Enantioselective electrophilic trifluoromethylthiolation of β-ketoesters: a case of reactivity and selectivity bias for organocatalysis.
about
Structural reevaluation of the electrophilic hypervalent iodine reagent for trifluoromethylthiolation supported by the crystalline sponge method for X-ray analysisDifluorocarbene-Derived Trifluoromethylthiolation and [(18)F]Trifluoromethylthiolation of Aliphatic ElectrophilesHypervalent iodine: a powerful electrophile for asymmetric α-functionalization of carbonyl compounds.Advances in catalytic enantioselective fluorination, mono-, di-, and trifluoromethylation, and trifluoromethylthiolation reactions.Late stage trifluoromethylthiolation strategies for organic compounds.Chiral phase-transfer catalysis in the asymmetric α-heterofunctionalization of prochiral nucleophilesEnantioselective Phase-Transfer Catalyzed α-Sulfanylation of Isoxazolidin-5-ones: An Entry to β(2,2) -Amino Acid Derivatives.N-Heterocyclic carbene-catalyzed sulfa-Michael addition of enals.Catalytic asymmetric trifluoromethylthiolation via enantioselective [2,3]-sigmatropic rearrangement of sulfonium ylides.Enantioselective electrophilic cyanation of β-keto amides catalysed by a cinchona organocatalyst.Tandem trifluoromethylthiolation/aryl migration of aryl alkynoates to trifluoromethylthiolated alkenes.S-Trifluoromethylation of Thiols by Hypervalent Iodine Reagents: A Joint Experimental and Computational Study.Selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation.Generation of the SCF3 Radical by Photoredox Catalysis: Intra- and Intermolecular Carbotrifluoromethylthiolation of Alkenes.Visible Light-Promoted Decarboxylative Di- and Trifluoromethylthiolation of Alkyl Carboxylic Acids.Synthesis of Trifluoromethylthiolated Alkenes and Ketones by Decarboxylative Functionalization of Cinnamic Acids.Catalytic asymmetric sulfenylation to structurally diverse dithioketals.Chiral phosphoric acid-catalyzed asymmetric transfer hydrogenation of 3-trifluoromethylthioquinolines.Enantioselective Trifluoromethylthiolating Lactonization Catalyzed by an Indane-Based Chiral Sulfide.Regioselective ortho-trifluoromethylthiolation of 2-arylbenzo[d]thiazole via tandem substrate-assisted C-H iodination and trifluoromethylthiolation.Silver-mediated oxidative aliphatic C-H trifluoromethylthiolation.Williamson Ether Synthesis with Phenols at a Tertiary Stereogenic Carbon: Formal Enantioselective Phenoxylation of β-Keto Esters.The direct electrophilic cyanation of β-keto esters and amides with cyano benziodoxole.Copper-mediated oxidative trifluoromethylthiolation of unactivated terminal alkenes.
P2860
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P2860
Enantioselective electrophilic trifluoromethylthiolation of β-ketoesters: a case of reactivity and selectivity bias for organocatalysis.
description
2013 nî lūn-bûn
@nan
2013年の論文
@ja
2013年学术文章
@wuu
2013年学术文章
@zh
2013年学术文章
@zh-cn
2013年学术文章
@zh-hans
2013年学术文章
@zh-my
2013年学术文章
@zh-sg
2013年學術文章
@yue
2013年學術文章
@zh-hant
name
Enantioselective electrophilic ...... vity bias for organocatalysis.
@en
Enantioselective electrophilic ...... vity bias for organocatalysis.
@nl
type
label
Enantioselective electrophilic ...... vity bias for organocatalysis.
@en
Enantioselective electrophilic ...... vity bias for organocatalysis.
@nl
prefLabel
Enantioselective electrophilic ...... vity bias for organocatalysis.
@en
Enantioselective electrophilic ...... vity bias for organocatalysis.
@nl
P2093
P2860
P356
P1476
Enantioselective electrophilic ...... vity bias for organocatalysis.
@en
P2093
Qilong Shen
Xiaolin Cheng
P2860
P304
12860-12864
P356
10.1002/ANIE.201305075
P407
P577
2013-09-02T00:00:00Z