Stereodivergent Synthesis of N-Heterocycles by Catalyst-Controlled, Activity-Directed Tandem Annulation of Diazo Compounds with Amino Alkynes.

Stereodivergent Synthesis of N-Heterocycles by Catalyst-Controlled, Activity-Directed Tandem Annulation of Diazo Compounds with Amino Alkynes.

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http://www.wikidata.org/entity/Q51726507
Functionalizing the γ-Position of α-Diazo-β-ketoesters.Cycloaddition reactions of enoldiazo compounds.Unusual reactions of diazocarbonyl compounds with α,β-unsaturated δ-amino esters: Rh(II)-catalyzed Wolff rearrangement and oxidative cleavage of N-H-insertion products.Rh(II)-mediated domino [4 + 1]-annulation of α-cyanothioacetamides using diazoesters: A new entry for the synthesis of multisubstituted thiophenes.Synthesis of seven-membered heterocycles via copper-catalyzed cross-coupling of terminal alkynes with diazo compounds and sequential Michael addition.Hypervalent iodine-triggered transformation of homopropargyl sulfonamides into dihalo-2,3-dihydropyrroles.Tandem Aryne-Capture/Sigmatropic Rearrangement as a Metal-Free Entry to Functionalized N-Aryl Pyrrolidines.Synthesis of Pyrrolidines and Pyrrolizidines with α-Pseudoquaternary Centers by Copper-Catalyzed Condensation of α-Diazodicarbonyl Compounds and Aryl γ-Lactams.Catalytic Divergent [3+3]- and [3+2]-Cycloaddition by Discrimination Between Diazo Compounds.Synthesis of 2,3'-spirobi[indolin]-2-ones enabled by a tandem nucleophilic benzylation/C(sp2)-N cross-coupling reaction sequence.Regiodivergent Intermolecular [3+2] Cycloadditions of Vinyl Aziridines and Allenes: Stereospecific Synthesis of Chiral Pyrrolidines.A controlled selective synthesis of dihydropyrans through tandem reaction of alkynes with diazo compounds.Gold-Catalyzed Formal [4+1]/[4+3] Cycloadditions of Diazo Esters with Triazines.Silver-mediated direct trifluoromethoxylation of α-diazo esters via the (-)OCF3 anion.Asymmetric Michael Addition of Aldimino Esters with Chalcones Catalyzed by Silver/Xing-Phos: Mechanism-Oriented Divergent Synthesis of Chiral Pyrrolines.Stereoselective Synthesis of Functionalized Pyrrolidines by the Diverted N-H Insertion Reaction of Metallocarbenes with β-Aminoketone Derivatives.
P2860

Stereodivergent Synthesis of N-Heterocycles by Catalyst-Controlled, Activity-Directed Tandem Annulation of Diazo Compounds with Amino Alkynes.

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http://www.wikidata.org/entity/Q51726507
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2015 nî lūn-bûn
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2015年の論文
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2015年学术文章
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name
Stereodivergent Synthesis of N ...... Compounds with Amino Alkynes.
@en
Stereodivergent Synthesis of N ...... Compounds with Amino Alkynes.
@nl
type
label
Stereodivergent Synthesis of N ...... Compounds with Amino Alkynes.
@en
Stereodivergent Synthesis of N ...... Compounds with Amino Alkynes.
@nl
prefLabel
Stereodivergent Synthesis of N ...... Compounds with Amino Alkynes.
@en
Stereodivergent Synthesis of N ...... Compounds with Amino Alkynes.
@nl
P1433
P1476
P2093
P2860
P304
P31
P356
P407
P433
P478
P50
P577
P698
P356
P1433
P1476
Stereodivergent Synthesis of N ...... o Compounds with Amino Alkynes
@en
P2093
P2860
P304
P31
P356
P407
P433
P478
P50
P577
P698