Unexpected effect of the fluorine atom on the optimal ligand-to-palladium ratio in the enantioselective Pd-catalyzed allylation reaction of fluorinated enol carbonates.

Unexpected effect of the fluorine atom on the optimal ligand-to-palladium ratio in the enantioselective Pd-catalyzed allylation reaction of fluorinated enol carbonates.

Item
http://www.wikidata.org/entity/Q46486780
Transition metal-catalyzed decarboxylative allylation and benzylation reactionsAn Efficient Protocol for the Palladium-catalyzed Asymmetric Decarboxylative Allylic Alkylation Using Low Palladium Concentrations and a Palladium(II) Precatalyst.Expanding insight into asymmetric palladium-catalyzed allylic alkylation of N-heterocyclic molecules and cyclic ketonesFluorine & chirality: how to create a nonracemic stereogenic carbon-fluorine centre?Fluorinated enol ethers: their synthesis and reactivity.Recent Advances in the One-Step Synthesis of Distally Fluorinated Ketones.Unusual allylpalladium carboxylate complexes: identification of the resting state of catalytic enantioselective decarboxylative allylic alkylation reactions of ketones.A unified approach to the daucane and sphenolobane bicyclo[5.3.0]decane core: enantioselective total syntheses of daucene, daucenal, epoxydaucenal B, and 14-para-anisoyloxydauc-4,8-diene.The catalytic enantioselective total synthesis of (+)-liphagal.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.Catalytic Enantioselective and Diastereoselective Allylic Alkylation with Fluoroenolates: Efficient Access to C3-Fluorinated and All-Carbon Quaternary Oxindoles.A diastereoselective Mannich-type reaction of α-fluorinated carboxylate esters: synthesis of β-amino acids containing α-quaternary fluorinated carbon centers.Assembly of Fluorinated Quaternary Stereogenic Centers through Catalytic Enantioselective Detrifluoroacetylative Aldol Reactions.Pd-catalyzed highly regio-, diastereo-, and enantioselective allylic alkylation of α-fluorophosphonates.
P2860

Unexpected effect of the fluorine atom on the optimal ligand-to-palladium ratio in the enantioselective Pd-catalyzed allylation reaction of fluorinated enol carbonates.

Item
http://www.wikidata.org/entity/Q46486780
description
2008 nî lūn-bûn
@nan
2008年の論文
@ja
2008年学术文章
@wuu
2008年学术文章
@zh
2008年学术文章
@zh-cn
2008年学术文章
@zh-hans
2008年学术文章
@zh-my
2008年学术文章
@zh-sg
2008年學術文章
@yue
2008年學術文章
@zh-hant
name
Unexpected effect of the fluor ...... f fluorinated enol carbonates.
@en
Unexpected effect of the fluor ...... f fluorinated enol carbonates.
@nl
type
label
Unexpected effect of the fluor ...... f fluorinated enol carbonates.
@en
Unexpected effect of the fluor ...... f fluorinated enol carbonates.
@nl
prefLabel
Unexpected effect of the fluor ...... f fluorinated enol carbonates.
@en
Unexpected effect of the fluor ...... f fluorinated enol carbonates.
@nl
P1433
P1476
P2093
P304
P31
P356
P407
P433
P577
P5875
P698
P921
P356
P1433
P1476
Unexpected effect of the fluor ...... f fluorinated enol carbonates.
@en
P2093
P304
P31
P356
P407
P433
P577
P5875
P698
P921