Metalated N-heterocyclic reagents prepared by the frustrated Lewis pair TMPMgCl·BF3 and their addition to aromatic aldehydes and activated ketones.
about
Atom-Efficient Synthesis of Alkynylfluoroborates Using BF3 -Based Frustrated Lewis Pairs.Zn-, Mg-, and Li-TMP Bases for the Successive Regioselective Metalations of the 1,5-Naphthyridine Scaffold (TMP=2,2,6,6-Tetramethylpiperidyl).Reactivity of highly Lewis acidic diborane(4) towards pyridine and isocyanide: formation of boraalkene-pyridine complex and ortho-functionalized pyridine derivatives.Regioselective Metalations of Pyrimidines and Pyrazines by Using Frustrated Lewis Pairs of BF3⋅OEt2and Hindered Magnesium- and Zinc-Amide Bases
P2860
Metalated N-heterocyclic reagents prepared by the frustrated Lewis pair TMPMgCl·BF3 and their addition to aromatic aldehydes and activated ketones.
description
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name
Metalated N-heterocyclic reage ...... dehydes and activated ketones.
@en
Metalated N-heterocyclic reage ...... dehydes and activated ketones.
@nl
type
label
Metalated N-heterocyclic reage ...... dehydes and activated ketones.
@en
Metalated N-heterocyclic reage ...... dehydes and activated ketones.
@nl
prefLabel
Metalated N-heterocyclic reage ...... dehydes and activated ketones.
@en
Metalated N-heterocyclic reage ...... dehydes and activated ketones.
@nl
P2093
P2860
P356
P1476
Metalated N-heterocyclic reage ...... dehydes and activated ketones.
@en
P2093
Konstantin Karaghiosoff
Milica Jaric
Sophia M Manolikakes
P2860
P304
P356
10.1039/C3CC39040C
P407
P50
P577
2013-02-07T00:00:00Z