Enantioselective gold-catalyzed functionalization of unreactive sp3 C-H bonds through a redox-neutral domino reaction.
about
Preparation of neuroprotective condensed 1,4-benzoxazepines by regio- and diastereoselective domino Knoevenagel-[1,5]-hydride shift cyclization reactionRedox-neutral α-oxygenation of amines: reaction development and elucidation of the mechanism.Recent advances in the gold-catalyzed additions to C-C multiple bonds.Asymmetric Redox-Annulation of Cyclic Amines.C-H bond functionalization via hydride transfer: formation of α-arylated piperidines and 1,2,3,4-tetrahydroisoquinolines via stereoselective intramolecular amination of benzylic C-H bonds.Transition metal-mediated synthesis of monocyclic aromatic heterocyclesMetal-free α-amination of secondary amines: computational and experimental evidence for azaquinone methide and azomethine ylide intermediates.Redox-neutral copper(II) carboxylate catalyzed α-alkynylation of amines.Facile Access to Ring-Fused Aminals via Direct α-Amination of Secondary Amines with ortho-Aminobenzaldehydes. Synthesis of Vasicine, Deoxyvasicine, Deoxyvasicinone, Mackinazolinone and Ruteacarpine.Intriguing mechanistic labyrinths in gold(I) catalysis.C-H bond functionalization through intramolecular hydride transfer.Gold-catalyzed C(sp3)-H bond functionalization.Organo- and Organometallic-Catalytic Intramolecular [1,5]-Hydride Transfer/Cyclization Process through C(sp(3) )-H Bond Activation.Hydrogen-Atom Transfer Reactions.Silver & gold-catalyzed routes to furans and benzofurans.Gold-Catalyzed Enantioselective Annulations.Intramolecular Redox-Mannich Reactions: Facile Access to the Tetrahydroprotoberberine Core.The redox-Mannich reaction.Redox-neutral α,β-difunctionalization of cyclic amines.Redox-neutral α-C-H bond functionalization of secondary amines with concurrent C-P bond formation/N-alkylation.Redox-neutral α-arylation of amines.Intramolecular [3 + 2]-cycloadditions of azomethine ylides derived from secondary amines via redox-neutral C-H functionalization.Modular synthesis of all-substituted furans through oxidative carbonylation of cyclopropenes with tandem metal relay catalysis.Redox-Neutral Aromatization of Cyclic Amines: Mechanistic Insights and Harnessing of Reactive Intermediates for Amine α- and β-C-H Functionalization.Phosphine-Mediated Sequential Annulation Reaction: Access to Functionalized Benzofurans and 4,5-Dihydrobenzofurans.Asymmetric tandem 1,5-hydride shift/ring closure for the synthesis of chiral spirooxindole tetrahydroquinolines.Gold-catalyzed cascade reactions for synthesis of carbo- and heterocycles: selectivity and diversity.A new type of chiral sulfinamide monophosphine ligands: stereodivergent synthesis and application in enantioselective gold(I)-catalyzed cycloaddition reactions.Gold/Brønsted acid relay catalysis for enantioselective construction of spirocyclic diketones.Gold(I)-catalyzed regiodivergent rearrangements: 1,2- and 1,2'-alkyl migration in skipped alkynyl ketones.Kinetic resolution of 1-(1-alkynyl)cyclopropyl ketones by gold(I)-catalyzed asymmetric [4+3]cycloaddition with nitrones: scope, mechanism and applications.Palladium(II)-catalyzed stereospecific three-component domino reactions of diyne-enones, nucleophiles, and vinyl ketones.Catalytic enantioselective tert-aminocyclization by asymmetric binary acid catalysis (ABC): stereospecific 1,5-hydrogen transfer.Hf(OTf)4-Catalyzed highly diastereoselective synthesis of 1,3-disubstituted tetralin derivatives via benzylic C(sp3)-H bond functionalization.Mild gold-catalyzed three-component dehydrogenative coupling of terminal alkynes to amines and indole-2-carboxaldehyde.The redox-neutral approach to C-H functionalization.Enantioselective gold-catalyzed intermolecular [2+2] versus [4+2]-cycloadditions of 3-styrylindoles with N-allenamides: observation of interesting substituent effects.Organocatalytic Asymmetric Direct C sp 3H Functionalization of Ethers: A Highly Efficient Approach to Chiral SpiroethersEnantioselective gold-catalyzed intermolecular [2 + 2]-cycloadditions of 3-styrylindoles with N-allenyl oxazolidinoneGold(i)-catalyzed asymmetric [3 + 2]-cycloadditions of γ-1-ethoxyethoxy-propiolates and aldehydes
P2860
Q34751801-E1810693-BD5E-4E69-8D03-DA75A02FF430Q35098651-A15673F4-096B-454D-8376-7AA59BBF2EB4Q35101911-0850FEEA-DD06-4DDD-B2B4-5B37E384FB2CQ36142441-D311B01E-209C-457E-9D88-4D61F9EADA73Q36207364-BDAF6A22-81FB-4F1D-AA58-8A763E7E7873Q36831938-D10B7A94-B122-41CC-B863-5A64ADB854C9Q36844734-3427EAB9-D604-48C1-BFA5-B588E3F611AEQ37173876-01955543-BA39-4316-AC00-50D88F882260Q37173920-FF947192-67C5-4983-8565-3C7B3AD7A6F8Q38157453-E6F59628-878D-42AF-BDAA-AA2850B4BB87Q38202610-B1FD9E9E-1906-425F-955E-8C9E1E1D9F08Q38213934-C731912B-E760-4AC3-A337-8E993ACE053DQ38803445-D21387EA-F35D-4EEF-921C-011BD569AC15Q38940195-95360E13-511F-46F6-A958-BD2992553CCFQ38976907-81531B37-B7DA-4D4E-98C6-F9E4F57B61CCQ38977009-789675F8-98A2-4557-B83B-21E47C730051Q39530179-6284C15C-9B94-4B31-8E6B-C7E62E2E79BCQ40758581-8B47E1E3-38B4-4BA9-A401-220F56B3B53BQ41067116-961F9EE1-F2ED-4847-84F0-299D391CB1B6Q41862545-AF6D0BEC-E99A-410F-B3CB-54E4CD8196AEQ42008846-0C746284-3DE8-41D4-8569-0AE8DA2440D8Q43050023-95125F6D-8836-45F2-8956-ED0CB49B9822Q45809241-58361F1A-F027-485B-B4B0-424544B9F842Q46586475-13E9E184-D726-4C45-92A4-3B7942F15AAAQ48206567-5EAC2C60-282F-429F-BB45-F2D9DEFC8BB4Q50445415-43D13774-4CA8-4561-83A0-DBC2144C0BCAQ50458693-122649F2-1936-4C5E-B39E-66B710B1ED3BQ50459109-8CC4C888-B14C-42ED-B68D-8290AA39B679Q50481514-C4678D4F-1AB7-4279-A613-F7BD02814FB0Q50489567-8A8C842B-77A1-42A9-B0B4-CB20B2207541Q50499571-3004D3EB-9AC1-4DF2-8963-6BAFF23462F9Q50506711-5925E36C-5F5D-4958-A4DF-46AE564556E1Q50508847-D52C48E1-73AB-456D-ADE7-0A182D2DD4FBQ50935939-F8F4C97B-60DA-41E8-9953-9EC40C6A938CQ51749025-0A0BC96F-5D6B-4F3D-96AB-5671885D36C5Q51785550-9426ADBF-BEA0-4721-BFA5-FF5DBA05A697Q55263192-C99C253A-8878-45A4-AC83-5326D881BD8CQ58374761-CBD229CC-37E5-40A8-921D-1B5675DC6489Q58948376-69069FA5-CAA5-4FCC-A44F-9B36D17ACD5DQ58948389-92906B2A-D685-42B9-B7D7-0FE42F5C63C4
P2860
Enantioselective gold-catalyzed functionalization of unreactive sp3 C-H bonds through a redox-neutral domino reaction.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年学术文章
@wuu
2011年学术文章
@zh
2011年学术文章
@zh-cn
2011年学术文章
@zh-hans
2011年学术文章
@zh-my
2011年学术文章
@zh-sg
2011年學術文章
@yue
2011年學術文章
@zh-hant
name
Enantioselective gold-catalyze ...... redox-neutral domino reaction.
@en
Enantioselective gold-catalyze ...... redox-neutral domino reaction.
@nl
type
label
Enantioselective gold-catalyze ...... redox-neutral domino reaction.
@en
Enantioselective gold-catalyze ...... redox-neutral domino reaction.
@nl
prefLabel
Enantioselective gold-catalyze ...... redox-neutral domino reaction.
@en
Enantioselective gold-catalyze ...... redox-neutral domino reaction.
@nl
P2093
P356
P1476
Enantioselective gold-catalyze ...... redox-neutral domino reaction.
@en
P2093
Guanghua Zhou
Junliang Zhang
P304
P356
10.1002/CHEM.201100019
P407
P577
2011-02-15T00:00:00Z