Synthesis and characterization of a neutral tricoordinate organoboron isoelectronic with amines.
about
The IX (X=O,N,C) Double Bond in Hypervalent Iodine Compounds: Is it Real?Oxidative addition of water and methanol to a dicationic trivalent phosphorus centre.Metal-free binding and coupling of carbon monoxide at a boron-boron triple bond.Borenium ion catalyzed hydroboration of alkenes with N-heterocyclic carbene-boranesSynthesis and reactions of N-heterocyclic carbene boranes.Carbene-Stabilized Main Group Radicals and Radical IonsDonor-acceptor chemistry in the main group.Synthetic and structural studies of phosphine coordinated boronium salts.Formation and Reactivity of Electron-Precise B-B Single and Multiple Bonds.A Tale of Two Elements: The Lewis Acidity/Basicity Umpolung of Boron and Phosphorus.Borylenes: An Emerging Class of Compounds.Unique molecular geometries of reduced 4- and 5-coordinate zinc complexes stabilised by diiminopyridine ligand.Versatile coordination of a reactive P,N-ligand toward boron, aluminum and gallium and interconversion reactivity.Design, Synthesis, and Structural Analysis of Divalent N(I) Compounds and Identification of a New Electron-Donating Ligand.Generation of 1,2-azaboretidines via reduction of ADC borane adducts.1,3,2,5-Diazadiborinine featuring nucleophilic and electrophilic boron centres.Easy access to nucleophilic boron through diborane to magnesium boryl metathesis.A Brief Survey of our Contribution to Stable Carbene Chemistry.Ambiphilic boron in 1,4,2,5-diazadiborinine.Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anionBorylation of fluorinated arenes using the boron-centred nucleophile B(CN)32- - a unique entry to aryltricyanoborates.Completing the series of boron-nucleophilic cyanoborates: boryl anions of type NHC-B(CN)2.Existence of dynamic tautomerism and divalent N(I) character in N-(pyridin-2-yl)thiazol-2-amine.A stable singlet biradicaloid siladicarbene: (L:)2Si.Synthesis and structure of carbene-stabilized N-centered cations [L2N]+, [L2NR]2+, [LNR3]2+ , and [L3N]3+.The first bismuth-NHC complexes.Recent advances in the field of main-group mono- and diatomic "allotropes" stabilised by neutral ligands.Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes.Synthesis and structure of the first heterodinuclear bis(borylene) complexes.Formation of trichlorosilyl-substituted carbon-centered stable radicals through the use of π-accepting carbenes.A coordination compound of Ge(0) stabilized by a diiminopyridine ligand.Chiral heterobimetallic complexes of carbodiphosphoranes and phosphinidene-carbene adducts.Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ-Donating and π-Accepting Ligands for Transition Metals.A snapshot of inorganic Janovsky complex analogues featuring a nucleophilic boron center.Triaminotriborane(3): A Homocatenated Boron Chain Connected by B-B Multiple Bonds.An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH].From Borane to Borylene without Reduction: Ambiphilic Behavior of a Monovalent Silylisonitrile Boron Species.Carbones as Ligands in Novel Main-Group Compounds E[C(NHC)2 ]2 (E=Be, B+ , C2+ , N3+ , Mg, Al+ , Si2+ , P3+ ): A Theoretical Study.Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square.Interactions of Isonitriles with Metal-Boron Bonds: Insertions, Coupling, Ring Formation, and Liberation of Monovalent Boron.
P2860
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P2860
Synthesis and characterization of a neutral tricoordinate organoboron isoelectronic with amines.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年学术文章
@wuu
2011年学术文章
@zh
2011年学术文章
@zh-cn
2011年学术文章
@zh-hans
2011年学术文章
@zh-my
2011年学术文章
@zh-sg
2011年學術文章
@yue
2011年學術文章
@zh-hant
name
Synthesis and characterization ...... ron isoelectronic with amines.
@en
Synthesis and characterization ...... ron isoelectronic with amines.
@nl
type
label
Synthesis and characterization ...... ron isoelectronic with amines.
@en
Synthesis and characterization ...... ron isoelectronic with amines.
@nl
prefLabel
Synthesis and characterization ...... ron isoelectronic with amines.
@en
Synthesis and characterization ...... ron isoelectronic with amines.
@nl
P2093
P2860
P356
P1433
P1476
Synthesis and characterization ...... ron isoelectronic with amines.
@en
P2093
Bruno Donnadieu
Gernot Frenking
Mehmet Ali Celik
P2860
P304
P356
10.1126/SCIENCE.1207573
P407
P50
P577
2011-07-01T00:00:00Z