Enantioselective, cyclopentene-forming annulations via NHC-catalyzed benzoin-oxy-cope reactions.
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Organocatalytic Reactions Enabled by N-Heterocyclic CarbenesLanthanum tricyanide-catalyzed acyl silane-ketone benzoin additions and kinetic resolution of resultant alpha-silyloxyketones.Catalytic Kinetic Resolution of a Dynamic Racemate: Highly Stereoselective β-Lactone Formation by N-Heterocyclic Carbene CatalysisAn enantioselective Claisen rearrangement catalyzed by N-heterocyclic carbenesChiral N-heterocyclic carbene-catalyzed generation of ester enolate equivalents from {alpha},{beta}-unsaturated aldehydes for enantioselective Diels-Alder reactionsLate-stage diversification of chiral N-heterocyclic-carbene precatalysts for enantioselective homoenolate additions.Chiral N-Heterocyclic Carbene Catalyzed Annulations of Enals and Ynals with Stable Enols: A Highly Enantioselective Coates-Claisen Rearrangement.Cooperative Lewis acid/N-heterocyclic carbene catalysisExploiting Acyl and Enol Azolium Intermediates via NHeterocyclic Carbene Catalyzed Reactions of Alpha-Reducible Aldehydes.Carbene catalystsChiral NHC-catalyzed oxodiene Diels-Alder reactions with alpha-chloroaldehyde bisulfite saltsLanthanum tricyanide-catalyzed acyl silane-ketone benzoin additions.Employing homoenolates generated by NHC catalysis in carbon-carbon bond-forming reactions: state of the art.A continuum of progress: applications of N-hetereocyclic carbene catalysis in total synthesis.Toward a symphony of reactivity: cascades involving catalysis and sigmatropic rearrangementsSwitchable divergent asymmetric synthesis via organocatalysis.Cooperative N-heterocyclic carbene/Lewis acid catalysis for highly stereoselective annulation reactions with homoenolates.The effect of the N-mesityl group in NHC-catalyzed reactions.Lewis acid activated synthesis of highly substituted cyclopentanes by the N-heterocyclic carbene catalyzed addition of homoenolate equivalents to unsaturated ketoesters.Carbene catalyzed umpolung of α,β-enals: a reactivity study of diamino dienols vs. azolium enolates, and the characterization of advanced reaction intermediatesCatalytic dynamic kinetic resolutions with N-heterocyclic carbenes: asymmetric synthesis of highly substituted β-lactonesOxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from EnalsSynthesis of cyclopentenones from cyclopropanes and silyl ynol ethers.Enantioselective synthesis of alpha,alpha-disubstituted cyclopentenes by an N-heterocyclic carbene-catalyzed desymmetrization of 1,3-diketonesFormal synthesis of salinosporamide A via NHC-catalyzed intramolecular lactonizationAsymmetric N-heterocyclic carbene catalyzed addition of enals to nitroalkenes: controlling stereochemistry via the homoenolate reactivity pathway to access δ-lactams.Alpha'-hydroxyenones as mechanistic probes and scope-expanding surrogates for alpha,beta-unsaturated aldehydes in N-heterocyclic carbene-catalyzed reactions.NHC-catalyzed/titanium(IV)-mediated highly diastereo- and enantioselective dimerization of enals.On the role of CO2 in NHC-catalyzed oxidation of aldehydesN-heterocyclic carbene and Brønsted acid cooperative catalysis: asymmetric synthesis of trans-γ-lactams.Stereodivergency of triazolium and imidazolium-derived NHCs for catalytic, enantioselective cyclopentane synthesis.N-heterocyclic-carbene-catalyzed one-pot synthesis of hydroxamic esters.N-heterocyclic carbene catalyzed [4+2] cycloaddition of nitroalkenes with oxodienes.Enantio- and periselective nitroalkene Diels-Alder reactions catalyzed by helical-chiral hydrogen bond donor catalysts.Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators.Controlled β-protonation and [4+2] cycloaddition of enals and chalcones via N-heterocyclic carbene/acid catalysis: toward substrate independent reaction control.β-Carbon activation of saturated carboxylic esters through N-heterocyclic carbene organocatalysis.N-Heterocyclic carbene catalysed redox isomerisation of esters to functionalised benzaldehydes.Organocatalytic Highly Regio- and Enantioselective Umpolung Michael Addition Reaction of α-Imino Esters.Construction of Fused Pyrrolidines and β-Lactones by Carbene-Catalyzed C-N, C-C, and C-O Bond Formations.
P2860
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P2860
Enantioselective, cyclopentene-forming annulations via NHC-catalyzed benzoin-oxy-cope reactions.
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年学术文章
@wuu
2007年学术文章
@zh-cn
2007年学术文章
@zh-hans
2007年学术文章
@zh-my
2007年学术文章
@zh-sg
2007年學術文章
@yue
2007年學術文章
@zh
2007年學術文章
@zh-hant
name
Enantioselective, cyclopentene ...... ed benzoin-oxy-cope reactions.
@en
Enantioselective, cyclopentene ...... ed benzoin-oxy-cope reactions.
@nl
type
label
Enantioselective, cyclopentene ...... ed benzoin-oxy-cope reactions.
@en
Enantioselective, cyclopentene ...... ed benzoin-oxy-cope reactions.
@nl
prefLabel
Enantioselective, cyclopentene ...... ed benzoin-oxy-cope reactions.
@en
Enantioselective, cyclopentene ...... ed benzoin-oxy-cope reactions.
@nl
P2093
P356
P1476
Enantioselective, cyclopentene ...... ed benzoin-oxy-cope reactions.
@en
P2093
Jeffrey W Bode
Juthanat Kaeobamrung
Pei-Chen Chiang
P304
P356
10.1021/JA0705543
P407
P577
2007-03-03T00:00:00Z