Reactivity of Pd(II) complexes with electrophilic chlorinating reagents: isolation of Pd(IV) products and observation of C-Cl bond-forming reductive elimination.
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An Umpolung Strategy for the Synthesis of β-Aminoketones via Copper-Catalyzed Electrophilic Amination of Cyclopropanols.Palladium-Catalyzed Ligand-Directed C−H Functionalization ReactionsReductive functionalization of a rhodium(III)-methyl bond by electronic modification of the supporting ligand.Carbon-heteroatom bond formation catalysed by organometallic complexesSynthetic and mechanistic studies on Pd(0)-catalyzed diamination of conjugated dienes.Bimetallic reductive elimination from dinuclear Pd(III) complexes.On the mechanism of palladium-catalyzed aromatic C-H oxidationExploring bis(cyclometalated) ruthenium(II) complexes as active catalyst precursors: room-temperature alkene-alkyne coupling for 1,3-diene synthesis.Palladium(III) in Synthesis and Catalysis.Palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chloridesMechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation.Stable gold(III) catalysts by oxidative addition of a carbon-carbon bond.Regioselective C-H bond amination by aminoiodanes.C-H bond activation at palladium(IV) centers.Monoprotected l-Amino Acid (l-MPAA), Accelerated Bromination, Chlorination, and Iodination of C(sp2 )-H Bonds by Iridium(III) Catalysis.Chemistry of polyvalent iodine.Organopalladium(IV) chemistry.If C-H bonds could talk: selective C-H bond oxidationHigh-valent organometallic copper and palladium in catalysis.Directed meta-Selective Bromination of Arenes with Ruthenium Catalysts.Aryl-CF(3) bond-forming reductive elimination from palladium(IV)Mechanism of C-F reductive elimination from palladium(IV) fluorides.Tuning the Stability of Pd(IV) Intermediates Using a Redox Non-innocent Ligand Combined with an Organolanthanide Fragment.Mechanistic comparison between Pd-catalyzed ligand-directed C-H chlorination and C-H acetoxylation.Oxidation of a cyclometalated Pd(II) dimer with "CF3+": formation and reactivity of a catalytically competent monomeric Pd(IV) aquo complex.C-F Bond Formation for the Synthesis of Aryl Fluorides.Methylpalladium complexes with pyrimidine-functionalized N-heterocyclic carbene ligands.Halide-Dependent Mechanisms of Reductive Elimination from Gold(III)Palladium-catalyzed oxidative arylhalogenation of alkenes: synthetic scope and mechanistic insights.Ruthenium-Catalyzed meta-Selective C-H BrominationReversible C-C bond formation at a triply cyclometallated platinum(iv) centre.Synthetic and mechanistic studies of Pd-catalyzed C-H arylation with diaryliodonium salts: evidence for a bimetallic high oxidation state Pd intermediate.Synthesis and reactivity of a mono-sigma-aryl palladium(IV) fluoride complex.Cationic Pd(II)-catalyzed C-H activation/cross-coupling reactions at room temperature: synthetic and mechanistic studies.Bis-N-heterocyclic carbene palladium(IV) tetrachloride complexes: synthesis, reactivity, and mechanisms of direct chlorinations and oxidations of organic substrates.Palladium-Catalyzed C-H Arylation Using Aryltrifluoroborates in Conjunction with a Mn(III) Oxidant under Mild Conditions.Copper-catalyzed direct synthesis of iodoenamides from ketoximes.Transition-Metal-Free Decarboxylative Iodination: New Routes for Decarboxylative Oxidative Cross-Couplings.Silver ion promoted, Pd(II)-catalyzed arylation of arenes with a free amine as directing group in aqueous medium.Directed C-H Activation and Tandem Cross-Coupling Reactions Using Palladium Nanocatalysts with Controlled Oxidation.
P2860
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P2860
Reactivity of Pd(II) complexes with electrophilic chlorinating reagents: isolation of Pd(IV) products and observation of C-Cl bond-forming reductive elimination.
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年学术文章
@wuu
2007年学术文章
@zh
2007年学术文章
@zh-cn
2007年学术文章
@zh-hans
2007年学术文章
@zh-my
2007年学术文章
@zh-sg
2007年學術文章
@yue
2007年學術文章
@zh-hant
name
Reactivity of Pd
@nl
Reactivity of Pd(II) complexes ...... forming reductive elimination.
@en
type
label
Reactivity of Pd
@nl
Reactivity of Pd(II) complexes ...... forming reductive elimination.
@en
prefLabel
Reactivity of Pd
@nl
Reactivity of Pd(II) complexes ...... forming reductive elimination.
@en
P356
P1476
Reactivity of Pd(II) complexes ...... forming reductive elimination.
@en
P2093
Salena R Whitfield
P304
15142-15143
P356
10.1021/JA077866Q
P407
P50
P577
2007-11-16T00:00:00Z