Multiple complexation of CO and related ligands to a main-group element.
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Transition Metal-Free Cleavage of CO.Reconstitution of Vanadium Haloperoxidase's Catalytic Activity by Boric Acid-Towards a Potential Biocatalytic Role of Boron.Formation and Reactivity of Electron-Precise B-B Single and Multiple Bonds.A Tale of Two Elements: The Lewis Acidity/Basicity Umpolung of Boron and Phosphorus.Borylenes: An Emerging Class of Compounds.Boron-mediated sequential alkyne insertion and C-C coupling reactions affording extended π-conjugated molecules.Ambiphilic boron in 1,4,2,5-diazadiborinine.(Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles.A snapshot of inorganic Janovsky complex analogues featuring a nucleophilic boron center.Triaminotriborane(3): A Homocatenated Boron Chain Connected by B-B Multiple Bonds.(CF3 )3 Au as a Highly Acidic Organogold(III) Fragment.From Borane to Borylene without Reduction: Ambiphilic Behavior of a Monovalent Silylisonitrile Boron Species.Carbones as Ligands in Novel Main-Group Compounds E[C(NHC)2 ]2 (E=Be, B+ , C2+ , N3+ , Mg, Al+ , Si2+ , P3+ ): A Theoretical Study.Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square.Interactions of Isonitriles with Metal-Boron Bonds: Insertions, Coupling, Ring Formation, and Liberation of Monovalent Boron.The [B3(NN)3](+) and [B3(CO)3](+) Complexes Featuring the Smallest π-Aromatic Species B3(+).Observation of Main-Group Tricarbonyls [B(CO)3 ] and [C(CO)3 ](+) Featuring a Tilted One-Electron Donor Carbonyl Ligand.Serendipitous Observation of Al(I) Insertion into a CO Bond in L2 PhB: (L=oxazol-2-ylidene).Exploring the reducing role of boron: added insights from theory.Carbene-induced synthesis of the first borironium cations using the [(η(5)-C5Me5)Fe(CO)2](-) anion as an unlikely leaving group.The synthesis and structure of a carbene-stabilized iminocarboranyl-boron(I) compound.Crystalline Neutral Allenic Diborene.Ring Enlargement of Three-Membered Boron Heterocycles upon Reaction with Organic π Systems: Implications for the Trapping of Borylenes.A DFT Study on the Stabilization of the B≡B Triple Bond in a Metallaborocycle: Contrasting Electronic Structures of Boron and Carbon Analogues.Reactivity of a Dihydrodiborene with CO: Coordination, Insertion, Cleavage, and Spontaneous Formation of a Cyclic Alkyne.Synthesis and Reduction of Sterically Encumbered Mesoionic Carbene-Stabilized Aryldihaloboranes.Synthesis and Trapping of Iminoboranes by M=B/C=N Bond Metathesis.Boron as an Electron-Pair Donor for B⋅⋅⋅Cl Halogen Bonds.Diverse Activation Modes in the Hydroboration of Aldehydes and Ketones with Germanium, Tin, and Lead Lewis Pairs.Ambireactive (R3 P)2 BH2 Groups Facilitating Temperature-Switchable Bond Activation by an Iron Complex.Phosphine-Stabilized Borylenes and Boryl Anions as Ligands? Redox Reactivity in Boron-Based Pincer Complexes.Cyclic (Amino)(Phosphonium Bora-Ylide)Silanone: A Remarkable Room-Temperature-Persistent Silanone.Isolable Boron Persulfide: Activation of Elemental Sulfur with a 2-Chloro-Azaborolyl Anion.Formation and characterization of the boron dicarbonyl complex [B(CO)2](-).Donor ligands based on tricoordinate boron formed by B-H-activation of bis(phosphine)boronium salts.Boron compounds tackle dinitrogen.Striking transformations of the hydroborylene ligand in a HB:→NiII complex with isocyanides and CO.Mild and Complete Carbonyl Ligand Scission on a Mononuclear Transition Metal Complex.Fundamental Differences between Group 8 Metals: Unexpected Oxidation State Preferences and Mechanisms in Ruthenium Borylene Complex Formation.Exceptionally Strong Electron-Donating Ability of Bora-Ylide Substituent vis-à-vis Silylene and Silylium Ion.
P2860
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P2860
Multiple complexation of CO and related ligands to a main-group element.
description
2015 nî lūn-bûn
@nan
2015年の論文
@ja
2015年学术文章
@wuu
2015年学术文章
@zh
2015年学术文章
@zh-cn
2015年学术文章
@zh-hans
2015年学术文章
@zh-my
2015年学术文章
@zh-sg
2015年學術文章
@yue
2015年學術文章
@zh-hant
name
Multiple complexation of CO and related ligands to a main-group element.
@en
Multiple complexation of CO and related ligands to a main-group element.
@nl
type
label
Multiple complexation of CO and related ligands to a main-group element.
@en
Multiple complexation of CO and related ligands to a main-group element.
@nl
prefLabel
Multiple complexation of CO and related ligands to a main-group element.
@en
Multiple complexation of CO and related ligands to a main-group element.
@nl
P2093
P2860
P50
P356
P1433
P1476
Multiple complexation of CO and related ligands to a main-group element.
@en
P2093
Christopher W Tate
Florian Hupp
Marco Nutz
P2860
P2888
P304
P356
10.1038/NATURE14489
P407
P577
2015-06-01T00:00:00Z
P6179
1016160745