Catalytic asymmetric vinylation and dienylation of ketones.
about
Asymmetric functional organozinc additions to aldehydes catalyzed by 1,1'-bi-2-naphthols (BINOLs).Activation of vinyl iodides for the highly enantioselective addition to aldehydes.One-pot synthesis of trisubstituted conjugated dienes via sequential Suzuki-Miyaura cross-coupling with alkenyl- and alkyltrifluoroboratesDirected evolution: an approach to engineer enzymes.One-pot catalytic enantio- and diastereoselective syntheses of anti-, syn-cis-disubstituted, and syn-vinyl cyclopropyl alcoholsChiral imine copper chloride-catalyzed enantioselective desymmetrization of 2-substituted 1,2,3-propanetriols.Formation of C-C Bonds via Catalytic Hydrogenation and Transfer Hydrogenation: Vinylation, Allylation, and Enolate Addition of Carbonyl Compounds and IminesA green chemistry approach to asymmetric catalysis: solvent-free and highly concentrated reactionsCatalytic asymmetric generation of (Z)-disubstituted allylic alcoholsTandem reactions for streamlining synthesis: enantio- and diastereoselective one-pot generation of functionalized epoxy alcoholsCatalytic carbonyl addition through transfer hydrogenation: a departure from preformed organometallic reagents.One-pot multicomponent coupling methods for the synthesis of diastereo- and enantioenriched (Z)-trisubstituted allylic alcohols.The Enantioselective Addition of Alkyne Nucleophiles to Carbonyl Groups.Formation of C-C Bonds via Iridium-Catalyzed Hydrogenation and Transfer Hydrogenation.Catalytic asymmetric synthesis of allylic alcohols and derivatives and their applications in organic synthesis.Direct vinylation of alcohols or aldehydes employing alkynes as vinyl donors: a ruthenium catalyzed C-C bond-forming transfer hydrogenation.Synthesis of quaternary carbon stereogenic centers through enantioselective Cu-catalyzed allylic substitutions with vinylaluminum reagents.Asymmetric synthesis of tertiary benzylic alcohols.Lewis acid mediated vinyl-transfer reaction of alkynes to N-alkylimines by using the N-alkyl residue as a sacrificial hydrogen donor.Highly efficient asymmetric additions of diethylzinc to aldehydes triply activated by chiral phosphoramide-Zn(II) complexes derived from cinchona alkaloids.Introducing deep eutectic solvents to polar organometallic chemistry: chemoselective addition of organolithium and Grignard reagents to ketones in air.Improved synthesis of cyclic tertiary allylic alcohols by asymmetric 1,2-addition of AlMe3 to enones.Preparation of conjugated 1,3-enynes by Rh(iii)-catalysed alkynylation of alkenes via C–H activationShedding New Light on ZnCl2-Mediated Addition Reactions of Grignard Reagents to Ketones: Structural Authentication of Key Intermediates and Diffusion-Ordered NMR Studies
P2860
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P2860
Catalytic asymmetric vinylation and dienylation of ketones.
description
2005 nî lūn-bûn
@nan
2005年の論文
@ja
2005年学术文章
@wuu
2005年学术文章
@zh
2005年学术文章
@zh-cn
2005年学术文章
@zh-hans
2005年学术文章
@zh-my
2005年学术文章
@zh-sg
2005年學術文章
@yue
2005年學術文章
@zh-hant
name
Catalytic asymmetric vinylation and dienylation of ketones.
@en
Catalytic asymmetric vinylation and dienylation of ketones.
@nl
type
label
Catalytic asymmetric vinylation and dienylation of ketones.
@en
Catalytic asymmetric vinylation and dienylation of ketones.
@nl
prefLabel
Catalytic asymmetric vinylation and dienylation of ketones.
@en
Catalytic asymmetric vinylation and dienylation of ketones.
@nl
P356
P1476
Catalytic asymmetric vinylation and dienylation of ketones.
@en
P2093
Hongmei Li
Patrick J Walsh
P304
P356
10.1021/JA0425740
P407
P577
2005-06-01T00:00:00Z