Catalytic formal [2+2+1] synthesis of pyrroles from alkynes and diazenes via Ti(II)/Ti(IV) redox catalysis.
about
Redox non-innocence permits catalytic nitrene carbonylation by (dadi)Ti[double bond, length as m-dash]NAd (Ad = adamantyl)Differences between the elimination of early and late transition metals: DFT mechanistic insights into the titanium-catalyzed synthesis of pyrroles from alkynes and diazenes.Group 5 chemistry supported by β-diketiminate ligands.η(6) -Arene-Zirconium-PNP-Pincer Complexes: Mechanism of Their Hydrogenolytic Formation and Their Reactivity as Zirconium(II) Synthons.Ti-Catalyzed Multicomponent Oxidative Carboamination of Alkynes with Alkenes and Diazenes.Generation of TiII Alkyne Trimerization Catalysts in the Absence of Strong Metal Reductants.α-Unsubstituted Pyrroles by NHC-Catalyzed Three-Component Coupling: Direct Synthesis of a Versatile Atorvastatin Derivative.From Five to Seven: Ring Expansion of Monoazadiene Titanium Complexes by Insertion of Aldehydes, Ketones and Nitriles.Titanium redox catalysis: insights and applications of an earth-abundant base metal.Trimethylsilyl-Protected Alkynes as Selective Cross-Coupling Partners in Titanium-Catalyzed [2+2+1] Pyrrole Synthesis.
P2860
Q33636486-6590635C-9506-4254-B7F2-E1D0711D31CEQ37724920-EFE6C81E-30A4-4D30-BABA-8E97785F0159Q38872015-8A6B03A9-704F-44E4-B26D-D32C2B43CF9DQ39711862-115C9479-5DEF-4F5C-AE12-FD56E6A7172FQ42955543-74112116-5962-4C2E-A599-48897DE321F1Q46338574-4810AD93-F9B7-415B-9A61-E9670AD5CD5BQ48193031-B842CA10-9771-4DF3-A5AE-C3232EAE1D0BQ48339998-9B039C54-6051-45B9-B5C6-18E43877F345Q53791843-7F6D31B4-D445-451E-9A48-7E020D411511Q55232314-F5653014-0AF6-4B1B-8A96-64E1721202D9
P2860
Catalytic formal [2+2+1] synthesis of pyrroles from alkynes and diazenes via Ti(II)/Ti(IV) redox catalysis.
description
2015 nî lūn-bûn
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2015年の論文
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2015年学术文章
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2015年学术文章
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2015年学术文章
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2015年学术文章
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2015年学术文章
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2015年学术文章
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2015年學術文章
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name
Catalytic formal [2+2+1] synthesis of pyrroles from alkynes and diazenes via Ti
@nl
Catalytic formal [2+2+1] synth ...... Ti(II)/Ti(IV) redox catalysis.
@en
type
label
Catalytic formal [2+2+1] synthesis of pyrroles from alkynes and diazenes via Ti
@nl
Catalytic formal [2+2+1] synth ...... Ti(II)/Ti(IV) redox catalysis.
@en
prefLabel
Catalytic formal [2+2+1] synthesis of pyrroles from alkynes and diazenes via Ti
@nl
Catalytic formal [2+2+1] synth ...... Ti(II)/Ti(IV) redox catalysis.
@en
P2093
P2860
P356
P1433
P1476
Catalytic formal [2+2+1] synth ...... Ti(II)/Ti(IV) redox catalysis.
@en
P2093
Ian A Tonks
Ryan J Hue
Zachary W Gilbert
P2860
P2888
P356
10.1038/NCHEM.2386
P577
2015-11-02T00:00:00Z