction of functionalized homoallylic alcohols by Ni-catalyzed diboron-promoted coupling of dienes and aldehydes.Modular monodentate oxaphospholane ligands: utility in highly efficient and enantioselective 1,4-diboration of 1,3-dienes.Ni(0)-catalyzed 1,4-selective diboration of conjugated dienesAsymmetric 1,4-dihydroxylation of 1,3-dienes by catalytic enantioselective diboration.Selective uni- and bidirectional homologation of diborylmethane.Enantioselective palladium-catalyzed diboration of 1,1-disubstituted allenes.Allylation of nitrosobenzene with pinacol allylboronates. A regioselective complement to peroxide oxidation.Catalytic enantioselective one-pot aminoborylation of aldehydes: a strategy for construction of nonracemic α-amino boronates.Enantioselective synthesis of boron-substituted quaternary carbon stereogenic centers through NHC-catalyzed conjugate additions of (pinacolato)boron units to enones.Palladium-catalyzed chemoselective allylic substitution, Suzuki-Miyaura cross-coupling, and allene formation of bifunctional 2-B(pin)-substituted allylic acetate derivatives.Orthogonal reactivity in boryl-substituted organotrifluoroborates.Amide-controlled highly selective catalytic borylcupration of allenes.Asymmetric diboration of terminal alkenes with a rhodium catalyst and subsequent oxidation: enantioselective synthesis of optically active 1,2-diols.Regio- and stereoselective copper-catalyzed β-borylation of allenoates by a preactivated diboron.Enantioselective Conjunctive Cross-Coupling of Bis(alkenyl)borates: A General Synthesis of Chiral Allylboron Reagents.One-pot three-component highly selective synthesis of homoallylboronates by using metal-free catalysis.Catalytic Enantioselective Assembly of Homoallylic Alcohols from Dienes, Aryldiazonium Salts, and Aldehydes.One-pot three-component catalytic enantioselective synthesis of homoallylboronates.Synthesis and application of a dual chiral [2.2]paracyclophane-based N-heterocyclic carbene in enantioselective β-boration of acyclic enones.
P2860
Q28817194-AE7BF541-8106-4F9E-A975-F303D9C0E7ACQ33938101-4D1E3D4E-A1C1-4545-B464-DEBAE562F887Q34723259-12C1D845-77BD-46DF-9768-191BB1660467Q35165451-1D260D71-E6C5-4766-B77F-2B013B0AE619Q35825220-1B1C7ACA-6F3A-40AD-87CF-B14354A80BB7Q37070538-F633FEA2-9CE9-4DD8-AEF8-6039F2214AD9Q37158638-497ED8E1-536E-4A99-9A6B-2B2AFCDD9B1AQ37189116-CC9FE4B8-48C7-45DF-B58A-E8315C790A78Q37305267-D3C27651-AF0A-4AB9-9553-2B1816A6B3CFQ37338903-3DB7A4E5-3AC1-41AA-B8F8-697D4C898E90Q38189659-F3260CB9-E325-4FAC-A66D-58102CB3B9DEQ38273207-0297A380-FE27-4C7D-8EE2-B6F0980B6B2BQ38784170-249808CF-70F1-47EE-BEDA-FAA88B334EEBQ39628761-1BA3658E-9548-4790-97A7-0AD0D6972388Q39837401-B7274F1F-132F-4702-88CC-978F861CAFCEQ41034107-F76DD5FC-8742-4333-B4F0-6DB3D26FAC73Q41094027-C70E34C4-F300-4C94-BC36-B95FB039B278Q41319490-6D21A7CE-A560-477C-8FB2-9D7EEBB1CD86Q41825369-F333D455-61B8-4798-ACDE-D7B3B950CE5DQ41869032-EF5A4BF7-D323-48BA-8019-F5B47CB996C9Q41917175-4F9A6787-D00B-4EA9-8C9F-275BEF5BEA97Q42034081-43E3E5D4-EA72-473F-8643-1076C3BC9658Q42131067-0DB87929-9062-47DA-A3E3-0D27CA32001EQ42138227-D8EBFE36-5C92-4334-B628-B49833D4268AQ42271049-020FA9DD-EEF9-4FAF-BE73-81F7F569190EQ42293064-D7CC2ABC-B5C5-466C-96AB-A139345D828CQ42364680-2708E679-1F51-449D-B8B0-7E6C818BB4ADQ42464168-B98E9AE9-9195-4AE1-BBF6-BF852005C875Q42566431-2043826C-C05F-4623-955D-1189A009D549Q42732502-5B0C9015-00B4-4697-B6F2-1FB5366AB7FAQ42974315-23D25F75-72D6-4219-87CE-33050B7744B0Q43177332-77340796-4A4F-4EA7-8549-C5C0C45666B2Q43596487-56DB63C8-A751-4812-9F8E-2924945AD297Q44532821-83D0CD79-773B-4393-9590-7608E17E6DF7Q44959682-8CC4F569-8073-453C-9EBE-706F62365149Q48368583-5D07009B-A1DF-49E5-B1A2-61F30F08A87AQ51401538-282E8B41-05A9-43D1-9BF8-B5CE18B5512BQ51490611-51939F5B-EB1D-40C7-96EA-79837012621AQ51516030-EA71FE4D-CE33-4569-A735-7E6C55F90768Q51727500-5E89238B-6E14-4E2C-A5BC-A612844E59BA
P2860
Palladium-catalyzed enantioselective diboration of prochiral allenes.
description
2004 nî lūn-bûn
@nan
2004年の論文
@ja
2004年学术文章
@wuu
2004年学术文章
@zh
2004年学术文章
@zh-cn
2004年学术文章
@zh-hans
2004年学术文章
@zh-my
2004年学术文章
@zh-sg
2004年學術文章
@yue
2004年學術文章
@zh-hant
name
Palladium-catalyzed enantioselective diboration of prochiral allenes.
@en
Palladium-catalyzed enantioselective diboration of prochiral allenes.
@nl
type
label
Palladium-catalyzed enantioselective diboration of prochiral allenes.
@en
Palladium-catalyzed enantioselective diboration of prochiral allenes.
@nl
prefLabel
Palladium-catalyzed enantioselective diboration of prochiral allenes.
@en
Palladium-catalyzed enantioselective diboration of prochiral allenes.
@nl
P2093
P356
P1476
Palladium-catalyzed enantioselective diboration of prochiral allenes
@en
P2093
Angela R Woodward
James P Morken
Joshua D Sieber
Nicholas F Pelz
P304
16328-16329
P356
10.1021/JA044167U
P407
P577
2004-12-01T00:00:00Z