Solvent effects on the rates and mechanisms of reaction of phenols with free radicals.
about
Proton-coupled electron transferMoving protons and electrons in biomimetic systemsBiochemistry and theory of proton-coupled electron transferCatalytic C-O bond cleavage of 2-aryloxy-1-arylethanols and its application to the depolymerization of lignin-related polymersPredicting organic hydrogen atom transfer rate constants using the Marcus cross relation.The importance of precursor and successor complex formation in a bimolecular proton-electron transfer reactionTuning of the thermochemical and kinetic properties of ascorbate by its local environment: solution chemistry and biochemical implications.Modulation of the antioxidant activity of phenols by non-covalent interactions.Understanding hydrogen atom transfer: from bond strengths to Marcus theory.Curcumin: from ancient medicine to current clinical trials.A Simple Marcus-Theory Type Model for Hydrogen Atom Transfer/Proton-Coupled Electron Transfer.Unraveling curcumin degradation: autoxidation proceeds through spiroepoxide and vinylether intermediates en route to the main bicyclopentadione.Structure-thermodynamics-antioxidant activity relationships of selected natural phenolic acids and derivatives: an experimental and theoretical evaluation.Oxidative Transformation of Demethoxy- and Bisdemethoxycurcumin: Products, Mechanism of Formation, and Poisoning of Human Topoisomerase IIαFragmentation of β-hydroxy hydroperoxidesQuantum-chemical investigation of the structure and the antioxidant properties of α-lipoic acid and its metabolitesThe Third Dimension of a More O'Ferrall-Jencks Diagram for Hydrogen Atom Transfer in the Isoelectronic Hydrogen Exchange Reactions of (PhX)(2)H(•) with X = O, NH, and CH(2).Degradation of Curcumin: From Mechanism to Biological Implications[CuO](+) and [CuOH](2+) complexes: intermediates in oxidation catalysis?Surprisingly long-lived ascorbyl radicals in acetonitrile: concerted proton-electron transfer reactions and thermochemistryFacile concerted proton-electron transfers in a ruthenium terpyridine-4'-carboxylate complex with a long distance between the redox and basic sites.Antioxidant properties of phenols.First experimental evidence of dopamine interactions with negatively charged model biomembranesHydrogen atom transfer reactions of a ruthenium imidazole complex: hydrogen tunneling and the applicability of the Marcus cross relation.Synthesis, Radical Reactivity, and Thermochemistry of Monomeric Cu(II) Alkoxide Complexes Relevant to Cu/Radical Alcohol Oxidation CatalysisTrends in ground-state entropies for transition metal based hydrogen atom transfer reactions.Slow hydrogen atom transfer reactions of oxo- and hydroxo-vanadium compounds: the importance of intrinsic barriers.Nitroxyl radical plus hydroxylamine pseudo self-exchange reactions: tunneling in hydrogen atom transfer.Stepwise N-H Bond Formation From N2-Derived Iron Nitride, Imide and Amide Intermediates to Ammonia.Riboflavin as a photosensitizer. Effects on human health and food quality.Reactivity of the copper(iii)-hydroxide unit with phenols.Free Radical Scavenging and Cellular Antioxidant Properties of AstaxanthinAddressing Facts and Gaps in the Phenolics Chemistry of Winery By-Products.Developing SyrinOX total antioxidant capacity assay for measuring antioxidants in humans.Chain-breaking antioxidant activity of reduced forms of mitochondria-targeted quinones, a novel type of geroprotectors.Pyridine and pyrimidine analogs of acetaminophen as inhibitors of lipid peroxidation and cyclooxygenase and lipoxygenase catalysis.Free-radical scavenging by tryptophan and its metabolites through electron transfer based processes.Importance of solvent association in the estimation of antioxidant properties of phenolic compounds by DPPH method.Linking an α-tocopherol derivative to cobalt(0) nanomagnets: magnetically responsive antioxidants with superior radical trapping activity and reduced cytotoxicity.On the Mechanism of Cytoprotection by Ferrostatin-1 and Liproxstatin-1 and the Role of Lipid Peroxidation in Ferroptotic Cell Death.
P2860
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P2860
Solvent effects on the rates and mechanisms of reaction of phenols with free radicals.
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年学术文章
@wuu
2007年学术文章
@zh
2007年学术文章
@zh-cn
2007年学术文章
@zh-hans
2007年学术文章
@zh-my
2007年学术文章
@zh-sg
2007年學術文章
@yue
2007年學術文章
@zh-hant
name
Solvent effects on the rates and mechanisms of reaction of phenols with free radicals.
@en
Solvent effects on the rates and mechanisms of reaction of phenols with free radicals.
@nl
type
label
Solvent effects on the rates and mechanisms of reaction of phenols with free radicals.
@en
Solvent effects on the rates and mechanisms of reaction of phenols with free radicals.
@nl
prefLabel
Solvent effects on the rates and mechanisms of reaction of phenols with free radicals.
@en
Solvent effects on the rates and mechanisms of reaction of phenols with free radicals.
@nl
P356
P1476
Solvent effects on the rates and mechanisms of reaction of phenols with free radicals.
@en
P2093
K U Ingold
P304
P356
10.1021/AR0682029
P407
P577
2007-03-01T00:00:00Z