Unusual allylpalladium carboxylate complexes: identification of the resting state of catalytic enantioselective decarboxylative allylic alkylation reactions of ketones.
about
Palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters.Mechanistic origin of the stereodivergence in decarboxylative allylationDecarboxylative benzylations of alkynes and ketonesEnantioselective synthesis of α-secondary and α-tertiary piperazin-2-ones and piperazines by catalytic asymmetric allylic alkylation.Transition metal-catalyzed decarboxylative allylation and benzylation reactionsAn Efficient Protocol for the Palladium-catalyzed Asymmetric Decarboxylative Allylic Alkylation Using Low Palladium Concentrations and a Palladium(II) Precatalyst.Expanding insight into asymmetric palladium-catalyzed allylic alkylation of N-heterocyclic molecules and cyclic ketonesGas extrusion in natural products total synthesis.Catalytic stereospecific allyl-allyl cross-coupling of internal allyl electrophiles with AllylB(pin).Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.Diastereocontrol in asymmetric allyl-allyl cross-coupling: stereocontrolled reaction of prochiral allylboronates with prochiral allyl chlorides.Catalytic enantioselective allyl-allyl cross-coupling with a borylated allylboronate.Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-Carbon Quaternary Stereocenters.A general enantioselective route to the chamigrene natural product family.Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism.A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres.Enantioselective construction of all-carbon quaternary centers by branch-selective Pd-catalyzed allyl-allyl cross-coupling.High-Throughput Screening of the Asymmetric Decarboxylative Alkylation Reaction of Enolate-Stabilized Enol Carbonates.The catalytic enantioselective total synthesis of (+)-liphagal.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.Pd-catalyzed enantioselective allyl-allyl cross-coupling.Enantioselective construction of α-quaternary cyclobutanones by catalytic asymmetric allylic alkylation.Efficient activation of aromatic C-H bonds for fused polyaromatic hydrocarbon construction.Stereoselective β-C-glycosylation by a palladium-catalyzed decarboxylative allylation: formal synthesis of aspergillide A.Enantioselective palladium-catalyzed decarboxylative allylation of carbazolones and indolones: formal synthesis of (+)-kopsihainanine A.Facile access to cis-2,6-disubstituted tetrahydropyrans by palladium-catalyzed decarboxylative allylation: total syntheses of (±)-centrolobine and (+)-decytospolides A and B.Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates.Palladium-Catalyzed Asymmetric Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters by Allylation of β-Ketocarbonyls with Morita-Baylis-Hillman Adducts.One-pot synthesis of β-N-glycosyl imidazole analogues via a palladium-catalysed decarboxylative allylation.β-Type glycosidic bond formation by palladium-catalyzed decarboxylative allylation.Palladium-Catalyzed Allylic Substitution at Four-Membered-Ring Systems: Formation of η1-Allyl Complexes and Electrocyclic Ring Opening
P2860
Q33833389-04E736EA-AD80-434B-AB4D-21E29DDC81BBQ34034806-5184A88E-2C01-41C7-A74C-3FCE107D6BABQ34072422-EC9489AA-F08F-4B5C-A3CF-356DE3819D10Q34850044-71537463-A57F-49BE-B907-415BB2DA2032Q35049991-6661EF28-EF97-459D-BF3C-B7716F57DC6BQ36739287-470208B9-75F3-42DA-8AC2-5FB079860C2EQ37274196-C4D295C9-5DC8-44A3-8825-204FCB4DF61CQ38039828-EB1FED2A-6BD5-448C-9534-9936516B7F17Q38951328-CCEDF3DB-021E-48C7-8125-E0B619EE4C4FQ39121643-FB7921A0-D1B0-48D4-9402-85EF4B0AE57CQ39190422-3EB484C9-59B5-4E99-9A82-FA558B70B90BQ41034107-06B01A9C-6DF0-4F01-A482-E3986610DBC0Q41136502-D2672771-CF74-4620-A1AC-E5AE72074B42Q41788466-ACD6752C-86F6-46FD-8F79-D730E6A7468FQ41866678-87292CAA-811F-4CA4-AB3E-6AA73F96FC71Q41878884-7F2770DD-2E62-4D8E-A4DA-FD04B72F7778Q41918809-7C10B0F2-AED8-441C-A601-BDFC1C88CE1EQ42136472-C93902D0-4BEE-4641-B221-A72D2BC025BBQ42179500-BA8FAB82-2147-4CD8-B203-0AB465AC464DQ42182848-2E1A88AD-2AEA-4752-AADB-8285788E1821Q42529225-E3D9B3C8-5527-4A1D-9DDA-FF81AE9D9106Q42921306-424E8E1B-DBA2-4D43-87D3-1AC865911017Q43055901-E874897B-EE5B-481B-82F1-A701CF438F90Q43861749-7EF78A45-F5BF-4B53-A2AE-27BDADB90017Q44003958-2C78DD58-D62A-434E-839C-DD5C831B0448Q44902741-2B2CCEFE-D77B-47A5-8646-A8CEF641AF2EQ46642667-F468F5C4-B7C9-430C-B7CC-304CB129D9A3Q48318928-5FE62B91-28AC-464F-B2AA-3D713788B356Q51102152-36D04EF0-88DE-46A2-84DF-896EA6B14759Q51155379-DEF468CC-51A1-4F2B-9279-8D91FE872B6CQ57397741-51CC43D0-5447-4ABE-A68D-00BCAF33C014
P2860
Unusual allylpalladium carboxylate complexes: identification of the resting state of catalytic enantioselective decarboxylative allylic alkylation reactions of ketones.
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年学术文章
@wuu
2009年学术文章
@zh-cn
2009年学术文章
@zh-hans
2009年学术文章
@zh-my
2009年学术文章
@zh-sg
2009年學術文章
@yue
2009年學術文章
@zh
2009年學術文章
@zh-hant
name
Unusual allylpalladium carboxy ...... kylation reactions of ketones.
@en
type
label
Unusual allylpalladium carboxy ...... kylation reactions of ketones.
@en
prefLabel
Unusual allylpalladium carboxy ...... kylation reactions of ketones.
@en
P2093
P2860
P356
P1476
Unusual allylpalladium carboxy ...... kylation reactions of ketones.
@en
P2093
Brian M Stoltz
Douglas C Behenna
Nathaniel H Sherden
Scott C Virgil
P2860
P304
P356
10.1002/ANIE.200902575
P407
P577
2009-01-01T00:00:00Z